• Title/Summary/Keyword: High Strength Nitrogen

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High Nitrogen Steel for Core of Over-head Transmission Line (가공송전선 코아용 고질소강 연구)

  • Kim, Bong-Seo;Yoo, Kyung-Jae;Kwon, Hae-Woong;Lee, Hee-Woong;Kim, Byung-Geol
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1555-1557
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    • 1998
  • In order to investigate the core material for over-head transmission line with non-magnetic and high strength nitrogen steel, microstructure and several basic properties of Fe-Mn-Cr-Ni-N steel have been studied. It is necessary that core material have a $\gamma$ phase to have a non-magnetic characteristics. To acquire a $\gamma$ phase, Mn, Ni and C are added as a alloying element. It was found that Fe-25Mn-16Cr-1Ni-N alloy have a stable $\gamma$ phase. The precipitate from this alloy system was $(Cr, Fe)_7C_3$. High Mn and N steel satisfies Sievert's relation that solubility of nitrogen increases with the square root of partial pressure of gas in metal-gas system and the hardness have proportional relation with nitrogen concentration.

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A Submerged Membrane Bioreactor with Anoxic-oxic Recycle for the Treatment of High-strength Nitrogen Wastewater

  • Shim, Jin-Kie;Yoo, Ik-Keun;Lee, Young-Moo
    • Korean Membrane Journal
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    • v.3 no.1
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    • pp.32-38
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    • 2001
  • Using the hollow fiber membrane module in a lab-scale membrane bioreactor, the anoxic- oxic (AO) process for nitrogen removal was operated for about one year. For the influent wastewater containing 1,200-1,400 mg $1^{-1}$ of CODcr and 200-310 mg $1^{-1}$ of nitrogen, this process achieved a high quality effluent of less than 30 mgCOD $liter^{-1}$ and 50 mgN $liter^{-1}$. The removal rate of organics was above 98% at a loading rate larger than 2.5 kgCOD $m^{-3}$$d^{-1}$. When the internal recycle from the oxic to the anoxic reactor changed room 2n to 600% rout the influent flow rate, the nitrogen removal rate increased from about 70 to 90% at a loading rate of 0.4 kgT-N m-s d-1. The initial increase of transmembrane pressure (TMP) was observed after a 4-month operation while maintaining the flux and MLSS concentration at 7-9 1 $m^2$ $h^{-1}$ and 6,000-14,000 mg $1^{-1}$, respectively. The TMP could be maintained below 15 cmHg for an 8-month operation. The chemical cleaning with an acid followed by an immersion in an alkali solution gave better cleaning result with the membrane operated for 10 month rather than that only by an alkali immersion.

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Development of the Fabrication Technology of High Tc Superconductor for Electrical Energy Storage (전기 에너지 저장을 위한 초전도 나노 합성 기술)

  • Lee, Sang-Heon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.9
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    • pp.442-445
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    • 2006
  • In order to realize the commercial application of HTSC materials, it is necessary to develop the fabrication process of high Tc oxide superconductor materials with desired shape and for practical application and high critical current density as well as good mechanical strength which can withstand high lorenz force generated at high magnetic field. Much studies have been concentrated to develop the fabrication technique for high critical current density but still there are a lot of gap which should be overcome for large scale application of HTSC materials at liquid nitrogen temperature. Recently some new fabrication techniques have been developed for YBaCuO bulk superconductor with high mechanical strength and critical current density. In this project, the establishment of fabrication condition and additive effects of second elements were examined so as to improve the related properties to the practical use of YBaCuO superconductor, and we reported the production of the YBaCuO high Tc superconductor by the pyrolysis method.

Cutting Characteristics and Deformed Layer of Type 316LN Stainless Steel (Type 316LN 스테인리스강의 절삭특성과 가공 변질층)

  • Oh, Sun-Sae;Yi, Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.2
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    • pp.196-205
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    • 2004
  • The cutting characteristics and the deformed layer of nitrogen(N)-added type 316LN stainless steel were comparatively investigated to type 316L stainless steel. The cutting force, the surface roughness(Ra) and the tool wear in face milling works were measured with cutting conditions, and the deformed layers were obtained from micro-hardness testing method. The cutting resistance of type 316LN was similar to type 316L in spite of its high strength. The surface roughness of type 316LN was superior to type 316L for all the cutting conditions. In particular, in the high cutting speed above 345m/min, the surface roughness of the two stainless steels was closely same. The deformed layer thickness of the two stainless steels was generated in the 150$\mu\textrm{m}$-300$\mu\textrm{m}$ ranges, and its value of type 316LN was lower than that of type 316L. This is due to the high strength properties by nitrogen effect. It was found that type 316LN was higher in the tool wear than that type 316L, and flank wear was dominant to crater wear. In face milling works of type 316LN steel, tool wear is regarded as a important problem.

Fabrication Technology of high Tc Superconductor for Electrical Equipment (전력기기 초전도 합성기술)

  • Lee, Sang-Heon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.7
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    • pp.364-366
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    • 2006
  • In order to realize the commercial application of HTSC materials, it is necessary to develop the fabrication process of high Tc oxide superconductor materials with desired shape and for practical application and high critical current density as well as good mechanical strength which can withstand high lorenz force generated at high magnetic field. Much studies have been concentrated to develop the fabrication technique for high critical current density but still there are a lot of gap which should be overcome for large scale application of HTSC materials at liquid nitrogen temperature. Recently some new fabrication techniques have been developed for YBaCuO bulk superconductor with high mechanical strength and critical current density. In this project, the establishment of fabrication condition and additive effects of second elements were examined so as to improve the related properties to the practical use of YBaCuO superconductor, and we reported the production of the YBaCuO high Tc superconductor by the pyrolysis method.

Microstructure and High Temperature Deformation Behavior of Heat Resistant Stainless Steel for a Retort (열환원반응관용 내열강의 미세조직과 고온변형거동)

  • Choi, G.S.;Ha, T.K.
    • Transactions of Materials Processing
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    • v.22 no.3
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    • pp.165-170
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    • 2013
  • High temperature deformation behavior of a heat-resistant duplex stainless steel, used as a retort in the Pidgeon process for Mg production, was investigated in this study. 25Cr-8Ni based duplex stainless steels were cast into rectangular ingots, with dimensions of $350mm{\times}350mm{\times}100mm$. Nitrogen and yttrium were added at 0.3wt.% each to enhance the heat-resistance of the steel. Phase equilibrium was calculated using the thermodynamic software FactSage$^{(R)}$ and the database of FSStel. For comparison, cast 310S steel, a widely used heat-resistant austenitic stainless steel, was also examined in this study. Dilatometry was conducted on the as-cast ingots for the temperature range from RT to $1200^{\circ}C$ and the thermal expansion coefficients were evaluated. The nitrogen addition was found to have an effect on the thermal expansion behavior for temperatures between 800 and $1000^{\circ}C$. High temperature tensile and compression tests were conducted on the ingots for temperatures ranging from 900 to $1230^{\circ}C$, which is the operation temperature employed in Mg production by the Silico-thermic reduction process. The steel containing both N and Y showed much higher strength as compared to 310S.

Characteristics of Electomigration & Surface Hardness about Tungsten-Carbon-Nitrogen(W-C-N) Related Diffusion Barrier (W-C-N 확산방지막의 전자거동(ElectroMigration) 특성과 표면 강도(Surface Hardness) 특성 연구)

  • Kim, Soo-In;Hwang, Young-Joo;Ham, Dong-Shik;Nho, Jae-Kue;Lee, Jae-Yun;Park, Jun;Ahn, Chan-Goen;Kim, Chang-Seong;Oh, Chan-Woo;Yoo, Kyeng-Hwan;Lee, Chang-Woo
    • Journal of the Korean Vacuum Society
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    • v.18 no.3
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    • pp.203-207
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    • 2009
  • Copper is known as a replacement for aluminum wire which is used for semiconductor. Because specific resistance of Cu ($1.67{\mu}{\Omega}$-cm) is lower than that of Al ($2.66{\mu}{\Omega}$-cm), Cu reduce RC delay time. Although melting point of Cu($1085^{\circ}C$) is higher than melting point of Al, Cu have characteristic to easily react with Silicon(Si) in low temperature, and it isn't good at adhesive strength with Si. For above these reason, research of diffusion barrier to prevent reaction between Cu and Si and to raise adhesive strength is steadily advanced. Our study group have researched on W-C-N (tungsten-carbon-nitrogen) Diffusion barrier for preventing diffusion of Cu through semiconductor. By recent studies, It's reported that W-C-N diffusion barrier can even precent Cu and Si diffusing effectively at high temperature. In this treatise, we vaporized different proportion of N into diffusion barrier to research Cu's Electromigration based on the results and studied surface hardness in the heat process using nano scale indentation system. We gain that diffusion barrier containing nitrogen is more stable for Cu's electromigration and has stronger surface hardness in heat treatment process.

Study on the Breakdown Performance of Synthetic Polypropylene Laminated Paper for Application of a HTS Cable (고온초전도 케이블의 응용을 위한 PPLP의 절연파괴 특성연구)

  • Kwag, Dong-Soon;Kim, Young-Seok;Kim, Hae-Jong;Kim, Sang-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05e
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    • pp.65-68
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    • 2003
  • In this paper, we researched breakdown characteristics of paper/liquid nitrogen composite insulation system for application of a high temperature superconducting cable. And, we have studied the AC breakdown performance of paper/ice composite insulating system immersed in liquid nitrogen. The electric strength in this paper/ice composite system is higher than that of paper/liquid nitrogen system. Furthermore this system shows a self-healing type breakdown behavior. Among the many kinds of liquid to be immersed and frozen to the ice, deionized water gives the highest electric breakdown strength. The paper/ice composite insulation system is thought to be one of good candidate for the electrical insulating system at cryogenic temperature.

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High-Rate Biological Nitrogen Removal from Plating Wastewater using Submerged MBR Packed with Granular Sulfur (황 충진 MBR을 이용한 도금폐수의 고효율 생물학적 질소 제거)

  • Kim, Dae-young;Moon, Jin-young;Baek, Jin-uk;Hwang, Yong-woo
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.2
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    • pp.200-208
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    • 2005
  • In this study, a new submerged membrane bioreactor process packed with granular sulfur (MBR-GS) was operated to identify the biological nitrogen removal behaviors with plating wastewater containing high-strength $NO_3{^-}$ concentration. The continuous denitrification was carried out at $20^{\circ}C$ with various nitrogen loading rates using synthetic wastewater, which composed of $NO_3{^-}$ and $HCO_3{^-}$, but also actual plating wastewater, which was collected from the effluent of the H metal plating company. As a result, high-rate denitrification in the range of $0.8kg\;NO_3{^-}-N/m^3\;day$ was accomplished at nitrogen loading rate of $0.9kg\;NO_3{^-}-N/m^3\;day$ using synthetic wastewater. Also, higher-rate denitrification with actual plating wastewater was achieved up to $0.91kg\;NO_3{^-}-N/m^3\;day$ at the loading rate of $1.11kg\;NO_3{^-}-N/m^3\;day$. Additionally, continuous filtration was possible during up to 30 days without chemical cleaning in the range of 20 cmHg of transmembrane pressure. On the basis of the proposed stoichiometry, ${SO_4}^{2-}$ production could be estimated efficiently, while observed alkalinity consumption was somewhat lower than theoretical value. Consequently, a new process, MBR-GS is capable of high-rate autotrophic denitrification by compulsive flux and expected to be utilized as an alternative of renovation techniques for nitrogen removal from not only plating wastewater but also municipal wastewater with low C/N ratio.

A Study on the Electrical Strength of Insulating Materials for High-Tc Superconducting Devices

  • Bae, Duck Kweon;Kim, Chung-Hyeok;Pak, Min-Sun;Oh, Yong-Cheul;Kim, Jin-Sa;Shin, Cheol-Gee;Lee, Joon-Ung;Song, Min-Jong;Choi, Woon-Shik
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.6
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    • pp.294-300
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    • 2005
  • According to the trend for electric power equipment of high capacity and reduction of its size, the needs for the new high performance electric equipments become more and more important. On of the possible solution is high temperature superconducting (HTS) power application. Following the successful development of practical HTS wires, there have been renewed activities in developing superconducting power equipment. HTS equipments have to be operated in a coolant such as liquid nitrogen ($LN_2$) or cooled by conduction-cooling method such as using Gifford-McMahon (G-M) cryocooler to maintain the temperature below critical level. In this paper, the dielectric strength of some insulating materials, such as unfilled epoxy, filled epoxy, and polyimide in $LN_2$ was analyzed. Epoxy is a good insulating material but fragile at cryogenic temperature. The filled epoxy composite not only compensates for this fragile property but enhances its dielectric strength.