• Title/Summary/Keyword: High Refractive

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Physical Properties of Styrene Copolymer and Contact Lens Application (스타이렌 공중합체의 물리적 특성 및 콘택트 렌즈로의 응용)

  • Kim, Tae-Hun;Ye, Ki-Hun;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.53 no.6
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    • pp.755-760
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    • 2009
  • Styrene is broadly used as a polymer and a copolymer and is useful in manufacturing contact lenses due to its high refractive index. This study used styrene with the cross-linker EGDMA (ethylene glycol dimethacrylate), HEMA (2-hydroxyethyl methacrylate) and the initiator AIBN (azobisisobutyronitrile) for copolymerization. Measurement of the physical characteristics of the copolymerized material showed that the refractive index is 1.4412 - 1.4628, water content 20 - 35%, visible transmittance 82.6 - 87% and the tensile strength 0.143 - 0.344 Kgf. Also, measurements showed that the refractive index and tensile strength increased while the water content decreased as the ratio of styrene increased. Based on the results of this study, the produced copolymer can be estimated to be suitable for use as a material for high performance functional contact lenses.

Proposal and Analysis of Characteristics of a Refractive Index Modulated Distributed Feedback Laser Diode (Refractive Index Modulated Distributed Feedback Laser Diode의 제안과 특성해석)

  • 김홍국;이홍석;김부균;김병호
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.5
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    • pp.88-98
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    • 1999
  • A refractive index modulated (RIM) DFB laser, in which the refractive index of a center region of the upper cladding layer comprising the grating region is different from that of side regions, is proposed to obtain and effective ${\lambda}$/4 phase shift in the center region. Since the coupling coefficient of a center region in a RIM-DFB laser is larger than that of side regions, a RIM-DFB laser has the effect of a distributed coupling coefficient. Simulation results show that RIM-DFB lasers have better operation characteristics - more uniform photon density profile, less SHB effect, and better single mode operation at high injection currents - compared to those of ${\lambda}$/4 phase-shifted DFB lasers and CPM-DFB lasers. In addition, the effect of the center region on the above threshold characteristics of a RIM-DFB laser is investigated.

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Synthesis of UV Curable 4,4'-Thiodibenzenethiol-based Epoxy Acrylate and Their Refractive Index Behavior (4,4'-Thiodibenzenethiol을 이용한 광경화형 에폭시 아크릴레이트 합성과 굴절률에 관한 연구)

  • Baek, Seung-Suk;Lee, Sang Won;Hwang, Seok-Ho
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.121-126
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    • 2013
  • UV-curable high refractive index di-functional epoxy acrylate, 4,4'-thiodibenzenethiol diglycidyl ether diacrylate, was synthesized from acrylic acid and 4,4'-thiodibenzenethiol diglycidyl ether that was obtained by reacting 4,4'-thiodibenzenethiol and epichlorohydrin using a direct method (Taffy process). Its chemical structure was identified by $^1H$ NMR and FTIR. After its dilution with a reactive diluent, 2-phenoxythiol ethyl acrylate as 5, 10, 15, 20, and 30 wt% content, the relationship between their viscosity and refractive index was investigated. Their degree of cure decreased with increasing the amount of reactive diluent, and the refractive index of UV-cured film increased with increasing the degree of cure.

Investigation of the Light Reflection from Dielectric Thin Films Coated on Substrates (기판 위에 입혀진 유전체 박막의 빛 반사에 관한 연구)

  • Kim, Deok Woo;Kim, Jiung;Kim, Byoung Joo;Cha, Myoungsik
    • Korean Journal of Optics and Photonics
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    • v.31 no.6
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    • pp.321-327
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    • 2020
  • We investigated the light reflection from thin films coated on substrates. Using a prism with a high refractive index as the incident medium, the phenomena of the total internal reflection (TIR) of the prism/film/substrate system and the light coupling into the optical waveguide formed by the air/film/substrate system were comprehensively studied and compared. If the refractive index of the thin film is greater than that of the substrate, within the TIR region of the substrate, sharp reflection minima occur at specific angles where the waveguide modes are excited, that can be used to accurately measure the refractive index and thickness of a thin film. On the other hand, if the refractive index of the thin film is smaller than that of the substrate, such waveguide modes do not exist. In this case, although not so distinct as a bulk medium, the TIR effect of the thin film is still observable, accompanied by an interference pattern. In this study we analyzed the overall reflection phenomena occurring from prism/film/substrate structures, to investigate the possibility of measuring the refractive index of a thin film in both cases.

A Study of Eye Refractive Error for High School Students in Tong-Du-Cheon Area ;(II) (동두천지역 고등학생의 안굴절상태 조사 및 연구 II)

  • Choi, Hae Jung;Cha, Jung Won;Park, Moon Chan;Chen, Ko Hsein
    • Journal of Korean Ophthalmic Optics Society
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    • v.3 no.1
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    • pp.103-113
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    • 1998
  • Until now, the study of eye refractive error examination for high school students are a few report that in Korea. In particular, there is few report about the visual power for same group during several years. We compared the study of refractive error done this year with that reported three years ago at the same high school. From the these data, the distribution of ammetropia was investigated. The study of refractive error for high school students was also compared with those reported before for the Adults and the middle school student. When the visual power is refered to spherical equivalent, the 36% of the whole students examined above had emmetropia and the other part of them fumed out to be ammetropia which is classify to 60.6% belonged to myopia and 4.4% belonged to hyperpia. The ratio of myopia for this year students is increased in comparision with the students in 1995. The ratio of emmetropia for this year students is 7.4% higher, and the ratio of myopia for this year students is 4% higher, but the ratio of hyperopia is very lower than that for the adults in 1997. In the kind of refractive error, it is classified that a simple myopia is shown to highest ratio as a 28.6% of 1212 eyes examined, a compound myopic astigmatism to the next high ratio as a 22.4%, a simple myopic astigmatism as 14.4%, a simple hyperopic astigmatism as 3.1%, a mixed astigmatism as a 1.7%, a simple astigmatism as 1.2%, a compound hyperopic astigmatism as 1.2%, respectively. The percentage of an astigmatism is a 76.7% of total eyes examined if Cyl-0.25 Dptr is included to an astigmatism. On the other hand, The percentage of an astigmatism is a 45.6% of total eyes examined if Cyl-0.25 Dptr is excluded to an astigmatism. In the kind of astigmatism, the number of students had an astigmatism with the rule is about 4.5 times than that of astigmatism against the rule. From the result of comparision the right eye with the left eye, the right eye of the students had more a myopic refractive error than the left eye, which is same as adults' case, there is no difference in a refractive error between the boy students and the girl students.

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ARAS coating with a conducting polymer (전도성 고분자를 이용한 ARAS 코팅)

  • 김태영;이보현;김종은;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.1039-1042
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    • 2001
  • A method for designing antireflection (AR) and antistatic (AS) films by the use of conducting polymer as an electrically conductive transparent layer is proposed. The conducting AR film is composed of four-layer with alternating high and low refractive index layer: silicon dioxide (n=1.44) and titanium dioxide (n=2.02) prepared at low temperature by sol-gel method are used as the low and high refractive index layer, respectively. The 3,4-polyethylenedioxythiophene (PEDOT) which has the sheet resistance of 10$^4$$\Omega$/$\square$ is used as a conductive layer. Optical constant of ARAS film was measured by the spectroscopic ellipsometer and from the measured optical constants the spectral properties such as reflectance and transmittance were simulated in the visible region. The reflectance of ARAS films on glass substrate was below 0.8 %R and the transmittance was higher than 95 % in the visible wavelength (400-700 nm). The measured AR spectral properties was very similar to its simulated results.

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Stability of High Internal Phase Emulsions

  • Park, C.I.;Cho, W.G.
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.25 no.4 s.34
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    • pp.65-74
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    • 1999
  • We have studied the stability of W/O high internal phase emulsions(HIPE) containing water, cetyl dimethicone copolyol and oils varying magnesium sulfate in the range 0 to 0.5 wt% and oil polarities, respectively. The rheological consistency was mainly destroyed by the coalescence of the deformed water droplets. The greater the increase of complex modulus was, the less coalescence occurred and the more consistent the concentrated emulsions were. The increasing pattern of complex modulus versus volume fraction has been explained with the resistance to coalescence of the deformed interfacial film of water droplets in concentrated W/O emulsion. The stability is dependent on: (i) the choice of the oil is important, the requirements coincide with the requirements for the formation of the rigid liquid crystalline phases; and (ii) addition of salts the aqueous phase opposes the instability due to coalescence. Increasing the salt concentration increases the refractive index of the aqueous phase. It lowers the difference in the refractive index between the oil and aqueous phases. This decreases the attraction between the water domains, thus increasing the stability.

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Solid Immersion Lens Microscope for Spectroscopy of Nanostructure Materials

  • Yim, Sang-Youp;Kim, Joon-Heon;Lee, Jong-Min
    • Journal of the Optical Society of Korea
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    • v.15 no.1
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    • pp.78-81
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    • 2011
  • We demonstrate a high-spatial-resolution imaging and spectroscopy tool using a solid immersion lens (SIL), a hemispherical lens made of high refractive index glass (n ~2). Photoluminescence (PL) images of single CdSe nanocrystals confirm a numerical aperture enhancement factor of ~2, close to the refractive index of the SIL. In particular, a bare-eye observation of PL signals emitted by single nanocrystals with ${\sim}10\;{\mu}m^{-2}$ densities was possible over an ${\sim}30\;{\mu}m$ diameter region. In addition, the PL spectra of single CdSe nanocrystals were successfully measured at room temperature. Thus, this SIL microscope ensures a simple but powerful method for nanostructure spectroscopy.

Stability of High Internal Phase Emulsions

  • Park, C-I.;W-G. Cho
    • Proceedings of the SCSK Conference
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    • 1999.10a
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    • pp.65-74
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    • 1999
  • We have studied the stability of W/O high internal phase emulsions(HIPE) containing water, cetyl dimethicone copolyol and oils varying magnesium sulfate in the range 0 to 0.5wt% and oil polarities, respectively. The rheological consistency was mainly destroyed by the coalescence of the deformed water droplets. The greater the increase of concentrated modulus was, the less coalescence occurred and the more consistent the concentrated emulsions were. The increasing pattern of complex modulus versus volume fraction has been explained with the resistance to coalescence of the deformed interfacial film of water droplets in concentrated W/O emulsion. The stability is dependent on: (i) the choice of the oil is important, the requirements coincide with the requirements for the formation of the rigid liquid crystalline phases :5; and (ii) addition of salts the aqueous phase opposes the instability due to coalescence:. Increasing the salt concentration increases the refractive index of the aqueous phase. It lowers the difference in the refractive index between the oil and aqueous phases. This decreases the attraction between the water domains, thus increasing the stability.

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Change of Refractive Index and Residual Stresses of Ta2O5 Thin Film Prepared by Dual Ion Beam Sputtering Deposition as the Substrate Temperature and Assist ion Beam Energy (이중 이온빔으로 제작한 Ta2O5 박막의 기판 온도 및 보조 이온빔 에너지에 따른 굴절률과 판류응력의 변화)

  • Yeon, Seok-Gyu;Kim, Yong-Tak;Kim, Hwek-Yung;Kim, Myoung-Jin;Lee, Hyung-Man;Yoon, Dae-Ho
    • Journal of the Korean Ceramic Society
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    • v.42 no.1
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    • pp.28-32
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    • 2005
  • The optical properties and intrinsic stress of $Ta_{2}O_{5}$ thin films deposited by Dual ion-Beam Sputtering: (DIBS) and Single ion-Beam Sputtering (SIBS) were studied as a function of the substrate temperature and assist ion beam voltage. The refractive index showed the maximum value (n = 2.144) at $150^{circ}C$ in the SIBS process. When the substrate temperature has above $150^{circ}C$ in the SIBS process the refractive index decreased. In the DIBS process, the increase of the substrate temperature affected the increase of the refractive index at a maximum value (n = 2.1117, at $200^{circ}C$). The low temperature process $(<100^{circ}C)$ can greatly reduce residual stress with the assist ion gun, but the high temperature process was unaffected. As the assist ion beam voltage increase from 250 to 350 V the refractive index increased to 2.185. However, the refractive index was decreased at the range of 350-650 V, As the assist ion beam voltage increased, the stress of the deposited film decreased to 0.1834 GPa at 650 V.