• Title/Summary/Keyword: High Polymer

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Synthesis and Antibiotic activity of Dextran-Phthalysulfathiazole (Dextran-Phthalylsulfathiazole의 합성과 항균성)

  • 김판기;이기창;황성규;오세영
    • Journal of Food Hygiene and Safety
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    • v.12 no.3
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    • pp.228-233
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    • 1997
  • Drug Dclivcry system (DDS) purpose to getting better remedial result by improving medication from ordinary methods. Applied for DDS, to improve selectivity and comtinuity during absorbing and delivery step, polmer drug (prodrug) was prepared by the esterification with dextran in such of biodegradable polymer and phthalylsulfathiazole with is efficient for entilitis. The polymer durg was prepared with dextran and phthalylsulfathiazole by the esterification. The synthetic procedures of polymer drug was performed by acid chloride and DCC methods. Polymer drug was synthesized in high yield by acid chloride method than DCC method. The antibiotic activities of polymer drug exhibited growth-inhibitory activity against Staphylococcus aureus, Staphylococcus epidermidis, E. coli, Salmonella typhimurium, Klebsiella pneumoniae at the concentration of 500 *g/m* in general through in vitro. As a result of test, polymer drug has 1/2 MIC than phthalylsulfathiazole. Also, it has high level MIC as much as phthalylsulfathiazole with Proteus, Pseudomonas. We conducted possibility of DDS as an applied for medicine with synthesized polymer drug by using natrural polymer. We consider that clinical research must be followed to verify safety and efficacy for controlled release, activity and toxicity.

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Study on Electro-optic Characteristics of the Optically Compensated Bend Liquid Crystal Display Using UV Curable Monomer (광경화성 단분자를 이용한 광학 보상 휨 액정 디스플레이의 전기광학 특성연구)

  • Lim, Young-Jin;Jeon, Eun-Jeong;Kwon, Dong-Won;Kim, Jeong-Hwan;Jeong, Kwang-Un;Lee, Myong-Hoon;Lee, Seung-Hee
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.496-500
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    • 2009
  • Optically compensated bend liquid crystal display (OCB-LCD) has many application fields owing to its fast response time and wide viewing angle. However, in order to operate the OCB-LCD in bend state, this device needs quick transitions from the initial splay state to bend state. Unlike conventional approach using transient high voltage for the transition, the OCB-LCD with high surface tilt angle, which was achieved by polymerization of UV curable reactive mesogen monomer under certain voltage, was manufactured and the cell showed bend state initially. Electro-optic and electrical characteristics of the cell were analyzed. The cell shows a fast response time owing to high surface pretilt angle and very low residual DC less than 0.1 V although another polymer layer is formed above polymer alignment layers.

Electrospun $SiO_2$ membrane using covalently cross-linked SPEEK/HPA by impregnation for high temperature PEMFC

  • Na, Heesoo;Hwang, Hyungkwon;Lee, Chanmin;Shul, Yonggun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.85.2-85.2
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    • 2010
  • There is widespread effort to develop polymer membranes in place of Nafion for high temperature polymer electrolyte membrane fuel cell(PEMFC). In our study, SiO2 membranes are arranged by electrospinning method. For impregnation solution, the modified sulfonated poly(ether ether ketone)(SPEEK) polymer is prepared from sulfonation, sulfochlorination, partial reduction and lithiation reaction. The modified polymer is cross-linked with 1,4-diiodobetane in NMP solvent and then blended with Heteropoly acid(HPA). The characterization of membranes is confimed by FT-IR, Thermogravimetry(TGA), water uptake test and single cell performance test for PEMFC, etc. The composite membrane shows satisfactory thermal and mechanical properties. Beside, The membrane exhibits good ion exchange capacity and high proton conductivity. As a result, The composite membrane is promising as an alternative membrane in high temperature PEMFC.

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Development of Ultra-Lightweight High Strength Trench Using Lightweight Polymer Concrete

  • Sung, Chan-Yong;Kim, Young-Ik
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.7
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    • pp.20-26
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    • 2003
  • The ultra-lightweight high strength polymer concrete could be used for the drain structures under severe condition. In this study, materials used were unsaturated polyester resin, heavy calcium carbonate, artificial lightweight coarse aggregate and perlite. In the test results, the unit weight of the ultra-lightweight high strength polymer concrete was 946 kg f/$\textrm{m}^3$ and the compressive strength was appeared in 34.5 MPa. The compressive strength, splitting tensile strength, flexural strength, acid resistance and weather resistance were shown in excellently than that of the normal cement concrete. The draining trench had 1m length, 0.24 m width, 0.02 m thickness and 0.07 m height. The developed trench could be effectively used at the draining structures.

Novel P(VDF-TrFE) Polymer Electrolytes: Their Use in High-Efficiency, All-Solid-State Electrochemical Capacitors Using ZnO Nanowires

  • Park, Young Jun;Bae, Joonho
    • Journal of Electrochemical Science and Technology
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    • v.9 no.2
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    • pp.126-132
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    • 2018
  • For the first time, an innovative approach using P(VDF-TrFE) as a polymer electrolyte for high efficiency, all-solid-state supercapacitors is presented. The polymer electrolyte was successfully achieved by dissolving P(VDF-TrFE) copolymers in dimethylformamide (DMF). Thermal analysis and infrared spectroscopy revealed excellent thermal stability up to $400^{\circ}C$ and copolymer's interaction with DMF. Electrochemical capacitors fabricated using P(VDF-TrFE) in DMF and ZnO NWs demonstrated high capacitive performance. Furthermore, the gel electrolyte-based supercapacitors demonstrated excellent mechanical durability up to a bend angle of $120^{\circ}$. Novel P(VDF-TrFE) electrolytes could be a promising approach for applications in flexible, fabric-based, and high-efficiency energy devices.

The method for manufacturing a aluminum solid electrolytic capacitor using a conducting polymer (전도성 고분자를 이용한 알루미늄 고체 전해 커패시터의 제조방법)

  • Shin, Dal-Woo;Kim, Sung-Ho;Lim, Kee-Joe
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.61-64
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    • 2001
  • This study relates to a method for manufacturing a solid electrolytic capacitor using a functional polymer composition. The method comprises immersing the rolled aluminum electrolytic capacitor device in polyaniline solution with high electric conductivity to impregnate the device with polyaniline, drying the impregnated device in a drying oven which is maintained at constant temperature to fully remove the solvent, inserting the dried device to a capacitor aluminum can and then sealing with epoxy resin, to manufacture a solid electrolytic capacitor using a conducting polymer. As such, the impregnation can be performed well at not only normal temperature and pressure, but also high temperature and reduced pressure. The solid electrolytic capacitor has the advantages of high capacity, low impedance and low ESR, and also, low manufacturing cost, simple processes and high reliability.

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Low-voltage Organic Thin-film Transistors with Polymeric High-k Gate Insulator on a Flexible Substrates (고유전율 절연체를 활용한 저 전압 유연 유기물 박막 트랜지스터)

  • Kim, Jae-Hyun;Bae, Jin-Hyuk;Lee, In-ho;Kim, Min-Hoi
    • Journal of Sensor Science and Technology
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    • v.24 no.3
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    • pp.165-168
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    • 2015
  • We demonstrated low-voltage organic thin-film transistors (OTFTs) with bilayer insulators, high-k polymer and low temperature crosslinkable polymer, on a flexible plastic substrate. Poly (vinylidene fluoridetrifluoroethylene) (P(VDF-TrFE)) and poly (2-vinylnaphthalene) are used for high-k polymer gate insulator and low temperature crosslinkable polymer insulators, respectively. The mobility of flexible OTFTs is $0.17cm^2/Vs$ at gate voltages -5 V after bending operation.

Highly efficient phosphorescent polymer OLEDs fabricated by screen printing

  • Lee, D.H.;Choi, J.S.;Cho, S.M.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.694-697
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    • 2007
  • We demonstrate the use of screen printing in the fabrication of highly efficient phosphorescent polymer organic-light-emitting devices (OLEDs) based on a green-emitting $Ir(ppy)_3$ and a host polymer PVK. We incorporate PBD in the polymer host as an electron-transporting dopant and ${\alpha}-NPD$ as a hole transporting dopant. The best screen printed single-layer device exhibits very high peak luminous efficiency of 63 cd/A at a relatively high operating voltage of 17.1 V at the luminance of $650\;cd/m^2$. We observed the highest luminance of $21,000\;Cd/m^2$ at 35V. Due to the high operating voltage, despite of the high peak luminous efficiency the peak power efficiency was found to be 12.2 lm/W at the luminance of $470\;cd/m^2$ (15.9 V).

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The method for manufacturing a aluminum solid electrolytic capacitor using a conducting polymer (전도성 고분자를 이용한 알루미늄 고체 전해 커패시터의 제조방법)

  • 신달우;김성호;임기조
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.61-64
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    • 2001
  • This study relates to a method for manufacturing a solid electrolytic capacitor using a functional polymer composition. The method comprises immersing the rolled aluminum electrolytic capacitor device in polyaniline solution with high electric conductivity to impregnate the device with polyaniline, drying the impregnated device in a drying oven which is maintained at constant temperature to fully remove the solvent, inserting the dried device to a capacitor aluminum can and then sealing with epoxy resin, to manufacture a solid electrolytic capacitor using a conducting polymer. As such, the impregnation can be performed well at not only normal temperature and pressure, but also high temperature and reduced pressure. The solid electrolytic capacitor has the advantages of high capacity, low impedance and low ESR, and also, low manufacturing cost, simple processes and high reliability.

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Strength properties of Polymer-modified Sandwich panel core using non-structural lightweight Aggregate (비구조용 경량 골재를 충진재로 활용한 폴리머 개질 샌드위치 패널 심재의 강도 특성)

  • 노정식;도정윤;문경주;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.775-780
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    • 2002
  • Sandwich panel made by foamed styrene and ployuretane has been used generally in the construction area because of the high thermal conductivity and light weight but they occur harmful gases to both bodies and environments in the high temperature over $50^{\circ}C$. So, the purpose of this study is to investigate the physical properties of light-weight panel using the non-structural lightweight aggregate as a part of the substitution of foamed styrene and ployuretane. This paper dealt with the effect of the addition of polymer dispersion such as SBR, St/BA-1 and St/BA-2 having polymer-cement ratio as 5, 10, 15% and the filling ratio of continuous void as 50, 60% on the strength of polymer-modified sandwich panel core. From the results, we could know that the compressive and flexural strength of the sandwich panel core using non-structural lightweight aggregate and polymer dispersion such as SBR, St/BA-1 and St/BA-2 tended to be increased with an increase in the polymer-cement ratio and the filling ratio of continuous void.

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