• Korean Chemical Engineering Research
• /
• v.56 no.1
• /
• pp.119-124
• /
• 2018

The production of methyl N-phenyl carbamate by an oxidative carbonylation method of aniline and methanol is of great interest as an environmentally friendly process that can replace the monomer production process of a polymer produce using conventional phosgene. In this study, heterogeneous catalysts were prepared by using Y-zeolite, $SiO_2$, $Al_2O_3$ as support, and oxidative carbonylation continuous operation from aniline and methanol was attempted using the prepared heterogeneous catalyst. Batch reactor was used to determine the support, and various reaction conditions such as reaction temperature, reaction pressure, and effect of promoter were established using palladium catalyst. A reaction kinetics study was conducted under optimum reaction conditions. The basic data for carbamate process development were obtained by performing continuous operation for a long time under established reaction condition.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.8 no.2
• /
• pp.115-128
• /
• 2006

The structural anisotropy and heterogeneity of rock mass, caused by discontinuities and weak zones, have a great influence on the deformation behavior of a tunnel. A tunnel construction in these complex ground conditions is very difficult. No matter how excellent a geological investigation is, local uncertainties of rock mass conditions still remain. Under these uncertain circumstances, an accurate forecast of the ground conditions ahead of the advancing tunnel face is indispensable to a safe and economic tunnel construction. This paper presents the effect of anisotropy and heterogeneity of the rock masses to be excavated by numerical analysis. The influences of distance from weak zone, the size or dimension, the different stiffness and the orientation of weak zones are analysed by 3-D finite element analysis. By analysing these numerical results, the tunnel behavior due to excavation can be well understood and the prediction of rock mass condition ahead of the tunnel face can be possible.

• Journal of the Korean Wood Science and Technology
• /
• v.25 no.4
• /
• pp.29-38
• /
• 1997

The effect and control of wood property of reconstituted composite panels for improved board properties by wood-waste materials and development of combination method for heterogeneous materials have been of interest to the wood science researchers. The purpose of this study is to consider the properties in relation to hot pressing conditions and to develope the optimum hot pressing condition with waste wood and waste tire for the manufacturing of composite boards. The study of composite boards for recycling of wood and waste tire is nothing up to the present. Physical and mechanical properties such as specific gravity, moisture content, swelling coefficient, modulus of rupture and modulus of elasticity in bending test were studied. The condition of 3-stage press time for the lowest moisture content of composite board was $4{\rightarrow}3{\rightarrow}3$ minutes. Specific gravity of composite panels was affected mainly by the amount of rubber chip. Because of the low rigidity and high elasticity in rubber chip, it is considered the composite panel was adequate material in the place of compression load, but not bending load. Therefore, it was concluded that a use of rubber-based wood composite panel is proper to the interior materials such as floor a room than exterior materials. From the test results, the most optimum hot pressing conditions were $4{\rightarrow}3{\rightarrow}3$ minutes for 3-stage press time and $45{\rightarrow}20{\rightarrow}5kg/cm^2$ for 3-stage press pressure. The rubber-based wood composite panel was very excellent in elasticity by combination of rubber chip in comparison with existing other wood-based materials. Therefore, it was considered that rubber-based wood composites can be applicable to every interior materials such as floor a room and will be expected to effective reuse and recycle of waste tires and wood-waste materials, and will be contribute to protection of environment pollution in earth.

• Structural Engineering and Mechanics
• /
• v.72 no.1
• /
• pp.113-129
• /
• 2019

A four-variable shear deformation refined plate theory has been proposed for dynamic characteristics of smart plates made of porous magneto-electro-elastic functionally graded (MEE-FG) materials with various boundary conditions by using an analytical method. Magneto-electro-elastic properties of FGM plate are supposed to vary through the thickness direction and are estimated through the modified power-law rule in which the porosities with even and uneven type are approximated. Pores possibly occur inside functionally graded materials (FGMs) due the result of technical problems that lead to creation of micro-voids in these materials. The variation of pores along the thickness direction influences the mechanical properties. The governing differential equations and boundary conditions of embedded porous FGM plate under magneto-electrical field are derived through Hamilton's principle based on a four-variable tangential-exponential refined theory which avoids the use of shear correction factors. An analytical solution procedure is used to achieve the natural frequencies of embedded porous FG plate supposed to magneto-electrical field with various boundary condition. A parametric study is led to carry out the effects of material graduation exponent, coefficient of porosity, magnetic potential, electric voltage, elastic foundation parameters, various boundary conditions and plate side-to-thickness ratio on natural frequencies of the porous MEE-FG plate. It is concluded that these parameters play significant roles on the dynamic behavior of porous MEE-FG plates. Presented numerical results can serve as benchmarks for future analyses of MEE-FG plates with porosity phases.

• Progress in Medical Physics
• /
• v.25 no.2
• /
• pp.100-109
• /
• 2014

In stereotactic body radiotherapy (SBRT), the accurate location of treatment sites should be guaranteed from the respiratory motions of patients. Lots of studies on this topic have been conducted. In this letter, a new verification method simulating the real respiratory motion of heterogenous treatment regions was proposed to investigate the accuracy of lung SBRT for Volumetric Modulated Arc Therapy. Based on the CT images of lung cancer patients, lung phantoms were fabricated to equip in $QUASAR^{TM}$ respiratory moving phantom using 3D printer. The phantom was bisected in order to measure 2D dose distributions by the insertion of EBT3 film. To ensure the dose calculation accuracy in heterogeneous condition, The homogeneous plastic phantom were also utilized. Two dose algorithms; Analytical Anisotropic Algorithm (AAA) and AcurosXB (AXB) were applied in plan dose calculation processes. In order to evaluate the accuracy of treatments under respiratory motion, we analyzed the gamma index between the plan dose and film dose measured under various moving conditions; static and moving target with or without gating. The CT number of GTV region was 78 HU for real patient and 92 HU for the homemade lung phantom. The gamma pass rates with 3%/3 mm criteria between the plan dose calculated by AAA algorithm and the film doses measured in heterogeneous lung phantom under gated and no gated beam delivery with respiratory motion were 88% and 78%. In static case, 95% of gamma pass rate was presented. In the all cases of homogeneous phantom, the gamma pass rates were more than 99%. Applied AcurosXB algorithm, for heterogeneous phantom, more than 98% and for homogeneous phantom, more than 99% of gamma pass rates were achieved. Since the respiratory amplitude was relatively small and the breath pattern had the longer exhale phase than inhale, the gamma pass rates in 3%/3 mm criteria didn't make any significant difference for various motion conditions. In this study, the new phantom model of 4D dose distribution verification using patient-specific lung phantoms moving in real breathing patterns was successfully implemented. It was also evaluated that the model provides the capability to verify dose distributions delivered in the more realistic condition and also the accuracy of dose calculation.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.11a
• /
• pp.60.2-60.2
• /
• 2010

A $TiO_2$ films in dye-sensitized solar cells was fabricated using $TiO_2$ colloidal sol prepared from titanium iso-propoxide used as a starting material by applying the sol-gel method. It was characterized by particle size analyzer, XRD, FE-SEM, and BET analysis. The adsorption isotherms of dye molecule on $TiO_2$ films were obtained at three different temperatures (30, 45, $60^{\circ}C$) and at three different pH (3, 5, 7). The adsorption kinetics of dye molecule on $TiO_2$ films were obtained at three different temperatures (30, 45, $60^{\circ}C$. The adsorption experimental data were correlated with Langmuir isotherm model and pseudo-second-order model. Also the isosteric enthalpies of dye adsorption were calculated by the Clausius-Clapeyron equation. In addition, the adsorption energy distribution functions which describe heterogeneous characteristics of nanocrystalline $TiO_2$ film surface were calculated by using the generalized nonlinear regularization method. We found that efficient adsorption of N719 dye from aqueous solution onto $TiO_2$ films can be successfully achieved by dye adsorption conditions and morphology of $TiO_2$ films.

• Journal of Labour Economics
• /
• v.39 no.2
• /
• pp.1-34
• /
• 2016

We estimate the effect of an increase in the minimum wage on employment. In Korea, there is no exogenous variation in the minimum wage across regions or industries. One single minimum wage is applied to every worker in the whole country. In this paper, we exploit arguably exogenous variation in the proportion of workers affected by the minimum wage across worker groups defined by age, sex, education, tenure and establishment size. Using the data from the Survey on Labor Conditions by Type of Employment (SLCTE) from 2006 to 2014, we find that a 1% increase in the minimum wage decreases the full-time equivalent employment by about 0.14%. The effect is heterogeneous across workers; we find the effect is more adverse for female workers, low-educated, younger and older workers, workers with a shorter tenure, and workers in small- and medium-sized establishments.

• Journal of Korean Institute of Industrial Engineers
• /
• v.32 no.3
• /
• pp.172-179
• /
• 2006

Over the past few years, a considerable number of studies have been conducted on modeling the bargaining game using artificial agents on within-model interaction. However, very few attempts have been made at study on between-model interaction. This paper investigates the interaction and co-evolutionary process among heterogeneous artificial agents in the bargaining game. We present two kinds of the artificial agents participating in the bargaining game. They play some bargaining games with their strategies based on genetic algorithm (GA) and reinforcement learning (RL). We compare agents' performance between two agents under various conditions which are the changes of the parameters of artificial agents and the maximal number of round in the bargaining game. Finally, we discuss which agents show better performance and why the results are produced.

• Clinical and Experimental Pediatrics
• /
• v.53 no.11
• /
• pp.931-935
• /
• 2010

Juvenile idiopathic arthritis (JIA) is comprised of a heterogeneous group of several disease subtypes that are characterized by the onset of arthritis before the age of 16 years and has symptoms lasting at least 6 weeks. The previous classification of JIA included seven different categories, whereas its current classification was compiled by the International League of the Association for Rheumatology, and replaced the previous terms of "juvenile chronic arthritis" and "juvenile rheumatoid arthritis," which were used in Europe or North America, respectively, with the single nomenclature of JIA. As mentioned above, JIA is defined as arthritis of unknown etiology that manifests itself before the age of 16 years and persists for at least 6 weeks, while excluding other known conditions. The clinical symptoms of JIA can be quite variable. Several symptoms that are characteristic of arthritis are not necessarily diagnostic of JIA and may have multiple etiologies that can be differentiated with careful examination of patient history. The disease may develop over days or sometimes weeks, thereby making the diagnosis difficult at the time of presentation. To make a clinical diagnosis of JIA, the first step is to exclude arthritis with known etiologies. Of note, late treatment due to excessive delay of diagnosis can cause severe damage to joints and other organs and impair skeletal maturation. Therefore, early detection of JIA is critical to ensure prompt treatment and to prevent long-term complications including the likelihood of disability in childhood.

• Journal of Korean Society for Atmospheric Environment
• /
• v.19 no.1
• /
• pp.67-76
• /
• 2003

Recently consideration of health and interest on bio aerosols have been growing steadily. In this study, inertial impactor, which can be used to collect airborne particles and bio aerosols, was newly devised for real-time observation on the particles collected on impaction plate. and named Visual Impactor. Flow field and particle trajectory in the space between nozzle and impaction plate was analyzed numerically, and the collection effciencies were calculated. Calibration and performance evaluation of the Visual Impactor was conducted with polydisperse aerosols generated from 0.1％ sodium chloride solution. Cut-off diameter from numerical simulation was in good agreement with that from experimental results. Because of particle bounce and particle deposition on nozzle tip due to short jet-to-plate distance, the collection efficiencies from numerical and experimental analyses were different slightly. Visual Impactor was used to collect airborne particles, and the features of collected particles could be seen in real-time. Airborne particles in different weather conditions (fine, cloudy, and rainy) were sampled and compared one another The features of collected airborne particles were dependent strongly upon relative humidity. In addition, with hours elapsing, shapes and colors of collected particles were changed by evaporation and surface tension, etc.