• 공업화학
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• 제29권1호
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• pp.103-111
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• 2018

본 연구에서는 온도가 큰 폭으로 변화하는 배기가스에 대응하기 위하여 플라즈마 촉매 공정을 이용하여 넓은 온도범위($150{\sim}500^{\circ}C$)에서 질소산화물($NO_x$)의 전환효율을 향상시키고자 하였다. 촉매 자체의 활성이 높은 고온에서는 $NO_x$저감이 효과적으로 일어나므로 고온 영역에서는 플라즈마 발생을 중지한 채 운전하고, 저온영역에서는 촉매상에 플라즈마를 발생시켜 $NO_x$ 전환효율을 증가시켰다. 촉매의 종류, 반응온도, 환원제(n-헵테인)의 농도 및 에너지 밀도의 변화가 $NO_x$ 전환효율에 미치는 영향을 조사하였다. 다양한 촉매를 비교분석한 결과, 고온에서 촉매에 의한 $NO_x$ 전환효율은 $Ag-Zn/{\gamma}-Al_2O_3$ 촉매의 경우가 90% 이상으로 가장 우수하였다. 저온 영역에서는 탄화수소 선택적 환원 공정에 의해 $NO_x$가 거의 제거되지 않았으나, 플라즈마를 촉매상에서 발생시킬 경우 약 90%의 높은 $NO_x$ 전환효율을 나타내었다. 배기가스의 온도변화에 대응하여 플라즈마를 촉매상에 생성시켜 운전할 경우 $150{\sim}500^{\circ}C$에서 $NO_x$ 전환효율을 높게 유지할 수 있다.

• 대한기계학회논문집A
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• 제24권7호
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• pp.1673-1680
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• 2000

The degradation of a boiler header constructed by a material, 1Cr-0.5Mo steel in a fossil power plant is observed when the header is exposed for a long period to the high temperature and pressure. The present investigations are for evaluating the effect of the degradation on the material, such as its strength changes. Reheat-treated metal is used to compare the mechanical properties of the degraded and that of reheat-treated materials. Through the investigation, following results are obtained 1) the area ratio of ferrite in the reheat-treated material is larger than that of the degraded material, 2) the hardness and tensile strength of the degraded material are lower than that of the reheat-treated material, 3) the ductile-brittle transition temperature(DBTT) increased toward high temperature region, 4) the fatigue crack growth rate(FCGR) of the degraded material is higher than that of the reheat-treated material in the region of low ΔK value while FCGR of the both materials are similar in high ΔK region.

• 한국세라믹학회지
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• 제44권11호
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• pp.597-606
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• 2007

With the advent of ubiquitous age, the high quality dielectric materials have been required for the wireless communications available to the millimeterwave as well as microwave frequencies. The utilizable region for the frequency has been expanding to the millimeter-wave region because of the shortage of radio frequency (RF) resources. These high frequencies would be expected for ultra high speed LAN, ETS and car anti-collision system on the intelligent transport system (ITS) and so on. Silicates are good candidates for microwave/millimeterwave dielectrics, because of their low dielectric constant ${\epsilon}_r$ and high quality factor (High Q). Forsterite ($Mg_2SiO_4$) is one of the silicates with low ${\epsilon}_r$ of 6.8 and Q f of 240000 GHz. In this paper, we reviewed following three categories for synthesis of forsterite: (1) Synthesis of high Q forsterite (2) Adjust the temperature coefficient of resonant frequency $TC_f$ (3) Diffusion of $SiO_{4^-}$ and Mg-ions on the formation of forsterite.

• 연구논문집
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• 통권24호
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• pp.161-174
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• 1994

The Ni-Al intermetallic compound that has the greatest potential to be commercialized shows the high ductility at room temperature with the addition of boron, but has extremely low ductility at high temperature and oxidation environment. On this research work, the changes of microstructure and compressive fracture properties were studied in ($NiAl+Ni_3Al$) two-phase alloys. The precipitation behavior of $Ni_3Al$ after solution treatment at $1300^\circC$ for 14hrs and aging treatment at $800^{\circ}C$ for 14hrs was varied with Al content in ($NiAl+Ni_3Al$) two-phase alloys. These microstructure could be modified dramatically by suitable heat treatments. Martensite or martensite plus $Ni_3Al$ microstructure was obtained upon oil quenching from $1300^\circC$. Aging of Martensite at $800^\circC$ resulted in the $Ni_3Al$ plus NiAl phase. The compressive fracture strength and compressive fracture strain were improved by the $Ni_3Al$ plus NiAl phase mixtures at room temperature and $1100^\circC$. Microcracks are observed mostly in the region of NiAl and the interface of $NiAl-Ni_3Al$ phase after compressive test at room temperature. In the case of high temperature compressive test, microcracks are formed in the region of $Ni_3Al$ phase.

• E2M - 전기 전자와 첨단 소재
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• 제10권5호
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• pp.453-460
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• 1997

In order to investigate the electrical conduction properties of polyethylene thin film for power cable with manufacturing methods, the thickness of specimen was the 30, 100[${\mu}{\textrm}{m}$] of LDPE and 200[${\mu}{\textrm}{m}$] of XLPE were manufactured. The experimental condition for conduction properties was measured until the breakdown occurs at temperature ranges from 30 to 110[$^{\circ}C$] and the electric field from 1$\times$10$^3$to 5$\times$10$^{6}$ [V/cm]. As for increase of temperature, the current density of LDPE was increased with constant ratio in low field, but changes with exponential function in high electric field. The tunnel current of pre-breakdown region is shifted toward low field as much as thermal excitation energy. At low electric field, the XLPE showed dominant electrical conduction properties by thermal excitation, and transformation of the electron was resisted by the crystal at high electric field.

• 한국환경복원기술학회지
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• 제24권2호
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• pp.71-84
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• 2021

Restoration of DMZ has come up with the discussion on the peaceful use of the DMZ and the conservation plan of the army. In this study, we aim to identify soil characteristics of 108 sites to figure out environmental conditions around the iron fence of DMZ where vegetation has been removed repeatedly. Based on the soil characteristics and climate variables, hierarchy clustering was performed to categorize sites. As a result, we categorized 108 sites into 4 types: middle elevation region, lowland, East coast lowland, other areas. Group of 'other area' is only high in nutrient and clay proportion. Others are in igneous rock and metamorphic rocks with a high proportion of sand and lower nutrients than the optimum range of growth in Korean forest soil. The middle elevation region has a high altitude, low temperature. The east coast lowland has a high temperature in January and low precipitation. The lowland has a low altitude and high temperature. This category provides the environmental condition around the DMZ fence and can be used to select plants for restoration. The restoration project around the DMZ iron fence should satisfy the security of military plans, which means that functional restoration is prior to ecological restoration such as vegetation management under a power line. Additionally, improvement of soil quality and surface stability through restoration projects is required to enhance the resilience of the ecosystem in DMZ.

• 설비공학논문집
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• 제16권4호
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• pp.311-317
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• 2004

In the present study, the cooling characteristics of the multi-air conditioner (A/C) using an inverter scroll compressor are experimentally investigated for the number of the indoor units and the operating conditions (2$0^{\circ}C$, 24$^{\circ}C$, 26$^{\circ}C$) under the cooling standard conditions by KS C 9306. In the case of the simultaneous operation for 3 indoor units, the cooling capacity, the mass flow rate and the input power have a decreasing trend and COP has an increasing trend, with decreasing the difference in the operating temperature of the indoor unit and the room temperature. In the case of the simultaneous operation for 2 indoor units, the COP of the indoor unit with large cooling capacity is high when the operating temperature is high, but the COP of the indoor unit with low cooling capacity is high when the operating temperature is low. In the case of the single operation for one unit, when the large cooling capacity of the indoor unit is less than 50％ the compressor operates at the minimum operation frequency region and the COP decreases.

• 설비공학논문집
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• 제7권1호
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• pp.89-97
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• 1995

Experimental study was performed for free convection and ice formation around two horizontal circular tubes which were placed vertically. Temperature and velocity distributions were visualized with real time holographic interferometry technique and tracer method. When water was cooled, super cooled region was formed around cooling pipe. It was found that flow induced by free convection always directed downwards when the coolant temperature was low, while it directed upwards when the coolant temperature was comparably high though it directed downwards initially. Flow phenomena with free convection were investigated in detail with varying cooling rate and length between cooling pipes. And growing process of dense ice was also investigated. Dendritic ice is suddenly formed within a supercooled region, and a dense ice layer begins to develop from the cooling wall.

• 설비공학논문집
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• 제16권1호
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• pp.70-76
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• 2004

High-temperature cylindrical sodium/stainless-steel heat pipes were manufactured and tested for transient as well as steady states. Total length of the heat pipe was 1 m and the diameter was 25.4 mm. Screen meshes of 3 different sizes were used to estimate the effect of mesh size on the thermal performance of the heat pipe. The minimum thermal resistance achieved was as low as 0.02$^{\circ}C$/W for the maximum thormal load of 2 ㎾. The average heat transfer coefficient in the evaporator was about 2,000 ㎾/$m^2$K and those in the condenser region were up to 5 times higher.

• 한국표면공학회지
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• 제14권4호
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• pp.215-220
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• 1981

The surface appearance of chromium electrodeposit was studied by employing a pulse curr-ent plating in self-regulating high speed (SRHS) bath containing 20 g/$\ell$, K2SiF6 7.5 g/$\ell$ SrSO4 and 250 g/$\ell$ CrO3. As the pulse frequency increased, the surface appearance changed suddenly from bright a-ppearance in a direct current plating condition to gray one in the range of pulse frequency less than about 20KHz. However the bright appearance is recovered as the pulse frequen-cy exceeded 20 KHz. This phenomena seemed to be related with the preferred orientation of electrodeposits, considering the relationship between the preferred orientation of elect-rodeposits and surface appearance in a SRHS bath. Direct current plating was also applied to both Sargent and SRHS bath and investigat-ion on surface appearance was extended to the high current density of 400 A/dm2. In a Sa-rgent bath, the increase in bath temperature was necessary for bright appearance as the current density was increased within 150 A/dm2, but bright region was shown in the cons-tant temperature of 70-75$^{\circ}C$ above the current density of 150A/dm2. On the other hand, two regions of surface brightness was found in a SRHS bath. One is region in the low temperature less than 25$^{\circ}C$ and the other in the moderate temperature range from 55$^{\circ}C$ to 65$^{\circ}C$.