• Journal of Korean Society of Environmental Engineers
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• v.29 no.6
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• pp.647-653
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• 2007

The ultimate objective of this study is to develop a reliable oxygen-enriched combustion techniques especially for the case of the flue gas recycling in order to reduce the $CO_2$ emissions from practical industrial boilers. To this end a systematic numerical investigation has been performed, as a first step, for the resolution of the combusting flame characteristics of lab-scale LNG combustor. One of the important parameters considered in this study is the level of flue gas recycling calculated in oxygen enriched environment. As a summary of flame characteristics, for the condition of 100% pure $O_2$ as oxidizer without any flue gas recycling, the flame appears as long and thin laminar-like shape with relatively high flame temperature. The feature of high peak of flame temperature is explained by the absence of dilution and heat loss effects due to the presence of $N_2$ inert gas. The same reasoning is also applicable to the laminarized thin flame one, which is attributed to the decrease of the turbulent mixing. These results are physically acceptable and consistent and further generally in good agreement with experimental results appeared in open literature. As the level of $CO_2$ recycling increases in the mixture of $O_2/CO_2$, the peak flame temperature moves near the burner region due to the enhanced turbulent mixing by the increased amount of flow rate of oxidizer stream. However, as might be expected, the flue gas temperature decreases due to presence of $CO_2$ gas together with the inherent feature of large specific heat of this gas. If the recycling ratio more than 80%, gas temperatures drop so significantly that a steady combustion flame can no longer sustain within the furnace. However, combustion in the condition of 30% $O_2/70% $ $CO_2$ can produce similar gas temperature profiles to those of conventional combustion in air oxidizer. An indepth analyses have been made for the change of flame characteristics in the aspect of turbulent intensity and heat balance.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.5
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• pp.525-544
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• 1999

Polycyclic aromatic hydrocarbons (PAH) were one of the first airborne pollutants to be identified as being carcinogenic. This class of compounds is ubiquitous in the urban atmosphere, and has therefore undergone considerable scrutiny for the last three decades. PAH can be formed in any incomplete combustion or high temperature pyrolytic process involving materials containing carbon and hydrogen, such as fossil fuels. In this paper, the literature on the occurrence, ambient levels, and atmospheric fate and behaviour of airbonrne PAH has been reviewed, with a particular emphasis on the role of automobile sources in PAH emissions. Sampling and analytical techniques for the determination of PAH in air have also been examined. In addition, health implications and legislative aspects of human exposure to airborne PAH have been briefly reviewed. Finally, future requirements for better understanding of the atmospheric behaviour of PAH recommended.

• Journal of the korean Society of Automotive Engineers
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• v.1 no.1
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• pp.28-41
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• 1979

Propane-Air premixed combustible gas was ignited by the conventional current break system inside the open combustion chamber under the atmospheric pressure and the room temperature to measure the flame propagating speed and the burning speed, also to elucidate the history of the propagating flame behavior and wall effects to flame shape by using Ion Gap Method and High Speed Schlieren Photography. The results obtained show that the maximum flame propagating speed and maximum burning speed are approximately 292 cm/sec and 36 cm/sec at the mixture ratio 4.6%, respectively. The cellular flame structures can be observable in the rich mixture region, moreover, the cellular structures become finer, with increasing the mixture strength.

• Transactions of the Korean hydrogen and new energy society
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• v.14 no.1
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• pp.24-34
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• 2003

For gaseous fuel combustion with inherent $CO_2$ capture and low NOx emission, chemical-looping combustion may yield great advantages for the savings of energy to $CO_2$ separation and suppressing the effect on environment, In chemical-looping combustor, fuel is oxidized by metal oxide medium in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor, $CO_2$ and $H_2O$, leave the system as separate stream. The $H_2O$ can be easily separated by condensation and pure $CO_2$ is obtained without any loss of energy for separation. In this study, five oxygen carrier particles such as NiO/bentonite, NiO/YSZ, $(NiO+Fe_2O_3)VYSZ$, $NiO/NiAl_2O_4$, and $Co_{\chi}O_y/CoAl_2O_4$ were examined &om the viewpoints of reaction kinetics, oxygen transfer capacity, and carbon deposition characteristics. Among five oxygen particles, NiO/YSZ particle is superior in reaction rate, oxygen carrier capacity, and carbon deposition to other particles. However, at high temperature ($>900^{\circ}C$), NiO/bentonite particle also shows enough reactivity and oxygen carrier capacity to be applied in a practical system.

• Journal of the Korean Applied Science and Technology
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• v.28 no.4
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• pp.455-463
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• 2011

The average sulfur content of crude oil is 2.2%. Coal is about 0.3 to 4.0 percent of the sulfur gases or particles being discharged into the atmosphere through the chimney as 1 to 2% $SO_3$(Sulfur trioxide) and about 95% of the $SO_2$ is reported. $SO_3$ gas, which has many different causes of, as the combustion of sulfur containing fuel during the air due to the excess $SO_2$ gas is oxidized to $SO_3$ gas. Sulfur trioxide emitted from high sulfur heavy oil fired boiler caused white plume in stack and high temperature and cold end corrosion of facilities. So, in order to control sulfur trioxide concentration of Fuel gas in boiler, various of additives are used in other foreign. They are injected to Fuel Oil and consumed in boiler and reduce ash and the conversion rate of sulfur trioxide. In domestic, MgO compounds are used as additives but the total volume of them are made from other foreign company. In this study, MgO compounds were developed with liquid MgO compounds and field application was accomplished. The effect of newly developed chemicals and process were nearly equal to foreign products. In Consequent, the chemicals and process produced by newly developed technology can be substituted for foreign products and reduce the cost of plant operation.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.608-611
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• 2011

Laser-induced combustions and explosions generated by high laser irradiances were explored by Laser-Induced Breakdown Spectroscopy (LIBS) in rich, and stoichiometric conditions. The laser used for target ablation is a Q-switched Nd:YAG laser with 7 ns pulse duration at wavelength of 1064 nm laser energies from 40 mJ to 2500 mJ ($6.88{\times}10^{10}-6.53{\times}10^{11}\;W/cm^2$). The plasma light source from aluminum detected by the echelle grating spectrometer and coupled to the gated ICCD(a resolution (${\lambda}/{\Delta}{\lambda}$) of 5000). This spectroscopic study has been investigated for obtaining both the atomic signals of aluminum (fuel) - oxygen (oxidizer) and the calculated ambient condition (plasma temperature and electron density). The essence of the paper is observing specific electron density ratio which can support the processes of combustion and explosion between ablated aluminum plume and oxygen from air by inducing high power laser.

• The KSFM Journal of Fluid Machinery
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• v.19 no.1
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• pp.24-30
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• 2016

In this study, a 2W micro-gas turbine engine was designed using micro-electro-mechanical systems (MEMS) technology, and experimental investigations of its potential under actual combustion conditions were performed. A micro-gas turbine (MGT) contains a turbo-charger, combustor, and generator. Compressor and turbine blades, and generator coil were manufactured using MEMS technology. The shaft was supported by a precision computer numerical control (CNC) machined static air bearing, and a permanent magnet was attached to the end of the shaft for generation. A heat transfer analysis found that the cooling effect of the air bearing and compressor was sufficient to cover the combustor's high temperature, which was verified in an actual experiment. The generator performance test showed that it can generate 2W at design rotational speed. Prototype micro-gas turbine generated maximum 1 mW electric power and lasted up to 15 minutes.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.4
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• pp.387-394
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• 2013

Hydrogen-compressed natural gas (HCNG) blend has attracted attention as a fuel that can reduce $CO_2$ emissions because it has low carbon content and burns efficiently. An increase in the compression ratio of HCNG engines was considered as one of the methods to improve their efficiency and reduce $CO_2$ emissions. However, a high combustion rate and flame temperature cause abnormal combustion such as pre-ignition or knocks, which in turn can cause damage to the engine components and decrease the engine power. In this study, the performance and knock characteristics with a change in the compression ratio of an HCNG engine were analyzed. The combustion characteristics of HCNG fuel were evaluated as a function of the excess air ratio using a conventional CNG engine. The effects of the compression ratio on the engine performance were evaluated through the same experimental procedures.

• Journal of the Korean Institute of Gas
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• v.24 no.6
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• pp.1-10
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• 2020

Reactivity controlled compression ignition (RCCI) combustion is one of dual-fuel combustion systems which can be constructed by early diesel injection during the compression stroke to improve premixing between diesel and air. As a result, RCCI combustion promises low nitrogen oxides (NOx) and smoke emissions comparing to those of general dual-fuel combustion. For this combustion system, to meet the intensified emission regulations without emission after-treatment systems, exhaust gas recirculation (EGR) is necessary to reduce combustion temperature with lean premixed mixture condition. However, since EGR is supplied from the front of turbocharger system, intake pressure and the amount of fresh air supplementation are decreased as increasing EGR rate. For this reason, the effect of various EGR rates on the brake power and thermal efficiency of natural gas/diesel RCCI combustion under two different operating conditions in a 6 L compression ignition engine. Varying EGR rate would influence on the combustion characteristic and boosting condition simultaneously. For the 1,200/29 kW and 1,800 rpm/(lower than) 90 kW conditions, NOx and smoke emissions were controlled lower than the emission regulation of 'Tier-4 final' and the maximum in-cylinder pressure was 160 bar for the indurance of engine system. The results showed that under 1,200 rpm/29 kW condition, there were no changes in brake power and thermal efficiency. On the other hand, under 1,800 rpm condition, brake power and thermal efficieny were decreased from 90 to 65 kW and from 37 to 33 % respectively, because of deceasing intake pressure (from 2.3 to 1.8 bar). Therefore, it is better to supply EGR from the rear of compressor, i.e. low pressure EGR (LP-EGR) system, comparing to high pressure EGR (HP-EGR) for the improvement of RCCI power and thermal efficiency.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.4
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• pp.463-472
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• 1996

Experiments were carried out to study the operation characteristics of a regenerator with a thermo-syphon pump and a surface-flame burner for a lithium bromide (LiBr)-water absorption heat pump. A cylindrical-shape metal-fiber burner and commercial grade propane were used. The emission of carbon monoxide and nitric oxide was measured by a combustion gas analyzer. Ther regeneration rate of water vapor as a refrigerant was measured. It could be as a reference value showing the performance of the regenerator. The circulation rate of the LiBr-water solution was also measured from both the tanks for the weak-and the strong-solution. Using a refractometer, the LiBr concetration in the solution was calculated from the measured refractory index of the solution. Temperature of the solution and the condensed water was recorded at several points in the experimental apparatus with thermocouples, using a personal computer. This data collecting system for measuring temperature was calibrated with a set of standard thermometers. The generating rate of water vapor as refrigerant increased linearly with heat supplied. It was about 4.0g/s with the heat supplied at a rate of 16,500kcal/h. The circulation rate of LiBr solution also increases with the heat supplied. The difference in LiBr concentrations between the weak and the strong solution was in the range of 1 to 5% when the concentration of the strong solution was about 60%. It was dependent upon both the heat supplied and the circulation rate of the solution. The initial concentration and the level of the LiBr solution in the regenerator were measured and recorded before experiments. The effect of them on the generating rate of water vapor and the circulation rate of the solution was also studied. The generating rate of water vapor was not strongly dependent upon both the level of the LiBr solution and the initial LiBr concentration. However, the concentration difference of the solution increases with the initial level of the LiBr solution.