• 한국표면공학회지
• /
• 제37권4호
• /
• pp.200-207
• /
• 2004

Molybdate chemical conversion coating layer formed on EGI has been studied in view of corrosion resistance, surface morphologies, and phases formed. It was found that coating layer consists of$ MoO_3$, $MoO_2$, Mo oxides having lower valences than 4 and ZnO. It is interesting to note that the coating layer formed at high Mo concentration (30 g/l) in the temperature range of $40-60^{\circ}C$ exhibited relatively high corrosion resistance, although thickness of coating layer is nearly identical with those formed under the other conditions. It was believed that an increase of driving force due to high Mo concentration plays an important role in the formation of corrosion-resistant coating layer, probably due to tile formation of dense coating layer.

• Journal of Korean Society for Atmospheric Environment
• /
• 제18권E2호
• /
• pp.107-120
• /
• 2002

Dimethyl sulfide (DMS) is the major sulfur gas released from the ocean. The atmospheric DMS released from the ocean is oxidized mainly by hydroxyl (OH) radical during the day and nitrate (NO$_3$) radical at night to form sulfur dioxide (SO$_2$) as well as other stable products. The oxidation mechanism of DMS via OH has been known to proceed by two channels; abstraction and addition channels. The major intermediate product of the addition channel has been known to be dimethylsulfoxide (DMSO) based on laboratory chamber studies and field experiments. However, a branching ratio for DMSO formation is still uncertain. The reaction of DMSO with OH ultimately produces SO$_2$and dimethylsulfone. The major product of the abstraction channel has known to be SO$_2$from laboratory chamber studies. But overall conversion efficiency for DMS to SO$_2$from DMS oxidation is still inconsistent in the literature. Based on laboratory and field studies, the conversion efficiency from the abstraction channel is likely to be greater than 0.5, while that from the addition channel is likely to be greater than 0.6. Overall conversion efficiency from DMS to SO$_2$might be greater than 0.5 based on the above two values in the remote marine boundary layer (MBL). This high efficiency in the remote MBL is supported by strong coupling between DMS and SO$_2$measurements with high temporal resolution.

• 한국결정성장학회지
• /
• 제28권1호
• /
• pp.44-50
• /
• 2018

The improved high-performance Fe-based perovskite-type oxides ($La_{0.7}Sr_{0.3}M_xFe_{1-x}O_3$, M = Cu, Cr, Ni) were synthesized by a citrate method and characterized by SEM, EDS, XRD and NMR spectroscopy analyses. The characterization analyses revealed that the stoichiometric amounts of lattice oxygen were existed in all of perovskite samples except for a nickel-doped perovskite. Fe-based perovskites exhibited a surprising result for ortho-para $H_2$ spin conversion reaction, indicating two orders of magnitude higher conversions and conversion rates than commercial $Fe_2O_3$. It was considered that this conversion difference might be attributed to the presence of oxygen vacancies in Fe-based perovskites prepared in this study.

• Journal of Microbiology and Biotechnology
• /
• 제11권2호
• /
• pp.329-332
• /
• 2001

It has been known that, in enzymatic synthesis of cephalexin, the conversion yield was reduced by high loading of ampicillin acylase. In order to elucidate this phenomena, pH-controlled synthesis of cephalexin was examined using a purified Acetobacter turbidans acylase. When the pH of the reaction mixture was maintained at $6.20{\pm}0.04$, the reduction of the maximal conversion rate was not observed even with high enzyme loading. The kinetic parameters also suggest that pH drop during the enzymatic synthesis of cephalexin was mainly attributed to the rapid hydrolysis of D-${\alpha}$-phenylglycine methyl ester to D-${\alpha}$-phenylglycine, rather than the disappearance of 7-amino-3-deacetoxycephalosporanic acid for cephalexin synthesis. At higher molar ratio of two substrates, [D-${\alpha}$-phenylglycine methyl ester]/[7-amino-3-deacetoxycephalosporanic acid], the conversion rate was also elevated under pH-controlled enzymatic synthesis, which implies that the main reason for the pH drop is due to the production of D-${\alpha}$-phenylglycine methyl easter, the effect of a water-methanol cosolvent system on the ester, the effect of a water-methanol cosolvent system on the conversion profile was also examined. Even the though the conversion rate was increased in 10% methanol solution, a higher than 16% methanol in the reaction mixture caused an inactivation of enzyme.

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2012년도 추계총회 및 학술대회 논문집
• /
• pp.17-17
• /
• 2012

Magnesium alloys exhibit many attractive properties such as low density, high strength/weight ratio, high thermal conductivity, very good electromagnetic features and good recyclability. However, most commercial magnesium alloys require protective coatings because of their poor corrosion resistance. Attempts have been made to improve the corrosion resistance of the Mg alloys by surface treatments, such as chemical conversion coatings, anodizing, plating and metal coatings, are commonly applied to magnesium alloys in order to increase the corrosion resistance. Among them, chemical conversion coatings are regarded as one of the most effective and cheapest ways to prevent corrosion resistance. In this study, zinc phosphate conversion coatings on various Mg alloys have been developed by selecting proper phosphating bath composition and concentration and by optimizing phosphating time, temperature. Morphology, coatings composition, corrosion resistance, adhesion and its formation and growth mechanism of the zinc phosphate conversion coatings were studied. Results have shown some attractive properties such as simplicity in operation, significantly increased corrosion protective property. However, adhesions between coatings and substrate and also between coatings and paint are still not satisfied. Resolving the problems and understanding the mechanism of phosphating process are targets of our study.

• Journal of Power Electronics
• /
• 제15권2호
• /
• pp.366-377
• /
• 2015

In order to minimize switching losses for high power applications, a boost PFC rectifier with a novel passive lossless snubber circuit is proposed. The proposed lossless snubber is composed of coupled inductors merged into a boost inductor. This method compared with conventional methods does not need additional inductor cores and it reduces extra costs to implement a soft switching circuit. Especially, the proposed circuit can reduce the reverse recovery current of output diode rectifiers due to the coupling effect of the inductor. During turn-on and turn-off operating modes, the proposed PFC converter operates under soft switching conditions with high power conversion efficiency. In addition, the performance improvement and analysis of the operating effects of the coupled inductors were also presented and verified with a 3.3 kW prototype rectifier.

• Nuclear Engineering and Technology
• /
• 제55권9호
• /
• pp.3121-3125
• /
• 2023

Neutron conversion detectors that use ¹⁰B-enriched boron carbide are feasible alternatives to ³He-based detectors. We prepared boron carbide films at micron-scale thickness using direct-current magnetron sputtering. The structural characteristics of natural B₄C films, including density, roughness, crystallization, and purity, were analyzed using grazing incidence X-ray reflectivity, X-ray diffraction, X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry, and scanning electron microscopy. A beam profile test was conducted to verify the practicality of the ¹⁰B-enriched B₄C neutron conversion layer. A clear profile indicated the high quality of the neutron conversion of the boron carbide layer.

• 한국응용과학기술학회지
• /
• 제16권2호
• /
• pp.117-125
• /
• 1999

The alkylation benzene with 1-dodecene of Mordenite, Zeolite ${\beta}$ and Zeolite Y was studied in the stirring batch reactor. The kinds of zeolites were found to have influenced the reaction conversion and distribution of phenyldodecane isomer in the product. Compared to the alkylation conducted over Zeolite Y and Zeolite ${\beta}$, the alkylation over Mordenite exhibited higher distribution of 2-phenyldodecane and the alkylation conducted over Zeolite Y and Mordenite, the alkylation over Zeolite ${\beta}$ exhibited higher distribution of heavy alkylate which formed through oligomerization reaction readily deactivated the Lewis acid sites. A special feature of the effect of the benzene to 1-dodecene ratio the reaction conversion and selectivity of phenyldodecane isomer was found. At alkylation of benzene with 1-dodecene over Zeolite ${\beta}$, when the catalyst content in the system was high, the reaction will reach the optimal conversion at the higher B/D. When the benzene to 1-dodecene ratio was high, the selectivity of phenyldodecane isomer is high. It was also found that at the similar reaction conversion there was the same product distribution regardless of D/C ratio.

• 전력전자학회논문지
• /
• 제19권1호
• /
• pp.23-30
• /
• 2014

This paper proposes a single power-conversion ac-dc converter with a dc-link capacitor-less and high power factor. The proposed converter is derived by integrating a full-bridge diode rectifier and a series-resonant active-clamp dc-dc converter. To obtain a high power factor without a power factor correction circuit, this paper proposes a suitable control algorithm for the proposed converter. The proposed converter provides single power-conversion by using the proposed control algorithm for both power factor correction and output control. Also, the active-clamp circuit clamps the surge voltage of switches and recycles the energy stored in the leakage inductance of the transformer. Moreover, it provides zero-voltage turn-on switching of the switches. Also, a series-resonant circuit of the output-voltage doubler removes the reverse-recovery problem of the output diodes. The proposed converter provides maximum power factor of 0.995 and maximum efficiency of 95.1% at the full-load. The operation principle of the converter is analyzed and verified. Experimental results for a 400W ac-dc converter at a constant switching frequency of 50kHz are obtained to show the performance of the proposed converter.

• 전력전자학회:학술대회논문집
• /
• 전력전자학회 2014년도 전력전자학술대회 논문집
• /
• pp.413-414
• /
• 2014

This paper proposed an optimized design of a dual active bridge converter for a low-voltage charger. The dual active bridge converter among various bi-directional DC/DC converters is a high-efficiency isolated bi-directional converter. In the general design, when the battery voltage is high, the ZVS region is reduced. In contrast, when the battery voltage is low, the efficiency is low due to high conduction loss. In order to increase the ZVS region and the power conversion efficiency, depending on the battery voltage, variable switching frequency method is applied. At the same duty, the same power is obtained regardless of the battery voltage using the variable switching frequency method. The proposed method was applied to a 5kW prototype converter, and the experimental results were analyzed and verified.