• Title/Summary/Keyword: High Density Poly Ethylene

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Design Validation and Improvement of District Heating Pipe Using FE Simulation (유한요소 시뮬레이션을 통한 지역난방열배관 특성 평가 및 강화이형관의 제안)

  • Kim, Joo-Yong;Kim, Ho-Bum;Ko, Hyun-Il;An, Yong-Mo;Cho, Chong-Du
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.4
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    • pp.337-345
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    • 2009
  • This paper investigates the reliability of district heating pipes at thermo-elastic fatigue loading. District heating pipes, subjected to $120^{\circ}C$ and $16kg_f/cm^2$ due to water distributing service through inside the pipes, should endure long term cyclic thermal-mechanical loadings. The heating pipes are the co-centric tubes of steel pipe, poly urethane(PUR) insulator, and high density poly ethylene(HDPE) case. On installation, foam pad is externally wrapped for accommodating stress reduction near the bend sections of pipes. However, there have been frequent reports on the failures of bend sections in the middle of long term service. This study scrutinizes the observed failures near the bend sections through applying the finite element methods. Specially in this study, heating pipes are studied on the influence of foam padding on failures and proposed new designs for reinforced bend without foam pad.

A study on the Measurement of the Coefficient of Thermal Expansion of Polymer materials Exposed to Different Thermal Environments (서로 다른 열환경에 노출된 고분자 소재의 열팽창계수 측정에 관한 연구)

  • Kim, Dong-Ju;Park, Seul-Hyun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.4
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    • pp.80-86
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    • 2021
  • Plastics are widely used in mechanical and other fields due to their light weight, design flexibility, and molding processability. In processing plastics, defective products are mixed and reprocessed to improve production efficiency and reduce costs. In this study, an experiment was conducted to confirm the coefficient of thermal expansion of HDPE during this reprocessing. The coefficient of thermal expansion was measured at different measurement directions and heating rates. As a result, we observed that the coefficient of thermal expansion in the direction perpendicular to the injection direction is greater than that in the horizontal direction.

Morphological Properties of Binary Blends of Polyolefins Synthesized by Metallocene and Ziegler-Natta Catalysts (Ziegler-Natta와 메탈로센 촉매로 합성된 폴리올레핀 2원 블렌드의 상 형태학)

  • Kwag, Hanjin;Kim, Hak Lim;Choe, Soonja
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.944-948
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    • 1999
  • The morphological properties of four binary blends of polyethylene synthesized by metallocene catalyst(MCPE) and four polyolefins prepared by Ziegler-Natta catalyst have been investigated to interpret the effect of micro-molecular structure on the phase morphology and interfacial behavior; four binary blend systems studied are high density polyethylene(HDPE)-metallocene polyethylene (MCPE), polypropylene(PP)-MCPE, poly(propylene-co-ethylene) (CoPP)-MCPE, and poly(propylene-co-ethylene-co-1-butylene) (TerPP)-MCPE, and they are all phase separated. The HDPE-MCPE blend shows evenly growing homogeneous HDPE domain on the continuous MCPE phase, on the other hand, the rest of three blends show complex heterogeneous phase behavior. The PP-MCPE blend shows that PP and MCPE and completely phase separated and phase inversion takes place at 50% MCPE. The CoPP-MCPE and TerPP-MCPE show enhanced interface due to the same micro-molecular structure of ethylene, and phase inversion takes place at 40% MCPE. In particular, TerPP-MCPE blend shows improved phase morphology between interfaces, and this may be arisen from the comonomer contents in TerPP, which are 1-butene and ethylene having the same chemical structure as that of MCPE. The enhancement of the phase morphology in the TerPP-MCPE blend is correlated with the mechanical and morphological properties. Thus, although the four blend systems are phase separated, the phase morphology suggests that the order of interfacial adhesion strength be HDPE-MCPE > TerPP-MCPE > CoPP-MCPE > PP-MCPE and that micro-molecular structure between constituents be one of major factors giving enhanced interfacial adhesion.

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Characteristics of the Adhesion Layer for the Flexible Organic Light Emitting Diodes (플렉시블 OLED 소자 제작을 위한 접합층 특성 연구)

  • Cheol-Hee Moon
    • Journal of Adhesion and Interface
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    • v.24 no.3
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    • pp.86-94
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    • 2023
  • To fabricate all-solution-processed flexible Organic Light-Emitting Diodes (OLEDs), we demonstrated a bonding technology using a polyethyleneimine (PEI) as an adhesion layer between the two substrates. As the adhesion layer requires not only a high adhesion strength, but also a high current density, we have tried to find out the optimum condition which meets the two requirements at the same time by changing experimental factors such as PEI concentration, thickness of the layer and by mixing some additives into the PEI. The adhesion strength and the electrical current density were investigated by tensile tests and electron only device (EOD) experiments, respectively. The results showed that at higher PEI concentration the adhesion strength showed higher value, but the electrical current through the PEI layer decreased rapidly due to the increased PEI layer thickness. We added Sorbitol and PolyEthyleneGlycohol (PEG) into the 0.1 wt% PEI solution to enhance the adhesion and electrical properties. With the addition of the 0.5 wt% PEG into the 0.1 wt% PEI solution, the device showed an electrical current density of 900 mA/cm2 and a good adhesion characteristic also. These data demonstrated the possibility of fabricating all-solution-processed OLEDs using two-substrate bonding technology with the PEI layer as an adhesion layer.

The improvement of Cu metal film adhesion on polymer substrate by the low-power High-frequency ion thruster

  • Jung Cho;Elena Kralkina;Yoon, Ki-Hyun;Koh, Seok-Keun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.60-60
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    • 2000
  • The adhesion interface formation between copper and poly(ethylene terephthalate)(PET), poly(methyl methacrylate)(PMMA) and Polyimide films was treated using Ion assisted reaction system to sequential sputter deposition by High-Frequency ion source. The ion beam modification system used a new type of low power HF ion thruster for space application as new low thruster electric propulsion system. Low power HF ion thruster with diameter 100mm gives the opportunity to obtain beams of Ar+ with currents 20~150 mA (current density 0.5~3.5 mA/cm2) and energy 200~2500eV at HF power level 10~150 W. Using Ar as a working gas it is possible to obtain thrust within 3~8 mN. Contact angles for untreated films were over 95$^{\circ}$ and 80 for Pet, 10o for PMMA and 12o for PI samples as a condition of ion assisted reaction at the ion dose of 10$\times$1016 ions/cm2, the ion beam potential of 1.2 keV and 4 ml/min for environmental gas flow rate. 900o peel tests yielded values of 15 to 35 for PET, 18 to 40 and 12 to 36 g/min. respectively. High resolution X-ray photoelectron spectrocopy is the Cls region for Cu metal on these polymer substrates showed increases in C=O-O groups for polymide, whereas PET and PMMA treated samples showed only C=O groups with increase the ion dose. Finally, unstable polymer surface can be changed from hydrophobic to hydrophilic formation such as C-O and C=O that were confirmed by the XPS analysis, conclusionally, the ion assisted reaction is very effective tools to attach reactive ion species to form functional groups on C-C bond chains of PET, PMMA and PI.

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Analysis of Structural Characteristics of HDPE Pipe for Manganese Lifting Test (근해역 양광시험을 위한 HDPE Pipe의 구조특성 연구)

  • Lee, Jae-Hwan;Yoon, Chi-Ho
    • Journal of Ocean Engineering and Technology
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    • v.25 no.6
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    • pp.86-90
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    • 2011
  • The mining of imitated manganese noodles in 1000 m of seawater is planned for 2012. Thus, it is necessary to prepare the lifting pipes to be used for the test. Because of storage and expense constraints, flexible and economic HDPE pipe is being considered, making it necessary to test the structural safety. Material, pressure-chamber tests and finite element analysis of HDPE pipe for the 1000-m depth were performed. The tangential stiffness of HDPE was obtained through tension and three-point bending material tests and used for a structural analysis. FEA results show that the current sample pipe segment is safe for 1000 m of water pressure, and the stress result is also within the safe value. From the current results, the HDPE pipe seems to be acceptable only for the currently suggested constraints. However, more numerical and pressure tests need to be considered by applying additional physical conditions such as gravitational and hydrodynamic loads, external and internal fluid pressure, axial force induced ship motion, and heavy pump pressure to determine future usage.

Preparation of Superabsorbent PVA Films with Polycarboxylic Acid Crosslinkers (폴리카르복시산 가교제를 이용한 고흡수성 PVA 필름의 제조)

  • Koo, Gwang-Hoe;Yoon, Sung-Jong;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.21 no.4
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    • pp.39-45
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    • 2009
  • PVA films were crosslinked with dimethylol dihydroxy ethylene urea (DMDHEU) and three polycarboxylic acids of butanetetracarboxylic acid (BTCA), citric acid and malic acid Different factors influencing the crosslinking treatment with BTCA were investigated including BTCA and sodium hypophosphite (SHP) concentration, curing temperature and time. The cured films was extracted with boiling water and gel fraction was calculated based on weight change of the PVA films. The gel fraction of PVA films increased with increasing curing temperature and time. And the resistance to water and thermal stability of the crosslinked PVA films improved with the BTCA crosslinking treatment. While crosslinking with citric acid gave the highest gel fraction among the crosslinkers, crosslinking with malic acid showed the highest absorbancy in 0.9% saline solution, which was attributed to lower crosslink density and high number-average molecular weight between crosslinks. The superabsorbent PVA films could be prepared by adjusting the crosslinking condition of PVA with polycarboxilic acids.

Fire Hazard of PP and LLDPE dust in Chemical Plant Process (석유화학플랜트에서 발생하는 PP(Poly Propylene) 및 LLDPE(Linear Low Density Poly Ethylene) 분진의 연소 위험성에 관한 연구)

  • 김정환;이창우;현성호;권경옥
    • Fire Science and Engineering
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    • v.15 no.1
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    • pp.16-22
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    • 2001
  • Thermal properties of PP and LLDPE dusts from chemical plant and their risks of coexisting with oxidizer were investigated by a pressure vessel. The thermal decomposition of PP and LLDPE dusts with temperature using DSC and the weight loss with temperature using TGA were also investigated to find the thermal hazard of PP and LLDPE dusts. Using the pressure vessel which can estimate ignition and explosion of PP and LLDPE dusts coexisting with oxidizer, a series of bursting of a rupture disc, experiments has been conducted by varying the orifice diameters the weight ratio of the sample coexisting with oxidizers and the species of oxidizer. And fire gases was measured by gas analyser ($ECOM-A^+$). According to the results of the thermal analysis of PP and LLDPE dusts, the decomposition temperature range of PP and LLDPE dusts was 200 to 350 and 300 to $500^{\circ}c$, respectively. The risk of PP and LLDPE dusts coexisting with oxidizer was increased as the orifice diameter was decreased. On the other hand, it was increased as the weight ratio of the sample to the oxidizer were increased. In addition, the risk of PP and LLDPE dusts coexisting with oxidizer was affected by the decomposition temperature of the sample and oxidizer. It is found that the risk of fire becomes high when the decomposition temperature of the sample is about same as that of oxidizer. Also, the fire gases was occurred carbon monoxide and carbon dioxide. The amount of carbon monoxide generated was found to be much higher in PP decomposition than in LLDPE due to incomplete combustion of PP which has high content of carbon in chemical compound.

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Geophysical Surveys for the Detection of Gallery and Geomembrane at the Imcheon Abandoned Mine (임천 폐광산의 지하갱도와 인공차수막의 탐지를 위한 지구물리탐사)

  • 김지수;한수형;이경주;최상훈
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.501-510
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    • 2003
  • Several geophysical surveys(electrical resistivity, electromagnetic, seismic refraction, CPR) were conducted to primarily investigate the gallery and the geomembrane at an abandoned mine(Imcheon mine). The subsurface structure mapped from seismic refraction survey mainly consists of three velocity layers(>1000 m/s, 1000∼2000 m/s,<2000 m/s). Top of the bedrock, whose velocities exceed 2000 m/s, appears to be at depth of 7.5∼10m. Higher resistivities (of ten thousands-hundred of thousands ohm-m) are interpreted to be associated with a open(cavities) gallery. The events at depth of approximately 0.5∼0.7m in GPR sections are probably caused by high-density-poly-ethylene geomembrane. Taking into consideration of the differences in the spatial resolution between georadar and electrical surveys, the events of geomembrane correspond to the top of the high resistivities at depth of about 2m. The segments, characterized with the higher conductivities in the electromagnetic data and the lower resistivities in the electrical resistivity data, are probably associated with surface water or tear zone of geomembrane.

Comparison of Biomass Productivity of the Microalgae, Tetraselmis sp. KCTC12236BP, in Polyvinyl Chloride Marine Photobioreactor and High Density Polyethylene Marine Photobioreactor (폴리비닐클로라이드 해양광생물반응기와 고밀도 폴리에틸렌 해양광생물반응기에서 미세조류, Tetraselmis sp. KCTC12236BP의 생산성 비교)

  • Jung, Seung-Gyun;Kim, Su-Kwon;Bun, Moon-Sup;Cho, Yonghee;Shin, Dong-Woo;Kim, Z-Hun;Lim, Sang-Min;Lee, Choul-Gyun
    • Journal of Marine Bioscience and Biotechnology
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    • v.8 no.1
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    • pp.18-23
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    • 2016
  • It is important to design photobioreactor by cheap material for economical microalgal biomass production. In this study, two types of marine photobioreactors (MPBR), made by either polyvinyl chloride (MPBR-PVC) or high density poly ethylene (MPBR-HDPE), are used and performance of these were compared. Tetraselmis sp. KCTC 12236BP is a green marine alga that isolated from Ganghwa Island, Korea, and the strain was used for marine cultivations using MPBR-PVC and MPBR-HDPE. The cultivations were performed three times in the spring season of 2012 using MPBR-PVC and of 2013 using MPBR-HDPE in the coastal area of Young Heung Island. As the results, MPBR-PVC shows higher biomass productivities than MPBR-HDPE, due to its high light transmittance. In the cultivations using MPBR-PVC, the average sea water temperature was $11.5^{\circ}C$ during the first experiment and $16.5^{\circ}C$ during the second and third experiments. Average light intensities during three times for experiments were 407.5, 268.1 and $273.0{\mu}{\cdot}E{\cdot}m^{-2}{\cdot}s^{-1}$, respectively. The maximum fresh cell weight and average biomass productivity were $1.2g{\cdot}L^{-1}$ and $0.12g{\cdot}L^{-1}{\cdot}day^{-1}$. These results showed that Tetraselmis sp. KCTC12236BP were adapted well with the environmental conditions from ocean, and grow in the MPBR-PVC and MPBR-HDPE.