• 제목/요약/키워드: High pressure phase behavior

검색결과 142건 처리시간 0.026초

이성분 폴리에틸렌/부탄과 폴리에틸렌/디메틸 에테르계의 고압 상거동 (High Pressure Phase Behavior in the Binary Polyethylene/Butane and Polyethylene/Dimethyl Ether Systems)

  • 전남석;변헌수
    • 공업화학
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    • 제10권5호
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    • pp.761-766
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    • 1999
  • 본 연구는 고압하에서 폴리에틸렌($M_w=700,\;1000$ 및 2000)/부탄(butane)과 폴리에틸렌($M_w=700,\;1000$ 및 2000)/디메틸 에테르(dimethyl ether)계에 대한 상거동 실험을 수행하였다. 폴리에틸렌/부탄계는 $M_w=700,\;1000$ 및 2000의 각 중량분자량에 대해 농도를 증가시키면서 압력-온도관계를 나타내었다. 각 중량분자량의 농도가 증가함에 따라 온도와 압력이 증가하다 농도가 약 16 wt % 이상에서 압력이 감소함을 보였다. 또한 각 분자량에 대해 폴리에틸렌의 양을 약 5 wt % 첨가하여 상거동을 압력-온도관계로 나타내었으며, $M_w=700,\;1000$ 및 2000으로 분자량이 증가함에 따라 압력이 증가함을 보였다. 폴리에틸렌/디메틸 에테르계는 각각의 분자량에 따라 상거동을 나타내었으며, 온도 약 $120{\sim}220^{\circ}C$ 범위에서 압력 40~290 bar 범위로 나타났다. 폴리에틸렌/디메틸 에테르계의 압력-온도관계는 폴리에틸렌의 분자량이 증가함에 따라 온도와 압력도 증가하였으며, 각 분자량에 따른 압력차는 60 bar 정도로 나타났다. 또한 각 분자량에 따라 약 5 wt % 일정량의 폴리에틸렌에 대한 폴리에틸렌/부탄과 폴리에틸렌/디메틸에테르계를 비교한 결과 압력차는 약 $25(M_w=700)$, 약 $90(M_w=1000)$ 및 약 100 bar($M_w=2000$)의 간격으로 나타났다.

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단일 구형 기포의 수학적 모델에 대한 수치적 해석 모델 (Numerical Modeling of the Mathematical Model of Single Spherical Bubble)

  • 강동근;양현익
    • 한국생산제조학회지
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    • 제19권6호
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    • pp.731-738
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    • 2010
  • Cavitation is described by formation and collapse of the bubbles in a liquid when the ambient pressure decreases. Formed bubbles grow and collapse by change of pressure, and when they collapse, shockwave by high pressure is generated. In general, bubble behavior can be described by Rayleigh-Plesset equation under adiabatic or isothermal condition and hence, phase shift by the pressure change in a bubble cannot be considered in the equation. In our study, a numerical model is developed from the mathematical model considering the phase shift from the previous study. In the developed numerical model, size of single spherical bubble is calculated by the change of mass calculated from the change of the ambient pressure in a liquid. The developed numerical model is verified by a case of liquid flow in a narrow channel.

축류송풍기의 실속셀 거동에 관한 실험적 연구 (Experimental Study on the Behavior of Stall Cell in an Axial Flow Fan)

  • 신유환;김광호;강창식
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2002년도 학술대회지
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    • pp.643-646
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    • 2002
  • Experimental study was conducted to reveal the flow mechanism under rotating stall in an axial flow fan. For this study unsteady pressure was measured using high frequency pressure transducers mounted on the casing wall of rotor passage and total pressure fields were measured at the rotor upstream and downstream. The measured pressure signal was analyzed by Wavelet Transform and Double Phase Locked Averaging Technique. From the result of unsteady pressure field of the casing wall, one period of rotating stall was divided into three zones and the flow characteristics on each zone were described in detail. The pressure field was also analyzed in terms of the pressure distribution along pressure side and suction side of blade tip. From the result of total pressure fields at inlet and outlet of the rotor, the useful information on the characteristics of the stall cell in radial direction was provided.

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가솔린 분무 거동에 미치는 분위기 조건의 영향 (Effect of Ambient Conditions on Spray Behavior of Gasoline Injector)

  • 이창식;이기형;최수천;권상일
    • 한국자동차공학회논문집
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    • 제8권2호
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    • pp.27-32
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    • 2000
  • The main objective of this work is to investigate the effect of ambient conditions on the spray behavior and spray characteristics of high-pressure fuel injector. For this purpose, the effects of ambient pressure and temperature on the spray characteristics have been studied by applying the analysis of visualization system and phase Doppler particle analyzer. In this experiment, the visualization of spray behavior was performed under various ambient gas conditions and injection parameters such as gas temperature, ambient pressure, injection pressure of injector, and axial distance from the nozzle tip. Based on the investigation results, the spray tip penetration and spray width decrease with the increase of ambient gas pressure in the spray chamber. The effects of the spray parameters on the microscopic characteristics of gasoline spray were discussed.

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CRITICAL FLOW EXPERIMENT AND ANALYSIS FOR SUPERCRITICAL FLUID

  • Mignot, Guillaume;Anderson, Mark;Corradini, Michael
    • Nuclear Engineering and Technology
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    • 제40권2호
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    • pp.133-138
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    • 2008
  • The use of Supercritical Fluids(SCF) has been proposed for numerous power cycle designs as part of the Generation IV advanced reactor designs, and can provide for higher thermal efficiency. One particular area of interest involves the behavior of SCF during a blowdown or depressurization process. Currently, no data are available in the open literature at supercritical conditions to characterize this phenomenon. A preliminary computational analysis, using a homogeneous equilibrium model when a second phase appears in the process, has shown the complexity of behavior that can occur. Depending on the initial thermodynamic state of the SCF, critical flow phenomena can be characterized in three different ways; the flow can remain in single phase(high temperature), a second phase can appear through vaporization(high pressure low temperature) or condensation(high pressure, intermediate temperature). An experimental facility has been built at the University of Wisconsin to study SCF depressurization through several diameter breaks. The preliminary results obtained show that the experimental data can be predicted with good agreement by the model for all the different initial conditions.

초임계 이산화탄소에서 소르비탄 모노팔미테이트 계면활성제의 상거동에 관한 연구 (Phase Behavior of Sorbitan Monopalmitate Surfactant in Supercritical Carbon Dioxide)

  • 오경환;김은진;신헌용
    • 청정기술
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    • 제19권1호
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    • pp.8-12
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    • 2013
  • 가변부피 투시셀이 장착된 고압 상평형 장치를 사용하여 이산화탄소 + 계면활성제 이성분계와 이산화탄소 + 계면활성제 + 물 삼성분계의 상평형 거동을 318 K부터 348 K의 온도범위에서 관찰하였다. 계면활성제로는 소르비탄 모노팔미테이트를 사용하였다. 이산화탄소 + 소르비탄 모노팔미테이트 이성분계에서 관측된 운점압력은 온도가 상승함에 따라 증가하며, 소르비탄 모노팔미테이트의 조성이 0.226 wt%에서 최대 운점압력이 측정되었다. 반면에 계면활성제의 농도를 0.1 wt%로 고정한 삼성분계에서 관측된 운점압력은 온도와 물의 조성이 증가함에 따라 커지는 것을 확인할 수 있었다. 물의 농도를 0.2 wt%로 고정한 삼성분계에서의 압력-조성의 곡선은 상대적으로 수평의 형태를 나타냈다. 이 때, 운점압력은 온도와 계면활성제의 조성이 증가함에 따라 상승함을 확인할 수 있다.

A Study on the Behavior Characteristics of Diesel Spray by Using a High Pressure Injection System with Common Rail Apparatus

  • Yeom, Jeong-Kuk;Hajime Fujimoto
    • Journal of Mechanical Science and Technology
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    • 제17권9호
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    • pp.1371-1379
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    • 2003
  • The effects of change in injection pressure on spray structure in high temperature and pressure field have been investigated. The analysis of liquid and vapor phases of injected fuel is important for emissions control of diesel engines. Therefore, this work examines the evaporating spray structure using a constant volume vessel. The injection pressure is selected as the experimental parameter, is changed from 22 MPa to 112 MPa using a high pressure injection system (ECD-U2). Also, we conducted simulation study by modified KIVA-II code. The results of simulation study are compared with experimental results. The images of liquid and vapor phase for free spray were simultaneously taken by exciplex fluorescence method. As experimental results, the vapor concentration of injected fuel is leaner due to the increase of atomization in the case of the high injection pressure than in that of the low injection pressure. The calculated results obtained by modified KIVA-II code show good agreements with experimental results.

직접 분사식 연료 분무에서의 기.액상 분리 계측에 관한 연구 (An Experimental Study on the Analysis of Liquid/Vapor Phase in GDI Spray)

  • 장석형;김정호;박경석;진성호;김경수
    • 한국분무공학회지
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    • 제5권4호
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    • pp.57-65
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    • 2000
  • For this research an extension of the LIF technique that the LIEF(Laser Induced Exciplex Fluorescence) technique has been used LIEF technique is the unique method to allows the visualization of fuel vapor phase and liquid phase individually by capturing each signals of them. In this work performed that the basic procedure for advanced LIEF technique using TEA and benzene as dopants md high power KrF excimer laser to excite the dopants. Iso-octane is used as the fuel because it does not absorb light at the laser wavelength. The boiling point of benzene and TEA are $81^{\circ}C\;and89^{\circ}C$, respectively, in comparison to $99^{\circ}C$ for iso-octane. It is observed that the behavior and distribution of high pressed fuel injection from various test condition. The injection pressure is set as 3MPa. and 5MPa. And the ambient pressure of test chamber is atmospheric pressure and 1MPa, the ambient temperature of chamber is room temperature, $300^{\circ}C\;and\;500^{\circ}C$ to imitate the condition of GDI engine cylinder.

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고압에서 CO2-아세토니트릴과 CO2-아크릴로니트릴계에 대한 상거동에 관한 연구 (A Study on Phase Behavior of CO2-Acetonitrile and CO2-Acrylonitrile System at High Pressure)

  • 변헌수;김윤섭;임종균
    • 공업화학
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    • 제9권6호
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    • pp.924-929
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    • 1998
  • 본 연구에서는 고압하에서 이산화탄소와 니트릴계인 아세토니트릴 (acetonitrile)과 아크릴로니트릴 (acrylonitrile)과의 이성분계에 대한 상평형데이터를 얻기 위해 실험을 수행하였다. 실험장치는 정지형으로서 본 실험을 위해 자체 제작하여 사용하였으며, 새로이 설계된 실험장치의 재현성과 정확도를 실험하기 위해 $75^{\circ}C$에서 이산화탄소-아세토니트릴계의 실험을 수행하여 McHugh 등[1]의 실험결과와 비교하였다. 이산화탄소와 아세토니트릴과의 이성분계 상거동 실험은 온도 $55.0^{\circ}C$, $75.0^{\circ}C$, 그리고 $100.0^{\circ}C$에서 실험하였으며, 이때 압력은 2.4~14.5 MPa 범위였으며, 이산화탄소-아크릴로니트릴계의 상평형 실험은 온도 $45.0^{\circ}C$, $65.0^{\circ}C$, $85.0^{\circ}C$, 그리고 $105.5^{\circ}C$와 압력 1.6~13.9 MPa 근처까지 실험하였다. 두 계에 대해 동일한 압력에서 아세토니트릴과 아크릴로니트릴의 용해도는 온도가 증가함에 따라 증가함을 알 수 있다. 또한 두 계에 대한 혼합물 임계곡선에나타내었다. 본 연구에서 실험한 결과를 Peng-Robinson상태방정식에 의해 계산하였으며, 그 결과 실험치와 계산치와의 좋은 일치를 보였다.

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Physiological Responses of Bacillus amyloliquefaciens Spores to High Pressure

  • Ahn, Ju-Hee;Balasubramaniam, V.M.
    • Journal of Microbiology and Biotechnology
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    • 제17권3호
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    • pp.524-529
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    • 2007
  • Pressure inactivation behavior of Bacillus amyloliquefaciens spores was investigated in deionized water. The spores of B. amyloliquefaciens were subjected to $105^{\circ}C$ and 700 MPa. The magnitude of the decrease in viability after pressure treatment was similar to that after pressure treatment followed by heat shock. The increase of dipicolinic acid (DPA) release was correlated with the spore inactivation, and the hydrophobicity did not significantly change during the pressure-assisted thermal processing (PATP). Lag phase duration increased with increasing pressure process time. The mechanisms of spore germination and inactivation during the PATP were related to a complex physiological process.