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Influence of the preparation design and artificial aging on the fracture resistance of monolithic zirconia crowns

  • Mitov, Gergo;Anastassova-Yoshida, Yana;Nothdurft, Frank Phillip;See, Constantin von;Pospiech, Peter
    • The Journal of Advanced Prosthodontics
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    • v.8 no.1
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    • pp.30-36
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    • 2016
  • PURPOSE. The aim of this study was to evaluate the fracture resistance and fracture behavior of monolithic zirconia crowns in accordance with the preparation design and aging simulation method. MATERIALS AND METHODS. An upper first molar was prepared sequentially with three different preparation designs: shoulderless preparation, 0.4 mm chamfer and 0.8 mm chamfer preparation. For each preparation design, 30 monolithic zirconia crowns were fabricated. After cementation on Cr-Co alloy dies, the following artificial aging procedures were performed: (1) thermal cycling and mechanical loading (TCML): 5000 cycles of thermal cycling $5^{\circ}C-55^{\circ}C$ and chewing simulation (1,200,000 cycles, 50 N); (2) Low Temperature Degradation simulation (LTD): autoclave treatment at $137^{\circ}C$, 2 bar for 3 hours and chewing simulation; and (3) no pre-treatment (control group). After artificial aging, the crowns were loaded until fracture. RESULTS. The mean values of fracture resistance varied between 3414 N (LTD; 0.8 mm chamfer preparation) and 5712 N (control group; shoulderless preparation). Two-way ANOVA analysis showed a significantly higher fracture loads for the shoulderless preparation, whereas no difference was found between the chamfer preparations. In contrast to TCML, after LTD simulation the fracture strength of monolithic zirconia crowns decreased significantly. CONCLUSION. The monolithic crowns tested in this study showed generally high fracture load values. Preparation design and LTD simulation had a significant influence on the fracture strength of monolithic zirconia crowns.

Kinetics for the Reaction of Benzyl Benzenesulfonate with Pyridine in Acetone Under High Pressure (Benzyl Benzenesulfonate와 피리딘과의 고압반응에 대한 반응속도론적 연구)

  • Jung-Ui Hwang;Soo-Dong Yoh;Jong-Gi Jee
    • Journal of the Korean Chemical Society
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    • v.24 no.2
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    • pp.150-154
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    • 1980
  • Kinetic studies of the reaction of benzyl benzenesulfonate with pyridine in acetone were carried out by the electric conductivity method under 1 to 2000 bars and at 20 to $40^{\circ}C$. The rate increases with increasing pressure and temperature. The activation enthalpy $({\Delta}H^{\neq}),\;entropy\;({\Delta}S^{\neq})$ and activation volume $({\Delta}V^{\neq})$ of the reaction are obtained by the above experiment. The isokinetic relationship between $({\Delta}H^{\neq})\;and\;({\Delta}S^{\neq})$ for pressure change in the reaction was shown, and its isokinetic temperature was $342^{\circ}K$. From all of the above results it was found that this reaction precedes on the $S_N2$ reaction mechanism in which the rate of the reaction was determined by $C{\cdots}N$ bond formation at transition state.

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Design and control of a proof-of-concept active jet engine intake using shape memory alloy actuators

  • Song, Gangbing;Ma, Ning;Li, Luyu;Penney, Nick;Barr, Todd;Lee, Ho-Jun;Arnold, Steve
    • Smart Structures and Systems
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    • v.7 no.1
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    • pp.1-13
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    • 2011
  • It has been shown in the literature that active adjustment of the intake area of a jet engine has potential to improve its fuel efficiency. This paper presents the design and control of a novel proof-of-concept active jet engine intake using Nickel-Titanium (Ni-Ti or Nitinol) shape memory alloy (SMA) wire actuators. The Nitinol SMA material is used in this research due to its advantages of high power-to-weight ratio and electrical resistive actuation. The Nitinol SMA material can be fabricated into a variety of shapes, such as strips, foils, rods and wires. In this paper, SMA wires are used due to its ability to generate a large strain: up to 6% for repeated operations. The proposed proof-of-concept engine intake employs overlapping leaves in a concentric configuration. Each leaf is mounted on a supporting bar than can rotate. The supporting bars are actuated by an SMA wire actuator in a ring configuration. Electrical resistive heating is used to actuate the SMA wire actuator and rotate the supporting bars. To enable feedback control, a laser range sensor is used to detect the movement of a leaf and therefore the radius of the intake area. Due to the hysteresis, an inherent nonlinear phenomenon associated with SMAs, a nonlinear robust controller is used to control the SMA actuators. The control design uses the sliding-mode approach and can compensate the nonlinearities associated with the SMA actuator. A proof-of-concept model is fabricated and its feedback control experiments show that the intake area can be precisely controlled using the SMA wire actuator and has the ability to reduce the area up to 25%. The experiments demonstrate the feasibility of engine intake area control using an SMA wire actuator under the proposed design.

Mechanical and Thermal Characteristics of Polyurethane Foam with Two Different Reinforcements and the Effects of Ultrasonic Dispersion in Manufacturing (이종 강화재를 첨가한 폴리우레탄 폼의 기계적 및 열적 특성과 제작 시 초음파 분산의 영향)

  • Kim, Jin-Yeon;Kim, Jeong-Dae;Lee, Jae-Myung
    • Journal of the Society of Naval Architects of Korea
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    • v.56 no.6
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    • pp.515-522
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    • 2019
  • Since Liquefied Natural Gas (LNG) is normally carried at 1.1 bar pressure and at -163℃, special Cargo Containment System (CCS) are used. As LNG carrier is becoming larger, typical LNG insulation systems adopt a method to increase the thickness of insulation panel to reduce sloshing load and Boil-off Rate (BOR). However, this will decrease LNG cargo volume and increase insulation material costs. In this paper, silica aerogel, glass bubble were synthesized in polyurethane foam to increase volumetric efficiency by improving mechanical and thermal performance of insulation. In order to increase dispersibility of particles, ultrasonic dispersion was used. Dynamic impact test, quasi-static compression test at room temperature (20℃) and cryogenic temperature (-163℃) was evaluated. To evaluate the thermal performance, the thermal conductivity at room temperature (20℃) was measured. As a result, specimens without ultrasonic dispersion have a little effect on strength under the compressive load, although they show high mechanical performance under the impact load. In contrast, specimens with ultrasonic dispersion have significantly increased impact strength and compressive strength. Recently, as the density of Polyurethane foam (PUF) has been increasing, these results can be a method for improving the mechanical and thermal performance of insulation panel.

Hydrogen Conversion of Syngas by Using WGS Reaction in a Coal Gasifier (가스화기에서 WGS 반응을 통한 합성가스의 수소 전환)

  • Lee, See Hoon;Kim, Jung Nam;Eom, Won Hyun;Baek, Il Hyun
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.1
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    • pp.12-19
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    • 2013
  • A gasification process with pre-combustion $CO_2$ capture process, which converts coal into environment-friendly synthetic gas, might be promising option for sustainable energy conversion. In the coal gasification for power generation, coal is converted into $H_2$, CO and $CO_2$. To reduce the cost of $CO_2$ capture and to maximize hydrogen production, the removal of CO and the additional production of hydrogen might be needed. In this study, a 2l/min water gas shift system for a coal gasifier has been studied. To control the concentration of major components such as $H_2$, CO, and $CO_2$, MFCs were used in experimental apparatus. The gas concentration in these experiments was equal with syngas concentration from dry coal gasifiers ($H_2$: 25-35, CO: 60-65, $CO_2$: 5-15 vol%). The operation conditions of the WGS system were $200-400^{\circ}C$, 1-10bar. Steam/Carbon ratios were between 2.0 and 5.0. The commercial catalysts were used in the high temperature shift reactor and the low temperature shift reactor. As steam/carbon ratio increased, the conversion (1-$CO_{out}/CO_{in}$) increased from 93% to 97% at the condition of CO: 65, $H_2$: 30, $CO_2$: 5%. However the conversion decreased with increasing of gas flow and temperature. The gas concentration from LTS was $H_2$: 54.7-60.0, $CO_2$: 38.8-44.9, CO: 0.3-1%.

A Study on the Economical Analysis of the Composite Precast Concrete Method (프리캐스트 콘크리트 복합화공법의 경제성 분석에 관한 연구)

  • Yoo, Dae-Ho;Lee, Han-Bok;Ahn, Jae-Cheol;Kang, Byeung-Hee
    • Proceedings of the Korean Institute Of Construction Engineering and Management
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    • 2007.11a
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    • pp.113-118
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    • 2007
  • In this study, we select a site adopting real composite precast concrete method. Estimating real construction cost and imaginary cost appling reinforced concrete method in the site, we compare the costs. Through using high intensity concrete and prestressed concrete, amount of concrete is reduced more than 50% but there isn't big gap in material cost. In the main construction cost of composite precast concrete method, the material cost with production cost and transportation cost are in that, joints and topping concrete are account for 90%. But in case of reinforced concrete, labor cost spent at concrete steel bar and form is account for 30%. In the cost of attached, compared with composite precast concrete method, the reinforced concrete method taken in big portion by temporary work and scaffolding is twice as much as composite precast concrete method in construction cost. Therefore, economic efficiency is excellent reducing 11% total cost of composite precast concrete method from the reinforced concrete method.

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Hydrogen Perm-Selectivity Property of the Palladium Hydrogen Separation Membranes on Porous Stainless Steel Support Manufactured by Metal Injection Molding (금속 사출성형 방식의 다공성 스테인리스 강 지지체에 형성된 팔라듐 수소 분리막의 투과 선택도 특성)

  • Kim, Se-Hong;Yang, Ji-Hye;Lim, Da-Sol;Kim, Dong-Won
    • Journal of the Korean institute of surface engineering
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    • v.50 no.2
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    • pp.98-107
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    • 2017
  • Pd-based membranes have been widely used in hydrogen purification and separation due to their high hydrogen diffusivity and infinite selectivity. However, it has been difficult to fabricate thin and dense Pd-based membranes on a porous stainless steel(PSS) support. In case of a conventional PSS support having the large size of surface pores, it was required to use complex surface treatment and thick Pd coating more than $6{\mu}m$ on the PSS was required in order to form pore free surface. In this study, we could fabricate thin and dense Pd membrane with only $3{\mu}m$ Pd layer on a new PSS support manufactured by metal injection molding(MIM). The PSS support had low surface roughness and mean pore size of $5{\mu}m$. Pd membrane were prepared by advanced Pd sputter deposition on the modified PSS support using fine polishing and YSZ vacuum filling surface treatment. At temperature $400^{\circ}C$ and transmembrane pressure difference of 1 bar, hydrogen flux and selectivity of $H_2/N_2$ were $11.22ml\;cm^{-2}min^{-1}$ and infinity, respectively. Comparing with $6{\mu}m$ Pd membrane, $3{\mu}m$ Pd membrane showed 2.5 times higher hydrogen flux which could be due to the decreased Pd layer thickness from $6{\mu}m$ to $3{\mu}m$ and an increased porosity. It was also found that pressure exponent was changed from 0.5 on $6{\mu}m$ Pd membrane to 0.8 on $3{\mu}m$ Pd membrane.

The Effect of Fuel Injection Timing on Combustion and Power Characteristics in a DI CNG Engine (직분식 CNG 엔진에서 연료 분사시기의 변화가 연소 및 출력 특성에 미치는 영향)

  • Kang, Jeong-Ho;Yoon, Soo-Han;Lee, Joong-Soon;Park, Jong-Sang;Ha, Jong-Yul
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.1
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    • pp.193-200
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    • 2007
  • Natural gas is one of the most promising alternatives to gasoline and diesel fuels because of its lower harmful emissions, including $CO_2$, and high thermal efficiency. In particular, natural gas is seen as an alternative fuel for heavy-duty Diesel Engines because of the lower resulting emissions of PM, $CO_2$ and $NO_x$. Almost all CNG vehicles use the PFI-type Engine. However, PFI-type CNG Engines have a lower brake horse power, because of reduced volumetric efficiency and lower burning speed. This is a result of gaseous charge and the time losses increase as compared with the DI-type. This study was conducted to investigate the effect of injection conditions (early injection mode, late injection mode) on the combustion phenomena and performances in the or CNG Engine. A DI Diesel Engine with the same specifications used in a previous study was modified to a DI CNG Engine, and injection pressure was constantly kept at 60bar by a two-stage pressure-reducing type regulator. In this study, excess air ratios were varied from 1.0 to the lean limit, at the load conditions 50% throttle open rate and 1700rpm. The combustion characteristics of the or CNG Engine - such as in-cylinder pressure, indicated thermal efficiency, cycle-by-cycle variation, combustion duration and emissions - were investigated. Through this method, it was possible to verify that the combustion duration, the lean limit and the emissions were improved by control of injection timing and the stratified mixture conditions. And combustion duration is affected by not only excess air ratio, injection timing and position of piston but gas flow condition.

Development of a Rapeseed Reaping Equipment Attachable to a Conventional Combine (Ill) - Analysis of Principal Factor for Loss Reduction of Rapeseed Mechanical Harvesting - (보통형 콤바인 부착용 유채 예취장치 개발 (III) - 유채 기계 수확 손실 절감을 위한 요인 구명 -)

  • Lee, C.K.;Choi, Y.;Jun, H.J.;Lee, S.K.;Moon, S.D.;Kim, S.S.
    • Journal of Biosystems Engineering
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    • v.34 no.2
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    • pp.114-119
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    • 2009
  • Field test was conducted to investigate primary factors reducing rapeseed harvesting using a reciprocating cutter-bar of combine. The results showed that the correlation between crop moisture content and yield loss had a U-type, which indicated that the yield reduction increased at too high and too low crop moisture contents. The proper ranges of crop moisture contents were 27${\sim}$35%, 21${\sim}$56%, and 62${\sim}$73% in case of grain, pod and stem, respectively. Crop moisture content was negatively correlated with header loss, but positively correlated with threshing loss. In contrary, stem moisture content showed positive correlations with total loss, threshing loss and separation loss. Working speed was positively correlated with header loss. Total flow rate, pod flow rate and stem flow rate were highly correlated with threshing loss and separation loss. However, grain flow rate did not show any correlation with total loss. According to the principal component analysis, two principal components were derived as components with eigenvalues greater than 1.0. The contribution rates of the first and the second components were 52.7% and 38.9%, which accounted for 91.6% of total variance. As a contributive factor influencing total loss of rapeseed mechanical harvesting, a crop moisture content factor was greater than a crop flow rate factor. The stepwise multiple regression analysis for total loss was conducted using crop moisture content factor, crop flow rate factor and coefficient. However, the model did not show any correlation among independent and dependent factors ($R^2$=0.060).

A Study of Stator Fault Detection for the Induction Motor Using Axial Magnetic Leakage Flux (축방향 누설자속 측정에 의한 유도전동기의 고정자 결함검출에 관한 연구)

  • Shin, Dae-Cheul;Kim, Young-Hwan
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.8
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    • pp.131-137
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    • 2005
  • The purpose of this paper is to evaluate the axial magnetic flux measurement could be used as a tool of the condition monitoring system for the induction motor and to develope the diagnostic algerian for the electric motors. The magnetic leakage flux signal is captured by the flux coil located at the end of motor without the disturbance of the operation. And the signal is analyzed both time and frequency bases to detect the failure of the motor. Specific signature can be described in time and frequency domain for each faults of the motor. The spectrum of the signal was found more useful for the monitoring purpose. The supply voltage imbalance and tin to turn failure of the stator winding could be detected by analysing the specific sidebands of the axial flux and sideband of the rotor bar pass frequency with the high resolution spectrum. The goal of this study verity that the axial flux measurement for the induction motor is a powerful tool for the diagnostic method and develope the algorithm to detect the fault.