• Title/Summary/Keyword: High ionization energy

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Influence of Alkali Metal Cation Type on Ionization Characteristics of Carbohydrates in ESI-MS

  • Choi, Sung-Seen;Kim, Jong-Chul
    • Bulletin of the Korean Chemical Society
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    • v.30 no.9
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    • pp.1996-2000
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    • 2009
  • Alkali metal salts were introduced to enhance the ionization efficiency of glucose and maltooligoses in electrospray ionization-mass spectrometry (ESI-MS). A mixture of the same moles of glucose, maltose, maltotriose, maltotetraose, maltopentaose, maltohexaose, and maltoheptaose was used. Salts of lithium, sodium, potassium, and cesium were employed as the cationizing agent. The ionization efficiency varied with the alkali metal cation types as well as the analyte sizes. Ion abundance distribution of the [M+$cation]^+$ ions of the carbohydrates varied with the fragmentor voltage. The maximum ion abundance at low fragmentor voltage was observed at maltose, while the maximum ion abundance at high fragmentor voltage shifted to maltotriose or maltotetraose for Na, K, and Cs. Variation of the ionization efficiency was explained with the hydrated cation size and the binding energy of the analyte and alkali metal cation.

Soil Ionization Phenomena around a Hemispherical Electrode Stressed by Impulse Voltages (임펄스전압에 의한 반구형 전극계에서 토양의 이온화 현상)

  • Heo, Dae-min;Kim, Hoe-gu;Lee, Bok-hee
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.4
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    • pp.601-608
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    • 2016
  • The electrical characteristics of the soil where a ground electrode is buried vary with regions, seasons and environmental factors. Electrical discharge in the vicinity of the ground electrode will occur differently and significantly affect the performance of the grounding system. It is necessary to analyze discharge and ionization characteristics of soils when the grounding system is designed. The aims of this investigation are to understand correlation between the soil ionization and the transient ground impedance. This paper presents the experimental results on the soil ionization parameters and the transient ground resistance due to the soil ionization around a hemispherical ground electrode stressed by lightning impulse voltages.

Fabrication of Ionization Chamber to Measure the Burnup of Spent Fuel (사용후핵연료 연소도 측정을 위한 이온 챔버 제작)

  • Park, Se-Hwan;Eom, Sung-Ho;Shin, Hee-Sung;Lim, Hye-In;Ha, Jang-Ho;Kim, Han-Soo
    • Journal of Radiation Protection and Research
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    • v.35 no.1
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    • pp.21-25
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    • 2010
  • Burnup of spent fuel should be determined accurately for the safety control of spent fuel. Especially, it is necessary to measure the burnup profile along the nuclear fuel axis. In the present work, an ionization chamber was designed and fabricated to measure the gamma ray profile inside the guide tube of spent fuel. The ionization chamber was composed of three parts; induction part, gas-inlet part, and sensor part. The sensor part had two electrodes; cathode and anode. A guide electrode was considered in the ionization chamber design to make the ionization chamber to be inserted easily into the guide tube. Pure gas (argon and xenon) was inserted into the ionization chamber, and the leakage current and saturation curve were measured to determine the operation characteristics of the ionization chamber. The gamma ray radiation was also measured in relatively high dose environment. The gamma ray profile of the spent fuel will be measured with the ionization chamber.

A Study on Increase of Sulfur Hexafluoride(SF6) Destruction and Removal Efficiency by Conditioning Agent(H2) (수소첨가에 의한 육불화황(SF6) 분해효율 향상 기초연구)

  • Ryu, Jae-Yong;Kim, Jong-Bum;Choi, Chang-Yong;Jang, Seong-Ho;Lee, Sang-Joon
    • Journal of Environmental Science International
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    • v.21 no.9
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    • pp.1163-1169
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    • 2012
  • Destruction and removal efficiency (DRE) of $SF_6$ was tested with low degrees of ionization. The applied dose of ionization energy varied from 63.70 to 212.34 kGy. The initial concentration and flow rate of $SF_6$ gas were 1,000 ppm and 50L/min, respectively. In order to increase the DRE, injection of conditioning agent ($H_2$) were conducted. The DRE of $SF_6$ increased about 2 times with injection of $H_2$ gas.

Atmospheric Pressure Plasma Research Activity in Korea

  • Uhm, Han S.
    • Journal of the Korean institute of surface engineering
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    • v.34 no.5
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    • pp.367-377
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    • 2001
  • Plasma is generated by electrical discharge. Most plasma generation has been carried out at low-pressure gas typically less than one millionth of atmospheric pressure. Plasmas are in general generated from impact ionization of neutral gas molecules by accelerated electrons. The energy gain of electrons accelerated in an electrical field is proportional to the mean free path. Electrons gain more energy at low-pressure gas and generate plasma easily by ionization of neutrals, because the mean free path is longer. For this reason conventional plasma generation is carried out at low pressures. However, many practical applications require plasmas at high-pressure. In order to avoid the requirement for vacuum pumps, researchers in Korea start to develop plasmas in high-pressure chambers where the pressure is 1 atmosphere or greater. Material processing, environmental protection/restoration and improved energy production efficiency using plasmas are only possible for inexpensive bulk plasmas. We thus generate plasmas by new methods and plan to set foundations for new plasma technologies for $21^{st}$ / century industries. This technological research will play a central role in material processing, environmental and energy production industries.

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Performance Analysis of A Variable-Spacing Cesium Thermionic Energy Converter (열전변환 장치의 특성 분석에 대한 연구)

  • Lee, Deuk-Yong
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.9
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    • pp.1085-1094
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    • 1992
  • A variable-spacing cesium thermionic energy conversion test station is designed and fabricated for the study of power generation. The diode is in the form of a guard-ringed plane-parallel geometry in which a polycrystalline rhenium emitter of 2 cmS02T area faces a radiation-cooled polycrystalline rhenium collector of 1.9 cmS02T area. The emission of plasma from heated refractory electrode metal is the driving reaction in the direct conversion of heat to electricity by thermionic energy conversion. The plasma is produced from electrons and positive ions formed simultaneously by thermionic emission and surface ionization of cesium atoms incident on the hot emitter from the cesium vapor in the diode. And high plasma density causes plasma multiplication within the gap due to volume ionization that results in high power output. The variation of the saturation current of a Knudsen converter is investigated at an emitter-collector gap of 0.1 mm and an emitter temperatures. A maximum power output of 13.47 watta/cmS02T is observed at a collector temperature of 963 K and a cesium reservoir temperature of 603 K.

Electron Transport Characterization Including L Valley at High Field (실리콘의 L valley를 고려한 강한 전계에서 전자 수송의 특성)

  • Rhee, Jun-Koo;Park, Young-June;Han, Min-Koo
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.257-260
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    • 1990
  • Monte Carlo simulations of electron impact ionization in silicon utilizing simple spherical band approximation including L valley are presented. The mean energy of electron at high electric field is lowered and the threshold energy of electron impact ionizaiotn is smeared out to $E_x$ by including L valley. This work also presents the importance of the modeling of L valley by calculating the electron population rate of it over the threshold energy of eletron impact ionization, which is higher than 10%

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Stem Effect Correction Factor of Ionization Chamber in Exposure Measurements of High Energy Photons (고 에너지 광자선의 조사선량 측정 시 전리함의 스템효과 보정계수)

  • Park, Cheol-Woo;Lee, Jae-Seung;Kweon, Dae-Chel;Cha, Dong-Soo;Kim, Jin-Soo;Kim, Kyoung-Keun
    • Korean Journal of Digital Imaging in Medicine
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    • v.12 no.1
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    • pp.51-58
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    • 2010
  • Ionization chambers often exhibit a stem effect, caused by interactions of radiation with air near the chamber end, or with dielectric in the chamber stem or cable. In this study measured stem effect correction factor for length of ionization chamber from medical linear accelerator recommend to with the use of stem correction method. For a model of the Farmer-type chamber, were used to calculate the beam quality correction factor. These interactions contribute to the apparent measured exposure. Additionally, it needs to consider ionization chamber use of small volume and stem effect of cable by a large field. Linear accelerator generated photons energy and increased dose repeatedly measured by using stem correction method. Stem effect was dependence of the energy and increases with photon energy conditions improved of beam quality. In conclusion, stem effect correction factor was measured within 0.4% calculated according to the exposures stem length and also supposed to determined below 1% of another stem correction method.

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Radiotherapy Technique of High Energy Electron (고에너지 전자선의 방사선 치료 기술)

  • SUH M.W.;PARK J.I.;CHOI H.S.;KIM W.Y.
    • The Journal of Korean Society for Radiation Therapy
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    • v.1 no.1
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    • pp.63-69
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    • 1985
  • High energy electron beams took effect for tumor radio-therapy, however, had a lot of problems in clinical application because of various conversion factors and complication of physical reactions. Therefore, we had experimentally studied the important properties of high energy electron beams from the linear accelerator, LMR-13, installed in Yonsei Cancer Center. The results of experimental studies on the problems in the 8, 10, 12 Mev electron beam therapy were reported as following. 1. On the measurements of the outputs and absorbed does, the ionization type dosimeters that had calibrated by $^{90}Sr$ standard source were suitable as under $3\%$ errors for high energy electrons to measure, but measuring doses in small field sizes and the regions of rapid fall off dose with ionization chambers were difficult. 2. The electron energy were measured precisely with energy spectrometer consisted of magnet analyzer and tele-control detector and the practical electron energy was calculated under $5\%$ errors by maximum range of high energy electron beam in the water. 3. The correcting factors of perturbated dose distributions owing to radiation field, energy and material of the treatment cone were checked and described systematically and variation of dose distributions due to inhomogeneous tissues and sloping skin surfaces were completely compensated. 4. The electron beams, using the scatters; i.e., gold, tin, copper, lead, aluminium foils, were adequately diffused and minimizing the bremsstrahlung X-ray induced by the electron energy, irradiation field size and material of scatterers, respectively. 5. Inproving of the dose distribution from the methods of pendulum, slit, grid and focusing irradiations, the therapeutic capacity with limited electron energy could be extended.

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