• Title/Summary/Keyword: Heavy metal pollution level

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Evaluation of Heavy Metal Contamination in Intertidal Surface Sediments of Coastal Islands in the Western Part of Jeollanam Province Using Geochemical Assessment Techniques (지화학적 평가기법을 이용한 전남 서해 도서갯벌 퇴적물내 중금속 오염도 평가)

  • Hwang, Dong-Woon;Kim, Seong-Gil
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.44 no.6
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    • pp.772-784
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    • 2011
  • We measured grain size, organic matter, and metallic elements (Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, and As) in intertidal sediments collected from six islands in the western part of Jellanam Province in order to evaluate heavy metal contamination in the tidal flat sediments of coastal islands. The evaluation of metal contamination was carried out using geochemical assessment techniques such as sediment quality guidelines (SQGs), enrichment factor (EF), and geoaccumulation index ($I_{geo}$). Surface sediments were classified into four sedimentary facies: sand, gravelly muddy sand, slightly gravelly mud, and silt. The concentrations of heavy metals in intertidal sediments from Jaeun, Amtae, Biguem, and Docho islands showed good positive correlations with mean grain size and ignition loss, indicating that the concentrations of metallic elements in these sediments were dependent on grain size and the organic matter content. The concentrations of heavy metals in sediments from almost all of the stations were lower than two criterion values proposed by the National Oceanic and Atmospheric Administration (NOAA) in the United States. Based on the EF and $I_{geo}$ results, surface sediments were a little polluted for Cr and were moderately polluted for As. Our results suggest that more intensive studies are necessary in the future in order to determine the major source of As in intertidal sediment and to evaluate the As pollution level in macrobenthos.

Comparison of Heavy Metal(loid)s Contamination of Soil between Conventional and Organic Fruit Farms

  • Lee, Hyun Ho;Kim, Keun Ki;Lee, Yong Bok;Kwak, Youn Sig;Ko, Byong Gu;Lee, Sang Beom;Shim, Chang Ki;Hong, Chang Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.5
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    • pp.401-408
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    • 2017
  • Organic amendments such as animal waste compost, lime-bordeaux mixture, and lime sulphur mixture contain heavy metal(loid)s which are toxic to human being, animal, and plant. The objective of this study was to compare heavy metal(loid)s contamination of soil between conventional and organic farm. Soil samples were collected from 10 conventional and 38 organic fruit farms. At each sampling point, top (0~15 cm) and sub soil (15~30 cm) were taken using hand auger. Total concentration for arsenic (As), cadmium (Cd), copper (Cu), nikel (Ni), lead (Pb), and zinc (Zn) in the collected soil were measured. The pollution index (PI) for heavy metal in organic farms indicated it was unpolluted area. However, mean value of PI for organic farms (0.143) was higher than that for conventional farms (0.122). High Geoaccumulation index (Igeo) for Cu, Pb, and Zn implied that grape farms were more polluted than others fruit farms because a lot of lime-bordeaux mixture and lime sulphur were applied in organic grape farms. Especially, top soils showed higher level of contamination than sub soil. Based on the above results, organic amendments might cause accumulation of heavy metals in soil. Therefore, particular attention should be paid for concentration of Cu, Pb, and Zn, when organic amendments are used in the organic fruit farms.

Investigation of Pollution of Polycyclic Aromatic Hydrocarbons and Heavy Metals in Soil near Railway Rails (철도레일 부근 토양의 다환방향족 탄화수소 및 중금속 오염도 조사)

  • Choi, Hyun-Kyung;Yoon, In-Ju;Shin, Tae-Cheon;Kim, Young-Hun
    • Journal of Environmental Science International
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    • v.27 no.11
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    • pp.947-956
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    • 2018
  • Trains have been a major means of transport in Korea during these past decades. However, train facilities such as stations and repair shops are contaminated with organic and inorganic substances. There is a high probability of train facility contamination with polyaromatic hydrocarbons (PAHs). This study evaluated the PAH and heavy metal contamination of soil near railroads in the Kyungpook area. A total of 18 soil samples were collected from the railroads and analyzed for 16 PAHs and 6 heavy metal species. The contamination level of the top soil was found to be slightly higher than that of the subsoil for contamination with PAHs. The ratio of carcinogenic PAH concentration to the total PAH concentration was relatively high, with a maximum of 0.9. The toxicity equivalent (TEQ) of the PAHs were 500.6 ng/kg in the topsoil and 355.5 ng/kg in the subsoil. The ratio of low molecular PAHs (LPAHs) to high molecular PAHs (LPAHs) ranged from 6.7 to 29.5; this shows that contamination is primarily due to combustion of fuel rather than due to petroleum. The ratio of phenanthrene to anthracene and the ratio of fluoranthene to pyrene also show that contamination occurred due to combustion for transportation. The heavy metal contamination level was lower than the Korean standard, but higher than the background concentration; this indicates that the soil was affected by the operation of the railways.

Fraction and Soil Pollution Assesment Index of heavy metals in cultivated land soils near the abandoned mine (폐광산지역 경작지 토양의 중금속 존재형태와 토양오염평가)

  • 김휘중;양재의;이재영;최상일;전상호
    • Journal of Soil and Groundwater Environment
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    • v.8 no.4
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    • pp.53-63
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    • 2003
  • Objectives of this research were to fractionate heavy metals in soil samples in the upper Okdong River basin and to assess the potential pollution index of each metal fraction. Soil samples were collected from the cultivated land soils and analyzed for physical and chemical properties. pH of cultivated soils ranged from 5.2 to 7.6. Contents of total kelhaldal nitrogen and loss on ignition were in the ranges of 0.6∼2.5%, and 1.9∼12.9%, respectively. Heavy metals in the cultivated land soils were higher in the abandoned closed coal mine near field soils than those in the paddy soils. Total concentrations of metals in the cultivated land soils were in the orders of Zn > Pb > Ni > Cu > Cd, exceed the corrective action level of the Soil Environment Conservation Law and higher than the naturals were abundance levels reported from uncontaminated cultivated land soils. Mobile fractions of metals were relatively small compared to the total concentrations. Soil Pollution Assesment Index (SPAI) values of each fraction of metals were leveled from Non polluted to Moderately polluted based on total concentrations. SPAI values of mobil fractions were lower than those of immobile fractions. Results on metal fractions and SPAI values of the cultivated land soils indicate that field soils samples were contaminated with heavy metals and had potential to cause a detrimental effects on plants. A prompt countermeasure to prevent field soils in the abandoned closed coal mine near fields are urgently needed.

A Study on the Correlation between River Contamination Level and Ground Pollution Source through Korean Case Study (국내 사례분석을 통한 하천오염도와 지반오염원의 상관관계에 관한 연구)

  • Choi, Joohwan;Song, Wonjun;Lee, Junhwan
    • Journal of Korean Society of societal Security
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    • v.3 no.1
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    • pp.51-60
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    • 2010
  • This study measured for comparison and analysis the correlation of River pollution and Soil contamination, based on the results of previous research, and then in order to increase the efficiency of study, heavy metals which cause serious side effects was limited to the case among pollutants. This study focused on the rivers that near the Urban and industrial districts, for example, Nak-Dong river, An-Yang river, Tae-Hwa river and the rivers that near the farm land or pasture, for example, Yeong-San river, Mi-Ho river, then compare and analyze the degree of actual pollution as gathered the results of Previous research. Correlationship about pollutants of river near the Urban, industrial area and drainage basin its river has been proven, and this expected because of the strong influence by point pollution source. On the other hand, I can found the opposite relationship where the river near the farm land or pasture, and this probably because of the influence by nonpoint pollution source.

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Analysis of mine tailings, soils, stream sediments and ground water around Imcheon disused mine (임천광산 광미와 주변 토양 및 지하수의 오염조사)

  • 김선태;윤양희;박제안;심의섭;박경수
    • Journal of Korea Soil Environment Society
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    • v.3 no.3
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    • pp.33-44
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    • 1998
  • Mine tailings, soils, stream sediments, and ground water around Imcheon disused mine were analyzed in order to investigate their pollution levels of heavy metals and cyanide. The average contents of As, Cd, Cu, Hg, Pb, Zn, and CN ̄ in mine tailings were 366, 28.8, 202, 15.2, 1.97$\times$$10^3$, 3.85$\times$$10^3$, 90.6mg/kg respectively, The pollution indices that calculated by the tolerance level of Kloke were 8~19 and the pH values were acidic in mine tailngs. In the field and paddy soils of Imcheon disused mine area except for soils nearby mine tailngs, concentraitons of the heavy metals were less than standards of soil pollution of agricultral area in the environmental protection law. The nitrate contents In the ground water for drink were more than tolerance level of the drinking water of Ministry of Health and Social Affairs.

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Measures to improve water quality of Lake Euiam by controlling the incoming pollutants to the lake (의암호에 유입되는 오염물질 관리를 통한 호소 수질개선 방안)

  • Hwang, Hwan-Min;Yi, Geon-Ho;Kim, Mi-Yeon;Kim, Dong-Jin;Kim, Yeong-Kwan
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.5
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    • pp.783-790
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    • 2011
  • The purpose of this study was to suggest the alternative measures to properly manage the water quality of Lake Euiam, Chuncheon. Current pollution level of Gongji stream (influent to Lake Euiam) and sources of contamination in Lake Euiam were investigated. Particle size, organic matter and nutrient contents, heavy metals were analyzed for sediment samples taken from lower region of Gongji stream. Average organic matter content of nine sediment samples was 5.7%, and for nitrogen and phosphorus it was 750 mg/kg and 977mg/kg, respectively. Heavy metals including aluminum, iron, manganese and zinc were measured, whereas Cd and As were not detected. Effluent from Chuncheon Wastewater Treatment Plant appeared to be one of the main cause of organic matter and nutrients level in Lake Euiam. Inhibition of primary production and consequent reduction of organic matter content within the Lake should be a key measure to protect the water quality of Lake Euiam. Preventive measures to reduce the level of nutrients in wastewater treatment effluent were found necessary.

Experimental Studies on the Cadium and Metallothioneien in Molluscs Collected from Mangyeong River, Korea (만경강 유역 연체동물 내 Cadmium 및 Cadmium-Methallothionein 함량의 실험적 조사)

  • 소진탁;유일수;김숙향;김재진
    • The Korean Journal of Malacology
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    • v.9 no.2
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    • pp.16-22
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    • 1993
  • Contamination of heavy metals in water and sediments along Mangyeong Gang(river) has reached up to critical level The object of the study is to elucidate somed molluscs which inhabit along the river on respect to the modulatory role in reducing the pollution. For the purpose, molluscs which are common in numbers and biomass in the area were collected, and Cadmim(Cd) was subjected as a reference metal in the experiment. The corresponding species were; Cipango;aludina chinensis (muddy snail) and Scapharca subcrenata (seashell). As methods, sample species were kept in laboratory under the natural condition as possible. Soil were brought from the site of the collection, dried autoclaved and wetted with ordinary water. It wad utilized as media to maintain the collected species in vitro all the way of the experiment. CdCI$^{2}$ was mixe in the medium according to experimental design. On the result obtained in the study, it is summarized that molluscs which inhabit along Mangyeong Gang(river)consume heavy mital-containing matters, so far Cd is concerned in the study. The amout of Cd concentration in tissues of the benthic natured invertebrates were dose and time related, and MT-Cd was also similar trend. Thus, Cd may eventually combine with low molecular protein forming metalloprotein, then reduce the toxicity of the heavy metal.

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Estimation of Heavy Metal Contamination Level in Masan Bay and Nakdong Estuary Sediments (마산만과 낙동강 하구역 해양 퇴적토의 중금속 오염도 산정 연구)

  • Lee, Junho;Yang, Changeun;Han, Kyongsoo;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.3
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    • pp.13-21
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    • 2020
  • The purpose of this study is to evaluate the concentrations of heavy metals in the marine sediments near the Masan bay and the Nakdong estuary, and to investigate the pollution intensity levels of six heavy metals using the existing pollution intensity assessment method. According to the US environmental protection agency, in the case of Cu, the B1 area was classified as severe pollution, while in Ni and Zn, it was classified as moderate pollution in some areas. According to the classification of Igeo, EF and PERF, the A and B regions were polluted by Cd. In particular, in the B1 region, Igeo, EF, and PERF values were the highest in all regions, and were regarded as serious pollution. According to the mean PEL quotient classification, which takes into account the effects of all six heavy metals, there is a 21% probability of toxicity from heavy metals in all regions. The highest concentration of Cd in the B1 region is 1.5 mg/kg. Therefore, the contamination of Cd contained in sediment near Masan Bay is serious, so it is necessary to clarify the cause and take careful approach to future treatment.

Concentration of Heavy Metals in Seawater, Fish, and Shellfish at Lake Shihwa (시화호 내 수질 및 어패류의 중금속 분포 연구)

  • Lee, Gyuyoung;Lee, Seunghun;Oh, Sehun;Choi, Minji;Lee, Yong-Woo
    • Journal of Korean Society on Water Environment
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    • v.34 no.2
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    • pp.157-163
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    • 2018
  • This study aims to determine the pollution levels of nine kinds of heavy metals (As, Cd, Cu, Cr, Hg, Mn, Ni, Pb, and Zn) in Lake Shihwa, which is susceptible to the inflow of pollutants, and the levels of heavy metal exposure in its fish and shellfish. Shihwa Lake's water quality did not exceed the short-term standard for protection of marine ecosystems, but concentrations of As, Cu, Cr, Hg, Ni, and Zn exceeded the long-term standard for protection of a marine ecosystem. In comparison to findings in prior research, performed in 2010, levels of Cr, Ni, As, and Zn are now 4.1 times lower. However, when compared to Saemangeum Lake, the environment is similar to that of Lake Shihwa, Cu, Ni, Hg, Mn, and Zn were 244.4 times higher. The levels of Pb, Cd, and Hg in fish's muscles did not exceed the average values set by the marine safety standard. However, when compared to the fish from the Korean coast, the levels of heavy metals were 9.7 times higher, on average. The levels of heavy metals in fish's livers were on average 26.8 times higher than in the muscles. In the case of shellfish, the levels of Pb, Cd, and Hg did not exceed the standard values, but in comparison to the shellfish from the south coast, the levels of heavy metals were 6.2 times higher on average. In particular, Mn (153.5 times higher) from fish and Cd (14.7 times higher) from shellfish were found in high amounts, indicating a concerning level of these specific heavy metals.