• Title/Summary/Keyword: High Resistivity

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Microstructures and Hall Properties of p-type Zno Thin Films with Ampouele-tube Method of P and As (Ampoule-tube 법을 이용한 P와 As 도핑 p형 ZnO 박막의 미세구조와 Hall 특성)

  • So, Soon-Jin;Lim, Keun-Young;Yoo, In-Sung;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.141-142
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    • 2005
  • To investigate the ZnO thin films which is interested in the next generation of short wavelength LEDs and Lasers, our ZnO thin films were deposited by RF sputtering system. At sputtering process of ZnO thin films, substrate temperature, work pressure respectively is $300^{\circ}C$ and 5.2 mTorr, and the purity of target is ZnO 5N. The thickness of ZnO thin films was about $1.9{\mu}m$ at SEM analysis after sputtering process. Phosphorus (P) and arsenic (As) were diffused into ZnO thin films sputtered by RF magnetron sputtering system in ampoule tube which was below $5\times10^{-7}$ Torr. The dopant sources of phosphorus and arsenic were $Zn_3P_2$ and $ZnAs_2$. Those diffusion was perform at 500, 600, and $700^{\circ}C$ during 3hr. We find the condition of p-type ZnO whose diffusion condition is $700^{\circ}C$, 3hr. Our p-type ZnO thin film has not only very high carrier concentration of above $10^{19}/cm^3$ but also low resistivity of $5\times10^{-3}{\Omega}cm$.

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Electrochemical Characteristics of Carbon/Carbon Hybrid Capacitor and Li-ion Battery/Hybrid Capacitor Combination (Carbon계 Hybrid Capacitor의 전기 화학적 기술 및 Li-ion Battery의 혼성 동력원 특성)

  • Lee, Sun-Young;Kim, Ick-Jun;Moon, Seong-In
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.597-598
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    • 2005
  • Recently, the performance of portable electric equipment can often improved by a Li-ion battery assisted by a supercapacitor. A supercapacitor can provide high power density as well as a low resistance in the hybrid system. In this study, we have prepared, as the pluse power souce, a commercially supplied Li-ion battery with a capacity of 700mAh and AC resistivity of $60m\Omega$ at 1kHz and nonaqeous asymmetric hybrid capacitor composed of an activated carbon cathode and MCMB anode, and have examined the electrochemical characteristics of hybrid capacitor and the pulse performances of parallel connected battery/hybrid capacitor source. The nonaqueous asymmetric hybrid capacitor, the stacks of 10 pairs of the cathode, the porous separator and the anode electrode were housed in Al-laminated film cell. The hybrid capacitor, which was charged and discharged at a constant current at $0.25mA/cm^2$ between 3 and 4.3V, has exhibited the capacitance of 100F. And the equivalent series resistance was $32m\Omega$ at 1kHz. By combining a Li-ion battery and a hybrid capacitor, the pulse performance of battery can be improved 23% in run time under a pulse discharge of 7C-rate.

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Realization of p-type Conduction in Antimony Doped ZnO Thin Films by PLD (PLD를 이용한 Antimony가 도핑된 p 형 ZnO 박막의 구현)

  • Bae, Ki-Ryeol;Lee, Dong-Wook;Elanchezhiyan, J.;Lee, Won-Jae;Bae, Yun-Mi;Shin, Byoung-Chul;Kim, Il-Soo;Shan, F.K.
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.10
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    • pp.814-820
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    • 2009
  • Antimony (Sb) doped ZnO thin films (0.1 at.%) were deposited on sapphire (0001) substrates at various temperatures (200 - 600$^{\circ}C$) by using pulsed laser deposition technique. All the thin films have been characterized by X-ray diffractometer, atomic force microscopy and spectrophotometer to investigate their structural, morphological and optical properties, respectively. Hall measurements were also carried out to identify the electrical properties of the thin films. These thin films were constituted in wurtzite structure with the preferential orientation of (002) diffraction plane and had as high as 80% optical transmission in the visible range. The bandgap energy also was determined by spectrophotometer which was around 3.28 eV. Hall measurements results revealed that the Sb dope ZnO thin film (0.1 at.%) grown at $500^{\circ}C$ exhibited p-type conduction with a carrier concentration of $8.633\times10^{16}\;cm^{-3}$, a mobility of $1.41\;cm^2/V{\cdot}s$ and a resistivity of $51.8\;\Omega{\cdot}cm$. We have successfully achieved p-type conduction in antimony doped ZnO thin films with low doping level even though the electrical properties are not favorable. This paper suggests the feasibility of p-type doping with large-size-mismatched dopant by using pulsed laser deposition.

Comparison of characteristics of IZO-Ag-IZO and IZO-Au-IZO multilayer electrodes for organic photovoltaics

  • Jeong, Jin-A;Choi, Kwang-Hyuk;Park, Yong-Seok;Park, Ho-Kyun;Kim, Han-Ki
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.131-131
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    • 2010
  • We compared the electrical, optical, structural, and interface properties of indium zinc oxide (IZO)-Ag-IZO and IZO-Au-IZO multilayer electrodes deposited by linear facing target sputtering system at room temperature for organic photovoltaics. The IZO-Ag-IZO and IZO-Au-IZO multilayer electrodes show a significant reduction in their sheet resistance (4.15 and 5.49 Ohm/square) and resistivity ($3.9{\times}10^{-5}$ and $5.5{\times}10^{-5}$Ohm-cm) with increasing thickness of the Ag and Au layers, respectively. In spite of its similar electrical properties, the optical transmittance of the IZO-Ag-IZO electrode is much higher than that of the IZO-Au-IZO electrode, due to the more effective antireflection effect of Ag than Au in the visible region. In addition, the Auger electron spectroscopy depth profile results for the IZO/Ag/IZO and IZO/Au/IZO multilayer electrodes showed no interfacial reaction between the IZO layer and Ag or Au layer, due to the low preparation temperature. To investigate in detail the Ag and Au structures on the bottom IZO electrode with increasing thickness, a synchrotron x-ray scattering examination was employed. Moreover, the OSC fabricated on the IZO-Ag-IZO electrode shows a higher power conversion efficiency (3.05%) than the OSC prepared on the IZO-Au-IZO electrode (2.66%), due to its high optical transmittance in the wavelength range of 400-600 nm, which is the absorption wavelength of the P3HT:PCBM active layer.

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Evaluation of Dynamic Ground Properties of Pohang Area Based on In-situ and Laboratory Test (현장실험 및 동적실내실험을 이용한 포항지역 동적 지반특성 평가)

  • Kim, Jongkwan;Kwak, Tae-Young;Han, Jin-Tae;Hwang, Byong-Youn;Kim, Ki-Seog
    • Journal of the Korean Geotechnical Society
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    • v.36 no.9
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    • pp.5-20
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    • 2020
  • In 2017, after the Pohang earthquake, liquefaction phenomena were firstly observed after the observation of domestic earthquake by epicenter. In this study, various in-situ tests and laboratory tests were performed to determine the dynamic properties in (1) Songlim Park, (2) Heunghae-eup, Mangcheon-ri and (3) Heungan-ri, Pohang. As a site investigation, the standard penetration test (SPT), cone penetration test (CPT), multichannel analysis of surface wave (MASW), density logging, downhole test, and electrical resistivity survey were performed. In addition, cyclic triaxial test against sampled sand from site was also conducted. Based on the result, high ground water level and loose sand layer in shallow depth were observed for all sites. In addition, liquefaction resistance ratio of soil sampled from Songlim park was lower than those of Jumunjin sand, Toyoura sand, and Ottawa sand.

EO Characteristics of the ion Beam Aligned TN-LCD on the NDLC Thin Film Surface (NDLC 박막 위에 Ion Beam 배향한 TN-LCD의 전기광학특성)

  • Park, Chang-Joon;Hwang, Jeoung-Yeon;Kang, Hyung-Ku;Ahn, Han-Jin;Kim, Kyung-Chan;Kim, Jong-Bok;Baik, Hong-Koo;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1054-1057
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    • 2004
  • The nitrogenated diamond-like carbon (NDLC) exhibits high electrical resistivity and thermal conductivity that are similar to the properties shown by diamond-like carbon (DLC) films. These diamond-like transparent properties in NDLC come in a material consisting of $sp^2$-bonded carbon versus the $sp^3$-carbon of DLC. The diamond-like properties and nondiamond-like bonding make NDLC an attractive candidate for applications. Liquid crystal (LC) alignment capabilities with ion beam exposure on NDLC thin films and electro-optical (EO) performances of the ion-beam-aligned twisted nematic liquid crystal display (TN-LCD) with oblique ion beam exposure on the NDLC thin film surface were studied. An excellent uniform alignment of the nematic liquid crystal (NLC) alignment with the ion beam exposure on the NDLC thin films was observed. In addition, it can be achieved that the good EO properties of the ion-beam-aligned TN-LCD. Finally, we will present the residual DC property of the ion-beam-aligned TN-LCD on the NDLC thin film surface.

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Enhancement of Electrical Conductivity in Silver Nanowire Network for Transparent Conducting Electrode using Copper Electrodeposition (구리 전기도금 방법을 이용한 은 나노와이어 투명전극의 전기전도도 향상)

  • Ji, Hanna;Jang, Jiseong;Lee, Sangyeob;Chung, Choong-Heui
    • Korean Journal of Materials Research
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    • v.29 no.5
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    • pp.311-316
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    • 2019
  • Transparent conducting electrodes are essential components in various optoelectrical devices. Although indium tin oxide thin films have been widely used for transparent conducting electrodes, silver nanowire network is a promising alternative to indium tin oxide thin films owing to its lower processing cost and greater suitability for flexible device application. In order to widen the application of silver nanowire network, the electrical conductance has to be improved while maintaining high optical transparency. In this study, we report the enhancement of the electrical conductance of silver nanowire network transparent electrodes by copper electrodeposition on the silver nanowire networks. The electrodeposited copper lowered the sheet resistance of the silver nanowire networks from $21.9{\Omega}{\square}$ to $12.6{\Omega}{\square}$. We perform detailed X-ray diffraction analysis revealing the effect of the amount of electrodeposited copper-shell on the sheet resistance of the core-shell(silver/copper) nanowire network transparent electrodes. From the relationship between the cross-sectional area of the copper-shell and the sheet resistance of the transparent electrodes, we deduce the electrical resistivity of electrodeposited copper to be approximately 4.5 times that of copper bulk.

Smelting of Platinum Group Metals and Recycling of Spent Catalyst (백금족 금속의 제련과 폐촉매의 리사이클링)

  • Son, Injoon;Sohn, Ho-Sang
    • Resources Recycling
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    • v.30 no.3
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    • pp.18-29
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    • 2021
  • Platinum group metals (PGMs) are used in a wide range of application fields such as catalysts, electronic devices, electrodes, electrical devices, fuel cells and high temperature materials due to their excellent electrical and thermal conductivity as well as chemical resistivity. Platinum group elements are generally associated with nickel-copper sulfides in magmatic rocks. Depending on the relative concentrations of the PGMs, they are produced either as the primary products or as by-products of the nickel and copper. However, PGMs natural resource deposits are strictly limited in countries such as South Africa and Russia. The annual supply of PGMs is only under 500 t. Considering the limited supply of PGMs, there will be a noticeable increase in the supply risk associated with PGMs in the near future. Therefore, it is extremely important to recover PGMs from secondary resources such as spent catalysts. This paper reviews on overview of PGMs extraction and recycling processes.

Literature Review on Material Development and Performance Evaluation Method for EMP Shielding Concrete (EMP 차폐 콘크리트 개발 및 성능평가 방법에 관한 문헌 연구)

  • Lee, Woong-Jong;Lee, Hwan;Kim, Young-Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.12
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    • pp.67-76
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    • 2020
  • The purpose of this study was to derive the directionality of technology development of high-power electromagnetic pulse (EMP) shielding concrete and standardization of a shielding performance evaluation method. Because the EMP shielding mechanism of concrete has not been identified clearly, and the verification method for EMP shielding performance has not been standardized, it is difficult to compare the research results between researchers. The development direction of EMP shielding concrete was derived from a consideration of the electromagnetic wave loss mechanism of metal. The standardization direction for verifying the EMP shielding performance of concrete was derived from a consideration of the electrical properties of concrete and the shielding performance evaluation methods of previous studies. As a result, the development of electrically conductive concrete is required, and test methods classified by the electromagnetic wave loss mechanism should be applied. For quality verification, the development of EMP shielding concrete will be feasible and its performance can be evaluated if a test method referencing the generalized shielding evaluation method (MIL-STD, etc.) is applied.

A study on the effective fault current limiting characteristics of stacked coated conductors with stainless steel stabilizer (스테인리스 스틸 안정화재를 가진 coated conductor의 적층 유무에 따른 효과적인 사고전류 제한을 위한 연구)

  • Na, J.B.;Ahn, M.C.;Kim, M.J.;Kim, Y.J.;Yang, S.E.;Park, D.K.;Kim, H.M.;Seok, B.Y.;Ko, T.K.
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.1
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    • pp.9-13
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    • 2007
  • Coated conductor(CC) is recently in actively progress for the research and development, and its can be used various stabilizer lot the specific requirements for each application. Among various superconducting applications, coated conductor applied to superconducting fault current limiters(SFCLS) bypasses fault current to its stabilizer, where the surge is abruptly reduced ; thus, stainless steel, which has large resistivity can be a suitable stabilizer for SFCLS. Despite high n-value of the YBCO, CC stabilized with stainless steel did not effectively limit the first peak fault current. In the short circuit test results of AMSC's 344S, a half period delay was observed between the fault and the generation of resistance(60Hz). In this paper, we performed short-circuit experiments with stacked and unstacked CC and compared the test results to analyze effective fault current limiting characteristics. we compared time of the generated resistance as the fault current limiting characteristics and made the samples one is the stacked CC and the other is unstacked CC. These samples were used equal numbers of pieces of CC. In addition, comparison and analysis was made for the stacked structure by measuring fault current limiting characteristics with respect to thermal insulation by impregnating with epoxy resin.