• Title/Summary/Keyword: Hexagonal plate

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The Syntheses, Characterizations, and Photocatalytic Activities of Silver, Platinum, and Gold Doped TiO2 Nanoparticles

  • Loganathan, Kumaresan;Bommusamy, Palanisamy;Muthaiahpillai, Palanichamy;Velayutham, Murugesan
    • Environmental Engineering Research
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    • v.16 no.2
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    • pp.81-90
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    • 2011
  • Different weight percentages of Ag, Pt, and Au doped nano $TiO_2$ were synthesized using the acetic acid hydrolyzed sol-gel method. The crystallite phase, surface morphology combined with elemental composition and light absorption properties of the doped nano $TiO_2$ were comprehensively examined using X-ray diffraction (XRD), $N_2$ sorption analysis, transmission electron microscopic (TEM), energy dispersive X-ray, and DRS UV-vis analysis. The doping of noble metals stabilized the anatase phase, without conversion to rutile phase. The formation of gold nano particles in Au doped nano $TiO_2$ was confirmed from the XRD patterns for gold. The specific surface area was found to be in the range 50 to 85 $m^2$/g. TEM images confirmed the formation a hexagonal plate like morphology of nano $TiO_2$. The photocatalytic activity of doped nano $TiO_2$ was evaluated using 4-chlorophenol as the model pollutant. Au doped (0.5 wt %) nano $TiO_2$ was found to exhibit higher photocatalytic activity than the other noble metal doped nano $TiO_2$, pure nano $TiO_2$ and commercial $TiO_2$ (Degussa P-25). This enhanced photocatalytic activity was due to the cathodic influence of gold in suppressing the electron-hole recombination during the reaction.

Effect of Water Content on the Morphology of ZnO Powders Synthesized in Binary Solvent Mixtures by Glycol Process

  • Phimmavong, Kongsy;Song, Jeong-Hwan;Cho, Seung-Beom;Lim, Dae-Young
    • Journal of the Korean Ceramic Society
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    • v.54 no.3
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    • pp.211-216
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    • 2017
  • ZnO nanopowder was synthesized using a relatively facile and convenient glycol process. ZnO nanopowder was successfully synthesized at temperatures as low as $125^{\circ}C$ using zinc acetate as the Zn source and 1,4-butanediol as the solvent. Then, the effects of water content on the growth process and morphological evolution of ZnO powders were investigated using 1,4-butanediol and water as binary solvent mixtures. Using pure 1,4-butanediol at a temperature above $125^{\circ}C$, the prepared hexagonal ZnO nanopowder exhibited a quasi-spherical shape with average crystalline size of approximately 30 - 50 nm. It is also demonstrated that the morphology of ZnO powders can be controlled by the addition of various water content in 1,4-butanediol. With increasing water content, the morphologies of the ZnO powders changed sequentially from quasi-spherical to hexagonal plate and pyramid, and finally to hexagonal prismatic with a pyramidal tip. A sharp peak centered at 384 nm in the UV region and a weak broad peak in the visible region between 450 and 700 nm were shown in the room temperature PL spectra of the ZnO synthesized using the glycol process, regardless of the addition of water, suggesting that ZnO nanopowders with the best crystallinity were obtained under these conditions.

Properties of Hexaferrite Co2Y(Ba2Co2Fe12O22) Prepared by Coprecipitation Method (공침법에 의해 제조된 육방정 산화철 Co2Y(Ba2Co2Fe12O22)의 특성)

  • 신형섭;이상걸;권순주
    • Journal of the Korean Ceramic Society
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    • v.29 no.3
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    • pp.195-201
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    • 1992
  • It had been studied the structure and the magnetic properties of singel phase Co2Y(Ba2Co2Fe12O22) powder, one of the hexagonal ferrite. The material was successfully prepared by a commercially applicable coprecipitation method. Adding asqueous solution of BaCl2, CoCl2 and FeCl2(Ba2+:Co2+:Fe2+=1:1:6 in mole ratio) to a mixture of NaOH and hydrogen peroxide solution, coprecipitate was formed with rapid oxidation of ferrous to ferric ion. The coprecipitate transformed to single phase Co2Y powder at heat treatment temperatures as low as 900$^{\circ}C$. The shape of Co2Y particles obtained at 900$^{\circ}C$ was hexagonal plate-like (diameter∼$\mu\textrm{m}$, aspect ratio>10). The structure of the Co2Y was refined by a Rietveld analysis of the measured X-ray diffractogram. The lattice parameters are ao=5.8602${\AA}$ and co=43.512${\AA}$. Co2Y is a soft magnetic material with saturation magnetization 30 emu/g and coecivity 170 . A standard X-ray diffraction pattern for Co2Y is proposed as well.

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Prediction of Rolling Texture for Mg Alloy AZ31B Sheet using Finite Element Polycrystal Model (유한요소 다결정 모델을 이용한 마그네슘 합금 AZ31B 판재의 압연 집합 조직 예측)

  • Won S. Y.;Kim Y. S.;Na K. H.;Takahashi Hiroshi
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.08a
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    • pp.72-82
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    • 2004
  • The deformation mechanism of hexagonal close-packed materials is quite complicate including slips and twins. A deformation mechanism, which accounts for both slip and twinning, was investigated for polycrystalline hop materials. The model was developed in a finite element polycrystal model formulated with initial strain method where the stiffness matrix in FEM is based on the elastic modulus. We predicted numerically the texture of Mg alloy(AZ31B) sheet by using FEM based on crystal plasticity theory. Also, we introduced the recrystallized texture employed the maximum energy release theory after rolling. From the numerical study, it was clarified that the shrink twin could not be the main mechanism for shortening of c-axis, because the lattice rotation due to twin rejects fur c-axis to become parallel to ND(normal direction of plate). It was showed that the deformation texture with the pyramidal slip gives the ring type pole figure having hole in the center.

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Synthesis of Sr-Ferrite by a Molten Salt Flux and Its Magnetic Properties (염을 이용한 Sr 페라이트의 분말합성과 그의 자성특성)

  • Kim, Jung-Sik;Kim, Si-Dong
    • Journal of the Korean Ceramic Society
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    • v.42 no.10 s.281
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    • pp.672-677
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    • 2005
  • In this study we prepared the Sr-ferrite powders and magnet by a molten salt method using the (NaCl+KCl) salt mixture. Starting materials of $Fe_{2}$$O_{3}$ and Sr$Co_{3}$ were mixed as the molar ratio of 5.70:1, and 0.08 mol$ \% $ $Al_{2}$$O_{3}$, 0.10 mo1$ \% $ Si$O_{2}$ and 0.12 mo1$ \% $ CaO were added as additives. Sr-ferrite powders synthesized at the reaction temperatures of 800$\∼$1200$ ^{\circ}C $ showed the typical M-type hexagonal ferrite phase, and hexagonal plate-like morphology with uniform distribution of 1$\∼$3 $\mu$m particle size. The bulk density of the sintered Sr-ferrite magnet prepared with powders by the molten salt method showed the maximum density of 4.82 g/$cm^{3}$ at the sintering temperature of 1200$^{\circ}C $. The maxima of remanent flux density (Br, 45 emu/g) and coercive force (iHc, 3.75 kOe) occurred at the sintering temperatures of 1150$ ^{\circ}C$ and 1200$^{\circ}C $.

Effect of position of hexagonal opening in concrete encased steel castellated beams under flexural loading

  • Velrajkumar, G.;Muthuraj, M.P.
    • Computers and Concrete
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    • v.26 no.1
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    • pp.95-106
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    • 2020
  • Castellated beams fabricated from standard I-sections are being used for several structural applications such as commercial and industrial buildings, multistory buildings, warehouses and portal frames in view of numerous advantages. The advantages include enhanced moment of inertia, stiffness, flexural resistance, reduction in weight of structure, by passing the used plate girders, the passage of service through the web openings etc. In the present study, experimental and numerical investigations were carried out on concrete encased steel castellated beams with hexagonal openings under flexural loading. Various positions of openings such as along the neutral axis, above the neutral axis and below the neutral axis were considered for the study. From the experimental findings, it has been observed that the load-carrying capacity of the castellated beam with web opening above neutral axis is found to be higher compared to other configurations. Nonlinear finite element analysis was performed by using general purpose finite element software ABAQUS considering the material nonlinearities. Concrete damage plasticity model was employed to model the nonlinearity of concrete and elasto-plastic model for steel. It has been observed that FE model could able to capture the behaviour of concrete encased steel castellated beams and the predicted values are in good agreement with the corresponding experimental values.

Hydrodynamic Characteristics in a Hexagonal Inverse Fluidized Bed (장방형 역유동층의 동력학적 특성)

  • 박영식;안갑환
    • Journal of Environmental Science International
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    • v.5 no.1
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    • pp.93-102
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    • 1996
  • Hydrodynamic characteristics such as gas holdup, liquid circulation velocity and bed expansion in a hexagonal inverse fluidized bed were investigated using air-water system by changing the ratio ($A_d$/$A_r$) of cross-sectional area between the riser and the downcomer, the liquid level($H_1$/H), and the superficial gas velocity($U_g$). The gas holdup and the liquid circulation velocity were steadily increased with the superficial gas velocity increasing, but at high superficial gas velocity, some of gas bubbles were carried over to a downcomer and circulated through the column. When the superficial gas velocity was high, the $A_d$/$A_r$ ratio in the range of 1 to 2.4 did not affect the liquid circulation velocity, but the maximum bed expansion was obtained at $A_d$/$A_r$ ratio of 1.25. The liquid circulation velocity was expressed as a model equation below with variables of the cross-sectional area ratio($A_d$/$A_r$) between riser to downcomer, the liquid level($H_1$/H), the superficial gas velocity($U_g$), the sparser height[(H-$H_s$)/H], and the draft Plate level($H_b$/H). $U_{ld}$ = 11.62U_g^{0.75}$${(\frac{H_1}{H})}^{10.30}$${(\frac{A_d}{A_r})}^{-0.52}$${(\frac({H-H_s}{H})}^{0.91}$${(\frac{H_b}{H})}^{0.13}$

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Classification and Characterization of Bacteriophages of Lectobacillus casei (Lactobacillus casei Bacperiophage의 분류 및 특성에 관한 연구)

  • 김영창;박민철;강국희;윤영호;이광웅
    • Korean Journal of Microbiology
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    • v.17 no.4
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    • pp.165-178
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    • 1979
  • Phages of Lactobaciilus casei (PLC) isolated from plant drainage were classified and characterized. The results are as follows : 1. On the basis of host range pattern, phages could be divided into 2 groups (PLC-B and PLC-C). PLC-B group phages could be further divided into 5 sub-groups $(B_1, \;B_2, \;B_3, \;B_4, \;and\;B_5)$. Although PLC-C group phages had the same host range, they could be also divided into 2 sub-groups $(C_1\;and\;C_2)$ by morphlogical type. 2. It was $B_3$ group phages that represented a major proportion (44.4%) of phages tested. However, $B_1$ group phages were shown to have the widest host range. 3. Electron micrographs revealed that the phages fell into three different morphological types. $(B_1, \;B_2, \;and\;B_3)$ group phages hd a hexagonal head (52nm in diameter) and a sheathless noncontractile (245 nm in length). $B_4\;and\;C_2$ group phages had a hexagonal head (56 nm) and a short flexible tail (169nm) having no sheath. $B_5\;and\;C_1$ group phages were shown to have a hexagonal head (81 nm) and a contractile tail (140 nm) having a sheath, a base plate and tail fibers. 4. The inactivation of the phages by antisera indicated that serological relationships correlated completely with morphological types. 5. $B_1, \;C_1\;and\;C_2$ group phages produced a large (1, 2 mm in diameter) plaque with a clear ring. The morphology of plaques of $B_3\;and\;B_5$ group phages was the same as those produced by the above, but the average plaque sizes for $B_3\;and\;B_5$ were 0.8 mm abd 0.5 mm, respectively. $B_2\;and\;B_4$ group phages produced a small (0.5 mm) turbid plaque with an irregular edge. 6. The latent period and the average burst size of $B_1\;and\;B_3$ group phages were 90 min and 100, respectively. These phages reuqired calcium ions for their miltiplication. 7. $B_3$ group phages could not be absrobed to R-variant $KC_1$. 8. The order of resistance of phages to heat was $B_2\;>\;B_1, B_4\;and\;B_5\;>\;B_3\;and\;C_2, \;B_5$ group phages were more stable than $B_3$ in various pH values. $C_2$ group phages were more sensitive to UV irradiation than $B_1\;and\;B_3$ group phages. 9. Strains YIT9018 and IAM 1043 were induced by mitomycin C treatment. Phage particles detected in the lysates had a hexagonal head (38 and 49 nm, respectively), but no tail. Any sensitive indicator strain could not be isolated in spite of repaeated trials.

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Control of a mobile robot supporting a task robot on the top

  • Lee, Jang M.
    • 제어로봇시스템학회:학술대회논문집
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    • 1996.10a
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    • pp.1-7
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    • 1996
  • This paper addresses the control problem of a mobile robot supporting a task robot with needs to be positioned precisely. The main difficulty residing in the precise control of a mobile robot supporting a task robot is providing an accurate and stable base for the task robot. That is, the end-plate of the mobile robot which is the base of the task robot can not be positioned accurately without external position sensors. This difficulty is resolved in this paper through the vision information obtained from the camera attached at the end of a task robot. First of all, the camera parameters were measured by using the images of a fixed object captured by the camera. The measured parameters include the rotation, the position, the scale factor, and the focal length of the camera. These parameters could be measured by using the features of each vertex point for a hexagonal object and by using the pin-hole model of a camera. Using the measured pose(position and orientation) of the camera and the given kinematics of the task robot, we calculate a pose of the end-plate of the mobile robot, which is used for the precise control of the mobile robot. Experimental results for the pose estimations are shown.

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Two-dimensional isotropic patterns for core materials in applications to sandwich structures (샌드위치 구조물 내에서의 응용과 관련된 2차원 단위 셀 형상을 지닌 심재에 대한 연구)

  • Kim, Beom-Keun;Christensen, R.M.
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.130-135
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    • 2007
  • The mechanical characteristics of three types of core with two-dimensional isotropic patterns-triangular, hexagonal and starcell-were studied in applications to sandwich structures. The Young's modulus and shear modulus were calculated for the three core types in the direction normal to the faces. The compressive buckling strength and shear buckling strength were calculated by modeling each cell wall of the core as a plate under compressive or shear load. To verify this model, tests were conducted on scaled specimens to measures the compressive buckling strength of each core. The bending flexibilities of the three cores were also studied. Compliances for the three cores were measured using biaxial flexural tests. The three isotropic core patterns exhibited distinct characteristics. In the direction normal to the faces, all three cores had the same stiffness. However, the starcell core exhibited high flexibility compared to the other cores, indicating potential for application to curved sandwich structures.

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