• Title/Summary/Keyword: High-Oxygen Concentration

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Modeling of Electrical Conductivity from $\sigma$tot vs. Po21/4 Plot in Wet Atmosphere for High-Temperature Proton-Conducting Oxides

  • Baek, Hyun-Deok
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.136-140
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    • 1998
  • This work demonstrates a method for modeling of electrical conductivity in high-temperature proton-conducting oxides. Total conductivity was calculated assuming that it comprises partial conductivities contributed by protons, oxygen ions and electron holes. From the polt $\sigma_{tot}$ vs. $po_2\;{1/4}$ in wet atmosphere, thermodynamic and kinetic parameters were obtained representing transport properties such as concentration and mobility of the charge-carrying defects. The formulas for the calculation of partial conduction were derived based on the defect structure of HTPCs. Illustrative calculation were made for $SrCe_{0.95}Yb_{0.05}O_{2.975}$ system.

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Process and Characteristics of High Power Catalyst Electrode for PEM Fuel Cell

  • Chang H.;Lim C.;Kim J.
    • Journal of the Korean Electrochemical Society
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    • v.2 no.3
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    • pp.171-175
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    • 1999
  • Novel process for high power catalyst electrode for PEM fuel cell has been developed. MEA having this catalyst electrode showed $0.5W/cm^2\;with\;0.2mg/cm^2$ of Pt loading at aunospheric humid hydrogen and oxygen condition. In this process, platinized carbon and plain carbon powders were coated with ionomer (Nafion) and hydrophobic polymer (PTFE), respectively and it could maximize two roles of catalyst electrode, l.e., reaction and gas supplying component. Those polarization characteristics proved the improved performance by reducing potential drop especially in the concentration polarization region.

Biotechnological Characteristics of Some Saccharomyces species Isolated from Wine Yeast Culture

  • Letitia, Oprean
    • Food Science and Biotechnology
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    • v.14 no.6
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    • pp.722-726
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    • 2005
  • The use of isolated wine yeasts in winemaking processes is preferable to spontaneous fermentation. Selection criteria of wine yeast strains depend also on capacity and rate of fermentation and on alcohologenic capabilities. Our studies have described the dynamics of fermentation of wine musts by some isolated wine yeast strains of Saccharomyces genus: strains 6 and 8 of S. cerevisiae var. ellipsoideus (S. ellipsoideus) and strains 5 and 7 of S. bayanus var. oviformis (S. oviformis). All have high technological properties and all are adapted for the specific pedoclimatic conditions of some areas of Sibiu viticultural region. The selected strains were used as inocula to ferment Sauvignon, Muscat Ottonel, Rose Traminer, and Pino Gris musts in controlled laboratory conditions. It was found that higher initial oxygen concentration in must is necessary to accelerate the fermentation of all the wine yeast strains studied. In order to obtain quality wines, strains with considerable fermentative capacity, high alcohologenic capabilities, and a good conversion efficiency are recommended.

Synethisis of fine BSCCO precursor powder by spray pyrolysis (분무 열분해에 의한 미세 BSCCO 전구체 분말의 합성)

  • 김성환;유재무;고재웅;김영국;박성창
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.99-102
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    • 2003
  • Many researches on synthesis process for BSCCO precursor powders have been developed for high J$_{c}$ BSCCO-2223/Ag tape. Spray pyrolysis method for fabrication of precursor powder has many advantages, such as high purity, fine particle size of BSCCO precursor powder. Fine, spherical powders were prepared by ultrasonic spray pyrolysis from the aqueous solution of metal nitrates. BSCCO precursor powders were synthesized with 0.1 M concentration and heat treatment conditions. Average particle size for spray pyrolysis powders was 1.5 ~ 3 ${\mu}{\textrm}{m}$. BSCCO -2223/Ag tape was prepared by PIT method and followed by various sintering conditions. The critical current density of BSCCO-2223/Ag tape sintered in low oxygen partial pressure was ~ 23 kAcm$^{-2}$.

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The Effects of the Spat Planting Time and Environmental Factors in the Arkshell, Scapharca broughtonii Schrenck Culture (피조개(Scapharca broughtonii Schrenck) 양식시 살포시기와 환경 특성의 영향)

  • Kim, Jeong-Bae;Lee, Sang-Yong;Jung, Choon-Goo;Jung, Chang-Su;Son, Sang-Gyu
    • Journal of Aquaculture
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    • v.20 no.1
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    • pp.31-40
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    • 2007
  • To find out the effect of the spat planting time and environmental factors in the arkshell, Scapharca broughtonii (Schrenck), we investigated the growth, survival rate of arkshell and habitat characteristics in Gamak Bay, Yeoja Bay and Saryang Island. We planted artificial spats of arkshell in Gamak Bay and Yeoja Bay at November 2004, and also planted domestic and Chinese natural spats in Saryang Island at March 2005. We measured growth, survival rate of arkshell, physiochemical parameters of the water mass (water temperature, salinity, dissolved oxygen, nutrients and chlorophyll a) and characteristics of the sediment (oxygen penetration depth, oxygen microprofiles, ignition loss and chemical oxygen demand) by monthly. The cumulative survival ratio of arkshell in Gamak Bay was the highest at December, whereas the ratio of arkshell in Yeoja Bay was recorded as 0% at October. The monthly growth rates of arkshell length in Gamak Bay and Yeoja Bay were the highest in May and the growth rate of the Korean arkshell in Saryang Island was higher than Chinese ones significantly. The high mortality (> 65%) of the arkshell in Yeoja Bay during summer probably caused by high water temperature, inflow of low salinity water, and low dissolved oxygen concentration in sediment. The concentrations of nutrient and sediment COD were considered to play an important role in the monthly survival ratio of arkshell in Gamak Bay and Sarayng Island. We suggest that the growth and mortality of arkshell might be influenced to the planting time of spat and the habitat characteristics.

Anthracite Oxygen Combustion Simulation in 0.1MWth Circulating Fluidized Bed (0.1 MWth 급 순환유동층에서의 무연탄 연소 전산유체역학 모사)

  • Go, Eun Sol;Kook, Jin Woo;Seo, Kwang Won;Seo, Su Been;Kim, Hyung Woo;Kang, Seo Yeong;Lee, See Hoon
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.417-428
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    • 2021
  • The combustion characteristics of anthracite, which follow a complex process with low reactivity, must be considered through the dynamic behavior of circulating fluidized bed (CFB) boilers. In this study, computational fluid dynamics (CFD) simulation was performed to analyze the combustion characteristics of anthracite in a pilot scale 0.1 MWth Oxy-fuel circulating fluidized bed (Oxy-CFB) boiler. The 0.1MWth Oxy-CFB boiler is composed of combustor (0.15 m l.D., 10 m High), cyclone, return leg, and so on. To perform CFD analysis, a 3D simulation model reactor was designed and used. The anthracite used in the experiment has an average particle size of 1,070 ㎛ and a density of 2,326 kg/m3. The flow pattern of gas-solids inside the reactor according to the change of combustion environment from air combustion to oxygen combustion was investigated. At this time, it was found that the temperature distribution in air combustion and oxygen combustion showed a similar pattern, but the pressure distribution was lower in oxygen combustion. addition, since it has a higher CO2 concentration in oxygen combustion than in air combustion, it can be expected that carbon dioxide capture will take place actively. As a result, it was confirmed that this study can contribute to the optimized design and operation of a circulating fluidized bed reactor using anthracite.

Absorption, Excretion and Antioxidative Effect of Rebamipide on Reproductive Organ (Rebamipide의 생식기관 내 흡수, 배설 및 항산화제로서 불임치료효과)

  • Kim, Jong Il;Park, Hyun Jun;Park, Nam Cheol
    • Clinical and Experimental Reproductive Medicine
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    • v.32 no.4
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    • pp.301-314
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    • 2005
  • Objective: Rebamipide is a propionic acid derivative that has an action of the inhibition of superoxide production and removal of hydroxyl radical with the sperm incubation and cryopreservation. In the present study, to investigate whether rebamipide is useful to treat male infertility and sterility, the author observed the antioxidative effects in patient with male infertility and also examined its absorption and distribution in rat genital organ. Methods: To measure the distribution of rebamipide in reproductive organ in the rat, carbon indicated rebamipide, $^{14}C-OPC-12759$, was orally administered to 10 Spraque-Dawley rats and its organ concentration in serum, liver, kidney, stomach, duodenum, colon, urinary bladder, seminal vesicle, epididymis and testicle were measured each time after 0.5, 1, 2, 4, 8 and 24 hours by using HPLC fluorescent method. The concentrations in semen were measured by HPLC fluorescent method in a sample of 50 infertile males who took 900 mg of rebamipide daily for 3 months. To measure the antioxidative effect and fertility rate for 3 months, each month before and after the treatment, sperm motility, vitality, the oxygen free radical formation, level of peroxidation, fetilizing capacity of semen sample which were obtained from infertile male patients by masturbation after at least 48 hours abstinence were analyzed by computer assisted semen analyzer, eosin-nigrosin stain, chemiluminescence, thiobarbituric acid method and hypo-osmotic swelling test. Simultaneously in a sample that wanted baby, both pregnancy and delivery were researched. Results: The $^{14}C-OPC-12759$ concentration in the body of white rats was highest in gastrointestinal organ like stomach, smal intestine and duodenum and followed by genital organ like seminal vesicle, testis and epididymis. The rebamipide concentration in semen of infertile males was $220.77{\pm}327.84ng/mL$ (SD) which showed a large deviation but it was higher than serum which was $126{\pm}76ng/mL$ (SD). In the infertile males, after the treatment with rebamipide, the level of seminal reactive oxygen species (ROS) and lipid peroxidation have significantly decreased in duration of the treatment (p<0.05) and sperm vitality and fertilizing capacity except sperm motility significantly improved on post treatment of 2~3 months (p<0.05). Out of the 41 cases who hoped for pregnancy, 15 cases (36.6%) became pregnant and 12 cases had childbrith, 2 cases had miscarriage and one case is ongoing. The side effect was observed in 1 case (2%) which experienced diarrhea but it was lost spontaneously. Conclusions: We conclude from this study that rebamipide showed relatively high tendancy of absorption and excretion in the genital organ. In infertile males who had elevated ROS in semen, by specifically inhibiting the cell damage from the antioxidation, a way to preserve sperm motility, vitality and fertilizing capacity was confirmed.

Nitrite Removal by Autotrophic Denitrification Using Sulfur Particles (황입자를 이용한 독립영양탈질에서의 아질산성질소 탈질 조건 탐색)

  • Kang, Woo-Chang;Oh, Sang-Eun
    • Korean Journal of Environmental Agriculture
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    • v.29 no.3
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    • pp.221-226
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    • 2010
  • Swine wastewater contains high amounts of organic matter and nutrients (nitrogen and phosphorus). The biological nitrogen removal can be achieved by nitrification and denitrification processes. Nitrification-denitrification can be performed via nitrite which is called as the short-cut process. This Short-cut process saves up to 25% of oxygen and 40% of external carbon during nitrification and denitrification. In this study, the batch tests were conducted to assess the different parameters for the nitrite sulfur utilizing denitrification, such as alkalinity, temperature, initial nitrite concentration, and dissolved oxygen. The experimental results showed that the nitrite removal efficiency of the reactor was found to be over 95% under the optimum condition ($30^{\circ}C$ and sufficient alkalinity). Autotrophic nitrate denitrification was inhibited at low alkalinity condition showing only 10% removal efficiency, while nitrite denitrification was achieved over 95%. The nitrite removal rates were found similar at both $20^{\circ}C$ and $30^{\circ}C$. In addition, nitrite removal efficiencies were inhibited by increasing oxygen concentration, but sulfate concentration increased due to sulfur oxidation under an aerobic condition. Sulfate production and alkalinity consumption were decreased with nitrite compared those with nitrate.

Preliminary Study on the Reproduction of Dissolved Oxygen Concentration in Jinhae Bay Based on Deep Learning Model (딥러닝 모형 기반 진해만 용존산소농도 재현을 위한 기초연구)

  • Park, Seongsik;Kim, Kyunghoi
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.2
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    • pp.193-200
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    • 2022
  • We conducted a case study to determine the optimal model parameters and predictors of Long Short-Term Memory (LSTM) for the reproduction of dissolved oxygen (DO) concentration in Jinhae Bay. The model parameter case study indicated the lowest accuracy when the Hidden node=10, Epoch=100. This was caused by underfitting of machine learning. The accuracy increased as the Hidden node and Epoch increased. The accuracy was the highest when the Hidden node=80 and Epoch=100 with R2=0.99. In the bottom DO reproduction of Step 1 of the predictors case study, accuracy was highest when the water temperature was used as a predictor with R2=0.81. In Step 2, The R2 value increased up to 0.92 when the water temperature and SiO2 were used as a predictor. This was caused by a high correlation between the bottom DO and SiO2 concentrations. Consequently, we determined the optimal model parameters and predictors of LSTM for the reproduction of DO concentration in Jinhae Bay.

A Study on the Distribution Characteristics of Nitrite Oxidizing Bacteria in Wastewater Nitrification Systems (폐수 질산화 시스템에서 아질산 산화 미생물의 분포 특성 연구)

  • Kim, Sun-Hee;Kim, Dong-Jin;Yoo, Ik-Keun;Cha, Gi-Cheol
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.10
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    • pp.1024-1030
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    • 2006
  • Genus Nitrospira and Nitrobacter species are the key nitrite-oxidizing bacteria(NOB) in nitrifying wastewater treatment plants. It has been hypothesized that genus Nitrospira are K-strategists(low $K_6$ value) that can exploit low amounts of nitrite more efficiently than Nitrobacter. In contrast, Nitrobacter species are r-strategists(high $V_{max}$) that can grow faster than Nitrospira. It has also been known that the availability of organic compounds and dissolved oxygen as well as nitrite affects the distribution of NOB. In this study, we determined the distribution and competition of NOB in wastewater nitrification systems where nitrite, organic compounds, and dissolved oxygen concentrations were compositively varied. For the purpose, several compounds of the laboratory-scale nitrificaiion bioreactor and full-scale $A_2O$ wastewater treatment plant and their distribution of NOB were analyzed and compared. The analysis showed that Nitrobacter was the dominant NOB in nitrification bioreactor where average nitrite was maintained at 5 mg-N/L with very low organic concentration in aerobic condition, whereas Nitrospira was the dominant NOB in full-scale $A_2O$ plant where nitrite was maintained very low and organic compounds were maintained relatively high in alternating aerobic-anoxic condition. The result indicates that nitrite concentration is more critical factor than organics and dissolved oxygen which determines the dominant NOB in nitrification system and it is confirmed that Nitrospira and Nitrobacter showed the characteristics of r-strategist and K-strategist, respectively.