• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 추계학술대회 논문집
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• pp.149-149
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• 2009

Generally, Nafion ionomer is used in the polymer electrolyte fuel cell (PEFC) electrodes to achieve high power density. At the high temperature operation of PEFC, however, ionic conductivity of Nafion remarkably decreased due to the evaporation of water in Nafion polymer. Recently, many researchers have focused on using the Ionic Liquids(ILs) instead of water in Nafion polymer. ILs have intrinsic properties such as good electrochemical stability, high ionic conductivity, and non-flammability. Especially, ILs play a crucial role in proton conduction by the Grottuss mechanism and act as water in water-free Nafion polymer. However, it was found that the ILs was leached out of the polymer matrix easily. In this study, we prepared membrane electrode assemblies with various contents of ILs. The effect of ILs in the electrode of each designed was investigated by a cyclic voltammetry measurement and the cell performance obtained through a single cell test using H2/Air gases. Electrodes with different contents of ILs in catalyst layer were examined at high temperature and low humidified condition.

• 한국압력기기공학회 논문집
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• 제16권1호
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• pp.22-29
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• 2020

In nuclear power plants, there is a risk of thermal fatigue in equipment and piping affecting system soundness because the temperature change of the system accompanies in every operation and shutdown. Therefore, in order to prevent the excess of the fatigue limit during the lifetime of plants, the fatigue limit of each piping material is determined in the designing stage. However, there are many cases where equipment or piping is locally subjected to thermal fatigue that is not considered in the design, resulting in damage to the equipment and piping, and failure during operation. Currently, local thermal fatigue generation mechanisms that are not taken into account in the design stage are gradually being identified. In this paper, the effects of the fluid temperature fluctuations on the piping soundness due to the mixing of hot and cold water, one of the local thermal fatigue generating mechanisms, were evaluated.

• 한국수소및신에너지학회논문집
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• 제19권3호
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• pp.232-238
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• 2008

Research has been proceeded on fuel cell which is fueled by hydrogen. Polymer electrolyte membrane fuel cell (PEMFC) is promising power source due to high power density, simple construction and operation at low temperature. But it has problems such as high cost, temperature dependent performance. These problems could be solved by experiment which is useful for analysis and optimization of fuel cell performance and heat management. In this paper, when hydrogen flows constantly at the stoichiometry of ${\xi}=1.6$, the performance of the fuel cell stack was increased and the voltage difference between each cells was decreased according to the increase of air stoichiometry by 2.0, 2.5, 3.0. Therefore, the control of air flow rate in the same gas channel is important to get higher performance. Purpose of this research is to expect operation temperature, flow rate, performance and mass transportation through experiment and to help actual manufacture of PEM fuel cell stack.

• 설비공학논문집
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• 제13권1호
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• pp.48-58
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• 2001

For the past few decades the vapor compression cycle with a solution circuit (VCCSC) has been known to provide high efficiency and variable capacity. In this study performance of a VCCSC cycle is examined through computer simulation. In the simulation heat exchangers were modelled by specifying UA or effectiveness values while the compressor performance was specified by an isentropic efficiency. Aqua/ammonia solution was chosen as the working fluid which can be used in the high temperature range. The results show that there exists an optimum operation condition which is dependent upon the temperatures of the external heat transfer fluids(HTFs). Besides the HTF\`s temperature, the maximum system pressure and the size of the solution heat exchanger are shown to have an influence on the optimum operation condition. Finally, as compared to a simple vapor compression heat pump with HFC134a, the COP of the VCCSC is shown to be 2∼22% higher.

• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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• pp.504-510
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• 2003

This study has been carried out to evaluate the passive treatment systems for acid mine drainage in Korea and to suggest, if possible, the method for the improvement. 35 passive treatment systems in 27 mines have been constructed since 1996. SAPS, being the main process, was combined with more than one of processes such as anaerobic wetland, aerobic wetland, and oxidation pond for the construction of passive treatment system. Problems observed during the operation include the poor sulfate removal ratio, overflow, leakage, unusabless of the whole system, and inefficiency. The reasons of the poor sulfate removal ratio are believed that the low temperature during the winter prohibits the SRB activity and HRT for bacterial sulfate reduction is insufficient. An alternative method In Adit Sulfate Reducing System which enables to keep the temperature constant at about $15^{\circ}C$ was suggested. IASRS is the methods of placing the SAPS inside the adit, which enables the temperature around the system constant can be maintained. The experiments using the laboratory scaled model systems made up of four sections showed high efficiencies in pH control and metal removal ratios, but showed still low sulfate removal ratio of about $23\%$ also with high COD at the beginning of the operation.

• 한국초전도ㆍ저온공학회논문지
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• 제13권4호
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• pp.10-13
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• 2011

For the operation of high temperature superconducting (HTS) power equipments, it is necessary to develop insulating materials and high voltage (HV) insulation technology at cryogenic temperature of bushing. In this paper, the surface flashover characteristics of various insulating materials in $LN_2$ are studied. These results are studied at both AC and impulse voltage under a non-uniform field. The negative impulse breakdown voltage of GFRP is slightly higher than the positive impulse breakdown voltage. The use of glass fiber reinforced plastic (GFRP) and polytetrafluoroethylene (PTFE, Teflon) as insulation body for HTS bushing should be much desirable. Especially, GFRP is excellent material not only surface flashover characteristics but also mechanical characteristics at cryogenic temperature. The surface flashover is most serious problem for the shed design in $LN_2$ and operation of superconducting equipment.

• Nuclear Engineering and Technology
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• 제28권3호
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• pp.257-264
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• 1996

The conventional Equipment Environment Qualification (EEQ) envelope is developed based on the containment responses during the design basis events. The Safety Depressurization System (SDS) design without In-containment Refueling Water Storage Tank (IRWST) adopted in the Ulchin 3&4 challenges the conventional EEQ envelope during long term Feed and Bleed (F&B) operation due to the direct discharge of high mass and energy into the containment. Therefore, it is necessary to confirm that the containment pressure and temperature history during the long term F&B operation does not violate the conventional EEQ envelope. However, this subject has never been quantitatively assessed before. To investigate the success path of long term F&B operation this paper analyzes the thermal hydraulic response of the containment and Reactor Coolant System (RCS) until the completion of depressurization and cooldown of RCS into Shutdown Cooling System (SCS) entry condition. It is found that the SCS entry condition can be reached within 6 hours without violating the EEQ curve by proper operation of SDS valves, High Pressure Safety Injection (HPSI) pumps and active Containment Heat Removal System (CHRS). The suggested strategy not only demonstrates the feasibility of long term F&B operation but also can be utilized in the preparation of Emergency Procedure Guidelines (EPGs)

• Nuclear Engineering and Technology
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• 제51권7호
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• pp.1738-1748
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• 2019

Previous research has shown that the inclined condition has an impact on the natural circulation (natural circulation) mode operation of Floating Nuclear Power Plant (FNPP) mounted on the movable marine platform. Due to its compact structure, small volume, strong maneuverability, the Integral Pressurized Water Reactor (IPWR) is adopted as marine reactor in general. The OTSGs of IPWR are symmetrically arranged in the annular region between the reactor vessel and core support barrel in this paper. Therefore, many parallel natural circulation loops are built between the core and the OTSGs primary side when the main pump is stopped. and the inclined condition would lead to discrepancies of the natural circulation drive head among the OTSGs in different locations. In addition, the flow rate and temperature nonuniform distribution of the core caused by inclined condition are coupled with the thermal hydraulics parameters maldistribution caused by OTSG group operating mode on low power operation. By means of the RELAP5 codes were modified by adding module calculating the effect of inclined, heaving and rolling condition, the simulation model of IPWR in inclined condition was built. Using the models developed, the influences on natural circulation operation by inclined angle and OTSG position, the transitions between forced circulation (forced circulation) and natural circulation and the effect on natural circulation operation by different OTSG grouping situations in inclined condition were analyzed. It was observed that a larger inclined angle results the temperature of the core outlet is too high and the OTSG superheat steam is insufficient in natural circulation mode operation. In general, the inclined angle is smaller unless the hull is destroyed seriously or the platform overturn in the ocean. In consequence, the results indicated that the IPWR in the movable marine platform in natural circulation mode operation is safety. Selecting an appropriate average temperature setting value or operating the uplifted OTSG group individually is able to reduce the influence on natural circulation flow of IPWR by inclined condition.

• 한국가시화정보학회지
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• 제19권1호
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• pp.62-67
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• 2021

Selective catalytic reduction(SCR) is an exhaust gas reduction device to remove nitro oxides (NOx). SCR operation of ship can be controlled through valves for minimizing economic loss from SCR. Valve in SCR-high pressure (HP) system is directly connected to engine exhaust and operates in high temperature and high pressure. Long-term thermal deformation induced by engine heat weakens the sealing of the valve, which can lead to unexpected failures during ship sailing. In order to prevent the unexpected failures due to long-term valve thermal deformation, a failure prediction system using autoregressive integrated moving average (ARIMA) was proposed. Based on the heating experiment, virtual data mimicking temperature range around the SCR-HP valve were produced. By detecting abnormal temperature rise and fall based on the short-term ARIMA prediction, an algorithm determines whether present temperature data is required for failure prediction. The signal processed by the data collection algorithm was interpolated for the failure prediction. By comparing mean average error (MAE) and root mean square error (RMSE), ARIMA model and suitable prediction instant were determined.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.147-147
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• 2010

An electrolyte membranes for high temperature/low humidity is a demand for the proton exchange membrane fuel cells (PEMFCs). In this work, we prepared hybrid membranes, which have novel glass content in the hydrophilic and hydrophobic part of sulfonated poly(arylene ether sulfone) (SPAES) by in-situ sol-gel synthesis of various functional silane. The effect of silicate from functional silane content on the proton conductivity, water uptake of the hybrid membranes under high temperature and low humidity was quantitatively identified. The silicate content contributed to the enhancement of not only proton conductivity, but also water retention ability for PEMFCs operation.