• Composites Research
• /
• v.35 no.6
• /
• pp.425-430
• /
• 2022

In this study, the mechanical properties of the pressure vessel composite exposed to the thermal environment were evaluated to establish the standard for high temperature static pressure test of the pressure vessel for hydrogen bus. As the tensile strength of the composite material approaches the glass transition temperature of the epoxy resin, the strength decreases due to the deterioration of the epoxy resin. In addition, it was confirmed that the tensile strength increased again due to the post-curing of the epoxy resin during long-term exposure. Therefore, the accelerated stress rupture test conditions of the pressure vessel for the hydrogen bus should be set based on the epoxy resin properties of the carbon fiber composite material.

• Korean Journal of Materials Research
• /
• v.4 no.3
• /
• pp.287-294
• /
• 1994

PAN-based carbon fiber roving and fabric were heat treated at the temperature of $2170^{\circ}C$. Using non-heat treated and heat treated fabric, greenbodies of CFRP and GFRP were manufactured in the Autoclave. After the analysis of heat treated and non-heat treated carbon fiber roving and two types of greenbodies, the variations of physical and mechanical properties of carbon fibers and greenbodies with heat treatment were studied. Observing the cross-section of carbon fiber with SEM, we knew the diameter of carbon fiber was decreased from 6.8gm to 6.4p1. The results of TGA showed that the oxidation resistence was enhanced after heat treatment. The tensile strength of carbon fiber was decreased from (3.11$\pm 0.32)\times 10^3$ MPa to (1.87$\pm 0.26)\times 10^3$MPa, but tensile modulus was increased from (1.94$\pm 0.06)\times 10^5$ MPa to (2.02$\pm 0.11)\times 10^5$MPa after heat treatment. The interlaminar shear strengths of CFRP and GFRP were 148.8$\pm$1.6Mpa and 82.2$\pm$1.1Mpa, respectively. Torch test showed that CFRP was abraded smoothly but GFRP was delaminated.

• Journal of Surface Science and Engineering
• /
• v.57 no.4
• /
• pp.317-324
• /
• 2024

We demonstrate a direct growth of carbon nanotubes (CNTs) on the surface of LiFePO₄ (LFP) powders for use in lithium-ion batteries (LIB). LFP has been widely used as a cathode material due to its low cost and high stability. However, there is a still enough room for development to overcome its low energy density and electrical conductivity. In this study, we fabricated novel structured composites of LFP and CNTs (LFP-CNTs) and characterized the electrochemical properties of LIB. The composites were prepared by direct growth of CNTs on the surface of LFP using a rotary chemical vapor deposition. The growth temperature and rotation speed of the chamber were optimized at 600 ℃ and 5 rpm, respectively. For the LIB cell fabrication, a half-cell was fabricated using polytetrafluoroethylene (PTFE) and carbon black as binder and conductive additives, respectively. The electrochemical properties of LIBs using commercial carbon-coated LFP (LFP/C), LFP with CNTs grown for 10 (LFP/CNTs-10m) and 30 min(LFP/CNTs-30m) are comparatively investigated. For example, after the formation cycle, we obtained 149.3, 160.1, and 175.0 mAh/g for LFP/C, LFP/CNTs-10m, and LFP/CNTs-30m, respectively. In addition, the improved rate performance and 111.9 mAh/g capacity at 2C rate were achieved from the LFP/CNTs-30m sample compared to the LFP/CNTs-10m and LFP/C samples. We believe that the approach using direct growth of CNTs on LFP particles provides straightforward solution to improve the conductivity in the LFP-based electrode by constructing conduction pathways.

• Korean Journal of Materials Research
• /
• v.20 no.5
• /
• pp.246-251
• /
• 2010

The composite photocatalysts of a Fe-modified carbon nanotube (CNT)-$TiO_2$ were synthesized by a two-step sol-gel method at high temperature. Its chemical composition and surface properties were investigated by BET surface area, scanning electron microscope (SEM), Transmission Electron Microscope (TEM), X-ray diffraction (XRD) and ultraviolet-visible (UV-Vis) spectroscopy. The results showed that the BET surface area was improved by modification of Fe, which was related to the adsorption capacity for each composite. Interesting thin layer aggregates of nanosized $TiO_2$ were observed from TEM images, probably stabilized by the presence of CNT, and the surface and structural characterization of the samples was carried out. The XRD results showed that the Fe/CNT-$TiO_2$ composites contained a mix of anatase and rutile forms of $TiO_2$ particles when the precursor is $TiOSO_4{\cdot}xH_2O$ (TOS). An excellent photocatalytic activity of Fe/CNT-$TiO_2$ was obtained for the degradation of methylene blue (MB) under visible light irradiation. It was considered that Fe cation could be doped into the matrix of $TiO_2$, which could hinder the recombination rate of the excited electrons/holes. The photocatalytic activity of the composites was also found to depend on the presence of CNT. The synergistic effects among the Fe, CNT and $TiO_2$ components were responsible for improving the visible light photocatalytic activity.

• Environmental Engineering Research
• /
• v.23 no.3
• /
• pp.250-257
• /
• 2018

We developed new composites by combining the solid waste from Low-Density Polyethylene in the form of plastic bag (PB) and biomass from rice husk (RH),in the form of $(RH)_x(PB)_{1-x}$ (x = (1, 0.9, 0.7, 0.5)), as alternative fuels for electrical energy sources, and for providing the best solution to reduce environmental pollution. Elemental compositions were obtained by using proximate analysis, ultimate analysis, and X-ray fluorescence spectroscopy, and the thermal characteristics were obtained from thermogravimetric analysis. The compositions of carbon and hydrogen from the ultimate analysis show significant increases of 20-30% with increasing PB in the composite. The activation energy for RH is 101.22 kJ/mol; for x = 0.9 and 0.7, this increases by 4 and 6 magnitude, respectively, and for x = 0.5, shows remarkable increase to 165.30 kJ/mol. The range of temperature of about $480-660^{\circ}C$ is required for combustion of the composites $(RH)_x(PB)_{1-x}$ (x = (1, 0.9, 0.7, 0.5)) to perform the complete combustion process and produce high energy. In addition, the calorific value was determined by using bomb calorimetry, and shows value for RH of 13.44 MJ/kg, which increases about 30-40% with increasing PB content, indicating that PB has a strong effect of increasing the energy realized to generate electricity.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.5 no.4
• /
• pp.1-11
• /
• 2001

A theory for time-dependent, high temperature ablation of poroelastic carbon composite insulators is applied using finite element methods to determine material properties from experimental data. The theory contains important revisions to that in Lee, Salamon and Sullivan[1] by making a sharp distinction between Biots constants and permeability and setting both to analytical functions of porosity. The finite element program and material modeling has been modified to (1) more closely adhere to porous-material theory, (2) include a newly discovered analytical simplification and (3) refine the material property descriptions. Application to experimental problems and comparisons with data permit determination of Biots constants and permeability and their evolution with respect to matrix decomposition and clearly show how material parameters affect the material response, e.g., amplitude and the location of peaks with respect to temperature. In particular, the response is very sensitive to permeability and dominated by it.

• Korean Journal of Materials Research
• /
• v.4 no.2
• /
• pp.194-205
• /
• 1994

In this research, we attempt to fabricate an excellent CFRC(Carbon Fiber Reinforced Carbon), which has good thermal and mechanical properties, with 8H/satin woven fabric prepreg, high modulus and high strength type continuous carbon fiber and raw coal tar pitch(RCTP) matrix or THF soluble fraction(THFSP) matrix which has good graphitizability. Green bodies were fabricated with hot press molding technique and CFRC samples were made after carbonization, impregnation, recarbonization and graphitization steps. For the purpose of characterization of the physical properties, SEM, polarized light microscope, TGA were observed, and tested flexural strength, modulus and ILSS. After heat treating the THFSP matrix up to $2300^{\circ}C$, the value of $C_0$/2 was 3.380$\AA$, which is analogous to the structure of natural graphite and the value of 2$\theta$ is $26.276^{\circ}$ approached to the Bragg's angle of natural graphite. As a result of TGA to test the high temperature air oxidation, the THFSP matrix, graphitized up to $2300^{\circ}C$, exhibited the best air oxidation resistance. And mechanical properties were increased up to 65~70% as fiber volume fraction increased. Because of the good orientation graphitizability, the fracture surface of THFSP matrix CFRC is very good.

• Composites Research
• /
• v.24 no.4
• /
• pp.48-54
• /
• 2011

The effect of moisture contents by salt water on the strength of composite single-lap bonded joints is investigated. The specimens were manufactured in an autoclave by secondary bonding and immersed in the 3.5% salt water of $71^{\circ}C$ for different durations to get various moisture contents; 0, 0.2, 0.5, 1.0, and 2.0%(saturation). A total of 80 joint specimens were tested for 5 different moisture contents and 2 temperature environments. Test results show that while the joint strengths after the saturation of moisture decrease compared to those of dry ones, the strengths of the pre-saturated joint up to 1.0% of moisture content increase in both room and elevated temperature conditions. It is also shown that the strengths of joints tested in elevated temperature are slightly higher than the strength in room temperature by 2-5% until the moisture content reaches 1 %. In contrast, the high temperature strength of the saturated joint is about 5% lower than the room temperature strength.

• Advanced Composite Materials
• /
• v.17 no.1
• /
• pp.57-73
• /
• 2008

The present paper focuses on experimental verification of the ply-by-ply basis inelastic analysis of multidirectional laminates. First of all, rate dependence of the tensile behavior of balanced symmetric cross-ply T800H/epoxy laminates with a $[0/90]_{3S}$ lay-up under off-axis loading conditions at $100^{\circ}C$ is examined. Uniaxial tension tests are performed on plain coupon specimens with various fiber orientations $[{\theta}/(90-{\theta})]_{3S}$ ($\theta$ = 0, 5, 15, 45 and $90^{\circ}C$) at two different strain rates (1.0 and 0.01%/min). The off-axis stress.strain curves exhibit marked nonlinearity for all the off-axis fiber orientations except for the on-axis fiber orientations $\theta$ = 0 and $90^{\circ}$, regardless of the strain rates. Strain rate has significant influences not only on the off-axis flow stress in the regime of nonlinear response but also on the apparent off-axis elastic modulus in the regime of initial linear response. A macromechanical constitutive model based on a ply viscoplasticity model and the classical laminated plate theory is applied to predictions of the rate-dependent off-axis nonlinear behavior of the cross-ply CFRP laminate. The material constants involved by the ply viscoplasticity model are identified on the basis of the experimental results on the unidirectional laminate of the same carbon/epoxy system. It is demonstrated that good agreements between the predicted and observed results are obtained by taking account of the fiber rotation induced by deformation as well as the rate dependence of the initial Young's moduli.

• Korean Journal of Materials Research
• /
• v.8 no.10
• /
• pp.918-924
• /
• 1998

This study has been carried out to investigate the effect of reaction milling time on the synthesis of Ti- TiC p powder synthesised from the elemental titanium and activated carbon by reaction milling(RM), and the effect of vacu­u urn hot pressing temperature and TiC volume fraction on microstructural and mechanical properties of Ti- TiC com­p posite $\infty$ns이idated by vacuum hot pressing(VHP).T The elemental powders of titanium and activated carbon can be converted into Ti- TiC composite powders by reac­t tion milling for about 300hours, and were the average grain size of the as- milled powders has been measured to be a about $5\mu\textrm{m}$. The relative density of Ti- TiC VHPed above $1000^{\circ}C$ during Ihr is about 98% and the mechanical properties o of In- situ Ti- TiC composites are improved by TiC particle dispersed uniformly on titanium matrix. In order to investi­g gate thermal stability of Ti- TiC composite, after annealing at $600^{\circ}C$ for 80hrs micro- Vickers hardness have been per­f formed, and the values have been shown little changed as compared with those before annealing. The compact has b been tested on high temperature compressive test at $700^{\circ}C$ and has showed a high temperature compressive strength of 330MPa in a Ti- 20vol% TiC.