• Title/Summary/Keyword: High-Concentration Electrolyte

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Emulsion stability of cosmetic creams based on water-in-oil high internal phase emulsions

  • Park, Chan-Ik;Cho, Wan-Gu;Lee, Seong-Jae
    • Korea-Australia Rheology Journal
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    • v.15 no.3
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    • pp.125-130
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    • 2003
  • The emulsion stability of cosmetic creams based on the water-in-oil (W/O) high internal phase emulsions (HIPEs) containing water, squalane oil and cetyl dimethicone copolyol was investigated with various compositional changes, such as electrolyte concentration, oil polarity and water phase volume fraction. The rheological consistency was mainly destroyed by the coalescence of the deformed water droplets. The slope change of complex modulus versus water phase volume fraction monitored in the linear viscoelastic region could be explained with the resistance to coalescence of the deformed interfacial film of water droplets in concentrated W/O emulsions: the greater the increase of complex modulus was, the more the coalescence occurred and the less consistent the emulsions were. Emulsion stability was dependent on the addition of electrolyte to the water phase. Increasing the electrolyte concentration increased the refractive index of the water phase, and thus decreased the refractive index difference between oil and water phases. This decreased the attractive force between water droplets, which resulted in reducing the coalescence of droplets and increasing the stability of emulsions. Increasing the oil polarity tended to increase emulsion consistency, but did not show clear difference in cream hardness among the emulsions.

계면활성제와 동전기 기술을 이용한 오염토양정화에서 APG사용의 타당성에 관한 연구

  • 양지원;이유진;박지연;김상준
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.243-246
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    • 2002
  • Surfactant-enhanced electrokinetic remediation is an emerging technology that can effectively remove hydrocarbons from low-permeability soils. In this study, the electrokinetic remediation using APG(alkyl polyglucoside) was conducted for the removal of phenanthrene from kaolinite. APG, which was an environmentally compatible and non-toxic surfactant, was used at concentrations of 5, 15, and 30g/1 to enhance the solubility of phenanthrene. Also an electrolyte solution was used for considering a relation between electrical potential gradient and removal efficiency of phenanthrene. When the electrolyte solution was used, it represented low electrical potential gradient, but the removal efficiency was lower than that of no electrolyte system. Removal efficiency of phenanthrene in EK process using surfactant solution depended on concentration of surfactant. Because surfactant increased the solubility and the mobility of phenanthrene, when surfactant concentration was high, high removal efficiency was observed.

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Effect of Sodium Aluminate Concentration in Electrolyte on the Properties of Anodic Films Formed on AZ31 Mg Alloy by Plasma Electrolytic Oxidation (AZ31 마그네슘 합금의 플라즈마 전해 산화에서 Sodium Aluminate 농도가 산화막 특성에 미치는 영향)

  • Lee, Jong-Seok;Baek, Hong-Gu;Kim, Sung-Wan
    • Journal of the Korean Society for Heat Treatment
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    • v.25 no.5
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    • pp.227-232
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    • 2012
  • Magnesium alloy have good physical properties such as good castability, good vibration absorption, high strength/weight ratios. Despite the desirable properties, the poor resistance of Mg alloy impedes their use in many various applications. Therefore, magnesium alloy require surface treatment to improve hardness, corrosion and wear resistance. Plasma Electrolytic Oxidation (PEO) is one the surface treatment methods to form oxide layer on Mg alloy in alkali electrolyte. In comparison with Anodizing, there is environmental process having higher hardness and faster deposition rate. In this study, the characteristics of oxide film were examined after coating the AZ31 Mg alloy through the PEO process. We changed concentration of sodium aluminate into $K_2ZrF_6$, KF base electrolyte. The morphologies of the coating layer were characterized by using scanning electron microscopy (SEM). Corrosion resistance also investigated by potentiodynamic polarization analysis. As a result, propertiy of oxide layer were changed by concentration of sodium aluminate. Increasing with concentration of sodium aluminate in electrolyte, the oxidation layer was denser and the pore size was smaller on the surface.

The Dispersion Stability of $\alpha-Fe_2O_3$ Particulate Soil in the Anionic/Nonionic Mixed Surfactant Solution (음/비이온계 혼합계면활성제 용액에서 $\alpha-Fe_2O_3$ 입자의 분산안정성)

  • 정선영;강인숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.6
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    • pp.854-861
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    • 2004
  • To estimate dispersion stability of particles in anionic and nonionic surfactant mixed solution, suspending power was examined as functions of duration time of suspension, ionic and nonionic surfactant mixed ratio, surfactant concentration, kinds of electrolyte, ionic strength and mole numbers of oxyethylene additions to nonionic surfactant using $\alpha$-Fe$_2$O$_3$ particle as the model of particulate soil. The suspending power of anionic and nonionic surfactant mixed solution was relatively higher than that of anionic and nonionic surfactant single solution regardless of solution concentration. The suspending power was gradually decreased with increasing duration time of suspension. In the absence of electrolyte, the effect of surfactant concentration on suspending power was small but in solution with electrolyte, suspending power was lowest at 1 % surfactant concentration. With 1${\times}$10$^{-3}$ ionic strength and polyanionic electrolyte in solution, the suspending power was high but effects of oxyethylene mole number to nonionic surfactant on suspending power was small. Generally the suspending power was gradually increased with decreasing the particle size. Hence the suspending power was inversely related to the particle size.

Studies on the Detergency of Particulate Soil using Vacuum Cleaner Dirt as Model (진공청소기 분진을 모델로 한 고형오염의 세척성에 관한 연구)

  • Kang In-Sook;Kim Sung-Reon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.3 s.31
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    • pp.286-294
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    • 1989
  • This Study has treated the effects of fiber, surfactants, temperature, surfactant concentration, pH, electrolyte, fatty acid contents and mechanical force on the removal of particulate soil from fabric, vacuum cleaner dirt was used as model particulate soil. The fabrics were soiled with mixture of vacuum cleaner dirt and fatty soil, and washed in Terg-O-tometer. The detergency was evaluated by measuring reflectance of a fabric before and after washing. The results were as follows. 1. The fiber type showed a different pattern of soil removal with surfactants. In general, particulate soil removal increased in the following order Acetate>PET. Nylon>Cotton. Particulate soil removal, which is affected by the surfactant type, increased in the following order NPE $(EO)_{10}\leqq$Soap>SLS>DBS>Tween 80. 2. The influence of temperature on the particulate soil removal was very complex because efficiency of removal was varied with surfactant and fiber types. The washing efficiency of NPE $(EO)_{10}$ was highest at around $40^{\circ}C\;and\;60^{\circ}C$ with cotton and PET but the washing efficiency of DBS was the highest at $60^{\circ}C$ with cotton, decreased monotonously with increasing temperature with PET 3. The detergency of particulate soil increased with increasing surfactant concentration at relatively low concentration and then levelled off above some optimum concentration. 4. The removal of particulate soil increased with increasing pH and mechanical force. 5. Effect of electrolyte on the particulate soil removal was depended on the concentration of the surfactant. At low concentration of surfactant, addition of electrolytes improved soil removal but above the some concentration no effect was observed. At high concentration of surfactant, Vie., $0.6\%$ , the maximum washing effect is reached without added electrolyte. These result indicate that added electrolyte only influence the adsorption of surfactant on the soil and fiber 6. Fatty acid content in the soil did not influence on particulate soil removal without regard to surfactants.

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Reaction Behavior of Ceramic Mat with Lithium Salt for the Electrolyte Separators of Thermal Batteries (전해질 분리판용 세라믹 부직포와 리튬염간의 반응성)

  • Cho, Kwang-Youn;Riu, Doh-Hyung;Shin, Dong-Geun;Lim, Kyoung-Hoon;Jin, Eun-Ju;Kim, Hyoun-Ee;Ha, Sang-Hyeon;Choi, Jong-Hwa
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.587-591
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    • 2009
  • Lithium salt have been used mainly as electrolyte of thermal battery for electricity storage. Recently, The 3phase lithium salt(LiCl-LiF-LiBr) is tried to use as electrolyte of thermal battery for high electric power. It is reported that LiCl-LiF-LiBr salt have high ion mobility due to its high lithium ion concentration. Solid lithium salt is melt to liquid state at above $500{^{\circ}C}$. The lithium ion is easily reacted with support materials. Because the melted lithium ion has small ion size and high ion mobility. For the increasing mechanical strength of electrolyte pellet, the research was started to apply ceramic filter to support of electrolyte. In this study, authors used SiOC web and glass fiber filter as ceramic mat for support of electrolyte and impregnated LiCl-LiF-LiBr salt into ceramic mat at above $500{^{\circ}C}$. The fabricated electrolyte using ceramic mat was washed with distilled water for removing lithium salt on ceramic mat. The washed ceramic mat was observed for lithium ion reaction behavior with XRD, SEM-EDS and so on.

Characteristic Evaluation of Anodic Film Depending on the Concentration of Sodium Silicate in the Electrolyte Anodized AZ31B Magnesium Alloy (전해액 중 Sodium silicate의 농도에 따라 양극 산화된 AZ31B 마그네슘 합금 양극 피막의 특성 평가)

  • Lee, Dong-Kil;Kim, Yong-Hwan;Park, Hyun;Jung, Uoo-Chang;Chung, Won-Sub
    • Journal of Surface Science and Engineering
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    • v.42 no.3
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    • pp.109-115
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    • 2009
  • Magnesium is one of the lightest metals, and magnesium alloys have excellent physical and mechanical properties such as high stiffness/weight ratios, good castability, good vibration and shock absorption. However their poor corrosion resistance, wear resistance, hardness and so on, have limited their application. To improve these defects, many techniques are developed. Micro arc oxidation(MAO) is a one of the surface treatments under anodic oxidation in which ceramic coating is directly formed on the surface of magnesium alloy. In this study, the characteristics of anodic film were examined after coating the AZ31B magnesium alloy through the MAO process. MAO was carried out in potassium hydroxide, potassium fluoride, and various concentration of sodium silicate in electrolyte. The morphology and chemical composition of the coating layer were characterized by SEM, XRD, EPMA and EDS. The hardness of anodic films was measured by micro-vickers hardness tester. As a result, the morphology and composition of anodic film were changed by concentration of sodium silicate. Thickness and Si composition of anodic film was increased with increasing concentration of sodium silicate in electrolyte. The hardness of anodic film was highly increased when the concentration of sodium silicate was above 40 g/l in electrolyte.

A Study on Measuring Electrical Capacitance to Access the Volumetric Water Content of Simulated Soil

  • Rial, W.S.;Han, Y.J.
    • Agricultural and Biosystems Engineering
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    • v.1 no.1
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    • pp.30-37
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    • 2000
  • Wet porous media representing agronomic soil that contains variable water content with variable electrolyte concentration was measured to study the shape of the curves of the electric double layer capacitance versus frequency (from 10 KHz to 10 MHz. This was done in an attempt to find the lowest practical operating frequency for developing low cost dielectric constant soil moisture probes. Cellulose sponge was used as the porous media. A high frequency electronic bridge circuit was developed for measuring the equivalent network parallel resistance and capacitance of porous media. It appears that the effects of the electric double layer component of the total parallel network capacitance essentially disappear at operating frequencies greater than approximately 25 MHz at low electrolyte concentrations but are still important at 50 MHz at higher concentrations. At these frequencies, the double layer capacitance masks the diffusion region capacitance where true water content capacitance values reside. The general shape of the curve of volumetric water content versus porous media dielectric constant is presented, with an empirical equation representing data for this type of curve. It was concluded that the lowest frequency where dielectric constant values which represent true water content information will most likely be found is between 30 and 50 MHz at low electrolyte concentrations but may be above 50 MHz when the total electrolyte concentration is near the upper level required for most mesophyte plant nutrition.

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Influences of Various Electrolytes on the Low-Temperature Characteristics of Ni-MH Secondary Battery (Ni-MH 2차 전지의 저온특성에 미치는 전해액의 영향)

  • Park, Chae-Gyu;Shim, Jong-Su;Jang, Min-Ho;Park, Choong-Nyeon;Choi, Jeon
    • Journal of Hydrogen and New Energy
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    • v.18 no.3
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    • pp.284-291
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    • 2007
  • The Ni-MH batteries for HEV and industry are normally placed in outdoor, consequently causing an too weak discharge power problem due to a cold weather specially in winter time. In order to improve the low temperature performances of the Ni-MH battery for HEV and industrial uses, it has been investigated the low temperature discharge characteristics of Ni-MH battery with various electrolytes at $-18^{\circ}C$. The summary of experimental results are as follows. The low temperature characteristics depended strongly on the characteristics of electrolytes. When the concentration of the electrolytes were too high or too low the low temperature performance was poor. The best electrolyte was composed of KOH 6.2M+LiOH 1.2M. An addition of RbOH or CsOH to electrolyte improved the low temperature performance. The best total concentration of electrolyte composed of KOH, NaOH and LiOH was about 7M.

Decolorization of a Rhodamine B Using Ru-graphite Electrode (Ru-흑연 전극을 이용한 Rhodamine B의 색 제거)

  • Park, Young-Seek
    • Journal of Environmental Science International
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    • v.17 no.5
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    • pp.547-553
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    • 2008
  • For the RhB removal from the wastewater, electrochemical method was adapted to this study. Three dimensionally stable anode (Pt, Ir and Ru) and graphite and Ru cathode were used. In order to identify decolorization, the effects of electrode, current density, electrolyte and air flow rate were investigated. The effects of electrode material, current, electrolyte concentration and air flow rate were investigated on the decolorization of RhB. Electro-Fenton's reaction was evaluated by added $Fe^{2+}$ and $H_2O_2$ generated by the graphite cathode. Performance for RhB decolorization of the four electrode systems lay in: Ru-graphite > Ru-Ru > Ir-graphite > Pt-graphite. A complete color removal was obtained for RhB (30 mg/L) at the end of 30 min of electrolysis under optimum operations of 2 g/L NaCl concentration and 2 A current. $Fe^{2+}$ addition increased initial reaction and decreased final RhB concentration. However the effect was not high.