• Title/Summary/Keyword: Heavy oil

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An Analysis of Effects of Changes in Foreign Exchange Rates on the Domestic Energy Prices : Diesel, Heavy Oil, and LNG (환율변동이 국내 에너지가격에 미치는 영향 분석 : 경유, 중유, LNG를 중심으로)

  • Jung Gi Chul;Choi Jea Seoung
    • Journal of the Korean Institute of Gas
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    • v.3 no.2 s.7
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    • pp.11-16
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    • 1999
  • Oil and LNG products are characterized by the facts that the raw materials are all imported and financing is dependent heavily upon foreign countries. This makes the oil and LNG products sensitive to changes in foreign exchange rates. However, the extent to which they respond to changes in foreign exchange rates, particularly the extent of price changes, vary considerably, due to the differences in the structures of price determination. The purposes of this paper are twofolds. The first one is to analyze the structures of price determination of diesel, heavy oil, and LNG. The second one is to analyze the effects of changes in foreign exchange rates on the prices of and price competitiveness of the fuels in question through the sensitivity analysis. The results of the sensitivity analysis indicate that diesel price is most sensitive and heavy oil price is least sensitive to changes in foreign exchange rates.

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Safety Profile Assessment and Identification of Volatile Compounds of Krill Eupausia superba Oil and Residues Using Different Extraction Methods

  • Haque, A.S.M. Tanbirul;Kim, Seon-Bong;Lee, Yang-Bong;Chun, Byung-Soo
    • Fisheries and Aquatic Sciences
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    • v.17 no.2
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    • pp.159-165
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    • 2014
  • In this study, Krill Eupausia superba oil was extracted using different solvents and supercritical carbon dioxide (SC-$CO_2$). During SC-$CO_2$ extraction, the pressure was set at 40 MPa and temperatures ranged from $40^{\circ}C$ to $55^{\circ}C$. We examined the differences in volatile compounds and safety profiles among extraction methods. Volatile compounds were determined using the thermal desorption system integrated with gas chromatography-mass spectrometry (GC-MS). Heavy metal content was analyzed by inductively coupled plasma mass spectrometry (ICP-MS). According to our results 10 volatile compounds were identified in krill sample. After SC-$CO_2$ extraction of oil, the concentrations of volatile compounds decreased, but increased after solvent extraction. In krill, heavy metal concentrations remained within the permissible limit. Moreover, Zn and Fe which have health benefits were detected at high concentrations. During a 90 days storage period at different temperatures, microbial activity was found to be lowest in SC-$CO_2$ extracted residues. Thus, the quality of krill oil and the residues obtained using SC-$CO_2$ extraction was higher and the oil was safer than those obtained using conventional solvent extraction. These results can be applied to the food industry to maintain high quality krill products.

Friction Power Loss Reduction for a Marine Diesel Engine Piston (박용엔진 피스톤 스커트 프로파일 변경에 의한 마찰손실(FMEP) 저감 연구)

  • An, Sung Chan;Lee, Sang Don;Son, Jung Ho;Cho, Yong Joo
    • Tribology and Lubricants
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    • v.32 no.4
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    • pp.132-139
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    • 2016
  • The piston of a marine diesel engine works under severe conditions, including a combustion pressure of over 180 bar, high thermal load, and high speed. Therefore, the analyses of the fatigue strength, thermal load, clamping (bolting) system and lubrication performance are important in achieving a robust piston design. Designing the surface profile and the skirt ovality carefully is important to prevent severe wear and reduce frictional loss for engine efficiency. This study performs flexible multi-body dynamic and elasto-hydrodynamic (EHD) analyses using AVL/EXCITE/PU are performed to evaluate tribological characteristics. The numerical techniques employed to perform the EHD analysis are as follows: (1) averaged Reynolds equation considering the surface roughness; (2) Greenwood_Tripp model considering the solid_to_solid contact using the statistical values of the summit roughness; and (3) flow factor considering the surface topology. This study also compares two cases of skirt shapes with minimum oil film thickness, peak oil film pressure, asperity contact pressure, wear rate using the Archard model and friction power loss (i.e., frictional loss mean effective pressure (FMEP)). Accordingly, the study compares the calculated wear pattern with the field test result of the piston operating for 12,000h to verify the quantitative integrity of the numerical analysis. The results show that the selected profile and the piston skirt ovality reduce friction power loss and peak oil film pressure by 7% and 57%, respectively. They also increase the minimum oil film thickness by 34%.

Comparative Crude Oil Productions on Liquefaction of Crop Residues (액화기술 적용 식물체 잔사별 원유 생산량 비교)

  • Shin, JongDo;Yoon, SunCheol;Paek, Yee;Park, SangWon;Choi, HongLim
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.4
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    • pp.50-56
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    • 2008
  • Aqueous thermal liquefaction of rice, barley, wheat, and rapeseed straws was investigated to compare the amount of heavy oil with catalysts such as $K_2CO_3$, NaOH and KOH in the reaction temperature at $320^{\circ}C$ for 10 minutes. The reaction was carried out in a 5,000ml liquefaction system with dispenser and external electrical furnace. Raw materials (160g), 2,000ml of distilled water and 10% (wt/wt) of catalyst to plant residue were fed into the reactor. It was observed that the maximum heavy oil yield was about 29% from the feeding stock, barley straw, with addition of KOH. The caloric values of crude oil from different crop residues were ranged from 55% to 66% relative to the raw materials depend on crop residue. It was appeared that its maximum calorific value from wheat straw was approximately 6190 kcal/kg.

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Liquefaction Characteristics of Polypropylene-Polystyrene Mixture by Pyrolysis at Low Temperature (Polypropylene-Polystyrene 혼합물의 저온 열분해에 의한 액화특성)

  • Cho, Sung-Hyun;Kim, Chi-Hoi;Kim, Su-Ho;Lee, Bong-Hee
    • Clean Technology
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    • v.16 no.1
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    • pp.26-32
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    • 2010
  • The low temperature pyrolysis of polypropylene (PP), polystyrene (PS) and polypropylene-polystyrene (PP-PS) mixture in a batch reactor at the atmospheric pressure and $450^{\circ}C$ was conducted to investigate the synergy effect of PP-PS mixture on the yield of pyrolytic oil. The pyrolysis time was varied from 20 to 80 mins. The products formed during pyrolysis were classified into gas, gasoline, kerosene, gas oil and heavy oil according to the petroleum product quality standard of Ministry of Knowledge Economy. The analysis of the product oils by GC/MS(Gas chromatography/Mass spectrometry) showed that new components were not detected by mixing of PP and PS. There was no synergy effect according to the mixing of PP and PS. Conversions and yields of PP-PS mixtures were linearly dependent on the mixing ratio of samples except for heavy oil yields. Heavy oil yields showed almost constant regardless of the mixing ratio.

Heavy Metal Contents of Canned Seafoods Packed in Oil (수산물 기름 담금 통조림 식품의 중금속 함량)

  • Heu, Min-Soo;Kim, Jin-Soo
    • Applied Biological Chemistry
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    • v.47 no.3
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    • pp.307-314
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    • 2004
  • Specification and heavy metal contents of canned seafoods packed in oil were investigated. 30 species of canned tuna were classified by 4 groups as follow; group (sample codes, 1-10) composed of tuna and oil only, group (11-18) composed of tuna, vegetable and oil, group (19-27) composed of tuna, sauce and oil, and group (28-30) composed of tuna, vegetable, sauce and oil. Commercial canned shellfish packed in oil were mainly produced from sea mussel (sample codes, 31 and 32) and oyster (33-35). Can bodies of canned tuna were made by tin-plate, and used c-enamel or aluminium-paste as coating materials. In pH values of canned tuna, sample codes 1-10 (pH 5.55-5.69) and 19-27 (pH 5.17-5.85) were higher than sample codes 11-18 (pH 4.95-5.43) and 28-30 (pH 5.20-5.38). There was no difference in salinity (1.3-1.9%) and vacuum degree (15-18 mmHg) among canned samples. Heavy metal contents of canned seafoods ranged from 1.04-9.03 ppm for Sn, and 0.17-0.68 ppm for Pb. Those values are below the permitted range (less than 150 ppm for Sn and 2 ppm for Pb).

The Optimum Design of Green Water Protector for FPSO (FPSO - Green Water Protector 구조 최적 설계)

  • Bae, Myung-Hyun;Kim, Sung-Jun;Moon, Jung-Yang
    • Special Issue of the Society of Naval Architects of Korea
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    • 2007.09a
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    • pp.94-98
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    • 2007
  • The latest development of the submarine oil field and the deep-sea explorer, FPSO is commonly proposed and used for offshore oil production. And because the fundamental requirement of FPSOs to remain moored at their position, they are unable to avoid severe weather and environment. FPSO normally operates head to the weather, and sensitive equipment located the exposed area will be influenced by green water damages, the damages may occur to both onboard equipment and topside structures with resulting risk to personnel. In this paper, the main focus considers the physical structures of green water protector in order to preserve topside structures, equipment and personnel from green water.

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Calculation of Breakeven Point for LNG-Heavy Oil Transfer of D Thermal Power Plant Considering $CO_2$ Emission Cost ($CO_2$ 배출비용을 감안한 D 발전소의 LNG-중유 연료교제 손익분기점 계산)

  • Jeong, Yeong-Ho;Lee, Sang-Joong;Lee, Gene-Kyu;Yang, Seong-Deog
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2008.10a
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    • pp.65-67
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    • 2008
  • Kyoto Protocol against global warming came into effect in Feb 2005. This paper presents a calculation $CO_2$ emission of D power plant for combusting LNG and heavy oil using the a, b, c coefficients obtained by the performance test. The authors also calculate the breakeven point of the fuel transfer from LNG to Oil considering recent $CO_2$ emission cost.

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Study on the Pyrolysis Kinetics of Deasphalted Oil Using Thermogravimetric Analysis (열중량 분석법을 이용한 Deasphalted Oil의 열분해 특성 분석)

  • Shin, Sang Cheol;Lee, Jung Moo;Lee, Ki Bong;Jeon, Sang Goo;Na, Jeong Geol;Nho, Nam Sun
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.391-397
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    • 2012
  • The depletion of conventional oil reserves and the increasing energy need in developing countries such as China and India result in exceeding oil demand over supply. As a solution of the problem, the efficient utilization of heavy oil has been receiving more and more interest. In order to utilize heavy oil, upgrading processes are required. Among the upgrading processes, thermal decomposition is thought to be relatively simple and economical. In this study, to understand basic characteristics of thermal decomposition of heavy oil, we conducted pyrolysis experiments of deasphalted oil (DAO) produced by a solvent deasphalting process. DAO is a mixture of many components and consists mainly of materials of carbon number 20~40. For the comparison with results of DAO pyrolysis, additional pyrolysis experiments with single materials of carbon number 30 ($C_{30}H_{62}$, $C_{30}H_{58}O_4S$, $C_{30}H_{63}O_3P$) were conducted. Pyrolysis experiments were carried out non-isothermally with variation of heating rate (10, 50, $100^{\circ}C$/min) in a thermogravimetric analyzer. Average pyrolysis activation energy determined by using Arrhenius method, Ingraham and Marrier method, and Coats and Redfern method was 72~99 kJ/mol. In the activation energy calculated by Ozawa-Flynn-Wall method, DAO had wider variation than other single materials.

Detection of Heavy Metal Contents in Sesame Oil Samples Grown in Korea Using Microwave-Assisted Acid Digestion

  • Park, Min-Kyoung;Yoo, Ji-Hyock;Lee, Je-Bong;Im, Geon-Jae;Kim, Doo-Ho;Kim, Won-Il
    • Journal of Food Hygiene and Safety
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    • v.28 no.1
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    • pp.45-49
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    • 2013
  • This study aimed to determine heavy metal contents in sesame oil samples produced in Korea through microwave-assisted acid digestion without using an emulsifier. Three heavy metal, cadmium (Cd), lead (Pb) and arsenic (As) in twelve sesame oil samples were determined by ICP-MS. The validation of analysis method was checked by standard addition method (10 and $100{\mu}g/kg$). As a result, linearity ($R^2$) was above 0.999 and RSDs were lower than 4%. The recovery of Cd, Pb and As ranged between 98.5-101.6%, 100.3-101.3%, and 102.1-111.2%, respectively. The detected ranges in sesame oil samples were as follows; N.D. to $0.109{\mu}g/g$ for Cd, 0.014 to $0.200{\mu}g/g$ for Pb and 0.014 to $0.125{\mu}g/g$ for As, respectively. Therefore, sesame seeds and products grown in heavy metal-polluted regions which are used as food should be given priority attention and consideration.