• Korean Journal of Environmental Agriculture
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• v.17 no.1
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• pp.48-53
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• 1998

The purpose of this study was to compare heavy metal concentrations in uncontaminated soil with those in soil influenced by industrial activities, and to investigate the relationship between change of heavy metal content and the kind of industry at the Iksan 1st Industrial Complex that has started since 1975. Soils sampled in 0-3㎝ and 3-6㎝ soil depth, respectively were analized for content of Cd, Cu, Ni, Pb and Zn. Change of heavy metal content in soil of the industrial complex were more accumulated 16 to 25% of Cd and Cu, 93% of Pb and Zn, respectively in samples compared with natural soil uncontaminated. But there was no different in Ni content between two soil. Distribution of Cd in soil layer of 0 to 3cm was the highest concentration of 5 ppm more at the textile industries, and then higher at the chemicals and the food processing industries. In 3 to 6㎝ soil layer Cd content was the highest concentration of 5 ppm more at the metal processing industries, and then higher at the textile industries. Cd accumulation in soil was different according to a kind of industry and soil depth. Cu content was the highest value of 400 ppm more in soil layer of 0 to 3cm at the manufacturing electric wires industry area and showed the accumulation phenomenon in soil layer 3 to 6cm at the ohmmeter, machines and electric wires industry area. Ni content was 35 ppm more in soil of the metal plating and processing industries regardless of soil sampling layer. Then it was 25 ppm more in soil of the building stones and semiconductor industries. Pb content was from 400 to 1000 ppm in soil of the chemicals and textiles industries regardless of soil sampling layer. Zn content was 1200 ppm more in soil of the chemicals and silk fabrics industries regardless of soil depth, and then lower in order to soil of leather processing${\le}$metal plating industries. In conclusion, changes of heavy metal kinds and content in soil of this industrial complex area were caused by the type or kinds of industrial activities. Changes of Pb and Zn content in soil were dominated at this area.

• Journal of Ocean Engineering and Technology
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• v.13 no.3 s.33
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• pp.49-56
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• 1999

Welding is a reliable process and is mainly adopted for fabricating heavy structures. Recently, transverse cracks in the weld metal is serious problem, and they affect cost, efficiency, safety and joint reliability for various welded structures. In this view of point, this study investigated the potential factors for weld metal transverse crack. The main results obtained are as follows; 1) The content of diffusible hydrogen in the commercial flux cored are welding wire was remarkable change by manufacturer. 2) The diffusible hydrogen content was thd main factor for weld metal transverse cracks. 3) Weld metal was immune to transverse cracking under the condition of low diffusible hydrogen content of high restraint condition. 4) The factors for weld metal transverse crack would be the content of diffusible hydrogen and restraint of weld joint.

• Journal of Environmental Science International
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• v.22 no.1
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• pp.59-72
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• 2013

The purpose of this study is to assess the effects of heavy metal concentrations in the blood and urine of the general population. This research had been conducted from April to December 2008, studying 545 residents of Daejeon and Chungcheong Province. Through the concentrations of heavy metals(Pb, Cd, Hg, As, Mn) in the biota samples and questionnaires, the residents heavy metal exposure level and the influential factors according to personal characteristics or lifestyle were evaluated. As to the heavy metal concentration in the blood and urine of the comparing region, were As and Mn statistically significant(p<0.01, p<0.05). Blood lead and urinary mercury concentrations were higher in males than females. The heavy metal concentration for each age group increased blood mercury. The concentration of all heavy metals were higher in the drinkers than in the non-drinkers. Blood lead and mercury concentrations were higher in the smokers than in the non-smokers, but the urinary cadmium, arsenic and blood manganese was higher in the non-smokers than in the smokers. As to the blood lead and urinary cadmium concentration according to the food preference fish showed high concentration. To clarify the factors affecting the heavy metal concentration in biota among subjects multiple regression analysis was conducted. As a results, it turned out that as to lead content in blood, sex, age and smoking have influence on the subjects with explanatory adequacy of 14.0 %. These results demonstrated that the factors affected the concentrations of heavy metals in blood and urine. The results of this study could be used as the foundational data for setting the health risk assessment.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.5
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• pp.397-403
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• 2015

Heavy metals reduce the photosynthetic efficiency and disrupt metabolic reactions in a concentration-dependent manner. Moreover, by replacing the metal ions in metalloproteins that use essential metal ions, such as Cu, Zn, Mn, and Fe, as co-factors, heavy metals ultimately lead to the formation of reactive oxygen species (ROS). These, in turn, cause destruction of the cell membrane through lipid peroxidation, and eventually cause the plant to necrosis. Given the aforementioned factors, this study was aimed to understand the physiological responses of rice to cadmium (Cd) and arsenic (As) toxicity and the effect of essential metal ions on homeostasis. In order to confirm the level of physiological inhibition caused by heavy metal toxicity, hydroponically grown rice (Oryza sativa L. cv. Dongjin) plants were exposed with $0-50{\mu}M$ cadmium (Cd, $CdCl_2$) and arsenic (As, $NaAsO_2$) at 3-leaf stage, and then investigated malondialdehyde (MDA) contents after 7 days of the treatment. With increasing concentrations of Cd and As, the MDA content in leaf blade and root increased with a consistent trend. At 14 days after treatment with $30{\mu}M$ Cd and As, plant height showed no significant difference between Cd and As, with an identical reduction. However, As caused a greater decline than Cd for shoot fresh weight, dry weight, and water content. The largest amounts of Cd and As were found in the roots and also observed a large amount of transport to the leaf sheath. Interestingly, in terms of Cd transfer to the shoot parts of the plant, it was only transported to upper leaf blades, and we did not detect any Cd in lower leaf blades. However, As was transferred to a greater level in lower leaf blades than in upper leaf blades. In the roots, Cd inhibited Zn absorption, while As inhibited Cu uptake. Furthermore, in the leaf sheath, while Cd and As treatments caused no change in Cu homeostasis, they had an antagonist effect on the absorption of Zn. Finally, in both upper and lower leaf blades, Cd and As toxicity was found to inhibit absorption of both Cu and Zn. Based on these results, it would be considered that heavy metal toxicity causes an increase in lipid peroxidation. This, in turn, leads to damage to the conductive tissue connecting the roots, leaf sheath, and leaf blades, which results in a reduction in water content and causes several physiological alterations. Furthermore, by disrupting homeostasis of the essential metal ions, Cu and Zn, this causes complete heavy metal toxicity.

• Journal of Environmental Health Sciences
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• v.22 no.2
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• pp.69-82
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• 1996

The samples for testing have been collected from Kangdong-myon, Nongso-myon, Beomseo-my on, and Cheongryang-myon in Ulju-Ku, Ulsan-city from July 1994 to March 1995 in order to grasp status of trace metals contained in some rice, soybean and soils, and to provide references in establishing their standard 96 collected samples(48 for cereals and 48 for soils) have been tested to measure levels of Hg, Pb, Cd, Cu, and Zn through methods of trace metal containing analysis and heavy metal analysis. moisture content was also analyzed. And at the same time 0.1N-HCl soluble heavy metal content of soil was measured. The average Hg containing level of samples is 0.006 ppm for cereal and 0.062 ppm for soil, Pb is 0.302 ppm for cereal and 1.137 ppm for soil, Cd is 0.012 ppm for cereal and 0.027 ppm for soil, Cu is 2.01 ppm for cereal and 0.885 ppm for soil, and Zn is 7.853 ppm for cereal and 2.366 ppm for soil.

• Environmental Analysis Health and Toxicology
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• v.4 no.1_2
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• pp.35-45
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• 1989

Studies on the heavy metal content of ginkgo leaves growing in all around Seoul. This study was carried out to investigate the concentration of heavy metals and soluble sulfur in ginkgo leaves. These leaves are found growing in park, residential, commercial and industrial areas all around Seoul. These analyzed the quantity of Cd, Co, Cu, Fe, Mn, Ni, Pb, Zn, Hg and soluble surfur in separate samples of washed and unwashed leaves. The results were as follows: 1. This order of heavey metal concentration was found in Seoul area,: Fe＞Mn＞Zn＞Ni＞Pb＞Cu＞Co＞Cd＞Hg. 2. Pb concentration was higher in the commercial area than in the other areas, and it concentration in washed leaves was higher 96～100% and unwashed leaves 85～170%. 3. In the residential area Ni concentration was significantly higer where about seven times more Ni as found on the top part of the leaves. 4. Water soluble surfur was higest in the inudstrial area, but the percentage on top of the leaves was only 0.04～0.05% simillar with other area. 5. Fe, Zn and Ni were almost positively correlated to each component but negatively correlated between Mn and souble sulfer. All of content except Mn and Ni were significance between each area in washed and unwashed leaves.

• Korean Journal of Environmental Agriculture
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• v.23 no.1
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• pp.15-21
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• 2004

Objectives of this study were to monitor the distribution of heavy metals, to compare extractable heavy metal with total content and to investigate the relationships between soil physico-chemical properties and heavy metals in orchard soil. Sampling sites were 48 in Gyeonggi, 36 in Gangwon, 36 in Chungbuk, and 44 in Chungnam, Soils were collected farm form two depths, 0 to 20 and 20 to 40 cm (here after referred to as upper and lower layers) from March to May in 1998. Total contents of heavy metal in soils were analyzed by ICP-OES after acid digestion ($HNO_3$:HCl:$H_2O_2$) whereas extractable contents were measured after successive extraction of 0.1N-HCl, 0.05 M-EDTA, and 0.005 M-DTPA. Mercury was analysed by mercury atomizer. The average contents of Cd Cu, and Pb in the extractant with 0.1N-HCl at upper layer were 0.080, 4.23, and 3.42 mg/kg, respectively. As content in the extractant with 1N-HCl was 0.44 mg/kg, and total contents of Zn, Ni and Hg were 78.9, 16.1, and 0.052 mg/kg, respectively. The ratios of concentrations of heavy metals to threshold values (Cd 1.5, Cu 50, Pb 100, Zn 300, Ni 40, Hg 4 mg/ke in Soil Environmental Conservation Act in Korea (2001) were low in the range of $1/2.5{\sim}1/76.9$ in orchard soils. The ratios of extractable heavy metal to total content ranged $5.4{\sim}9.21%$ for Cd, $27.9{\sim}47.8%$ for Cu, $12.6{\sim}21.8$% for Pb, $15.8{\sim}20.3%$ for Zn, $5.3{\sim}6.3%$ for Ni, and $0.7{\sim}3.6%$ for Zn, respectively. Cu and Pb contents in 0.05 M-EDTA extractable solution were higher than those in the other extractable solution. Total contents of Cd, Ni and Ni in soils were negatively correlated with sand content but positively correlated with silt and clay contents. Ratios of extractable heavy metal to total content were negatively correlated with clay content but ai and Ni contents were positively correlated with soil pH, organic matter, and available phosphorous. Therefore, the orchard soil was safe because the heavy metal contents of orchard soil were very low as compared to its threshold value in the Soil Environmental Conservation Act. However, it need to consider the input of agricultural materials to the agricultural land for farming practices for assessment of heavy metals.

• Journal of Environmental Science International
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• v.26 no.3
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• pp.311-324
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• 2017

To certificate change in the geochemical characteristics of surface sediments in the main stream of the Nakdong River, surface sediments from 12 sampling sites during the first and second half year (total 24 sampling sites) were collected and analyzed for grain size, ignition loss, total organic carbon and heavy metal content. Surface sediments mainly composed of sand (coarse and medium sand) and fining changed from the first half to the second half of the year. Ignition loss, total organic carbon and heavy metals content increased in the second half of the year. Some heavy metals (Zn, Ni and Cu) were found to be at the lowest effect levels according to Ontario sediment quality guidelines. Additionally, most heavy metals were found to be at the non polluted level and level I according to USEPA sediment quality standards and National Institute of Environmental Research sediment pollution evaluation standard, respectively. The enrichment factor (< 1) and index of geoaccmulation (< 0) were non polluted in the study area. The correlation analysis results showed that ignition loss, total organic carbon and heavy metal content were highly correlated with grain size. Regarding changes in geochemical characteristics of surface sediments in the study area, grain size fine and organic matter and heavy metal content increased in the second half year. Nonetheless these results indicated pollution levels that did not adversely affect the benthos.

• The Korean Journal of Ecology
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• v.27 no.4
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• pp.231-237
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• 2004

In this research we determined the levels of heavy metals in soil and metal-accumulating plants from a D military shooting site in the Kyungkido district of Korea. The data obtained may be useful in the development of methods for the efficient phytoremediation of contaminated soil. The total Cd, Cu, Pb, and Zn concentrations in the soil were found to be 1.67-5.04 mg/kg, 52.51-106.26 mg/kg, 37.24-90.32mg/kg, and 111.45-188.19mg/kg, respectively. These results show that the soil is contaminated with Cd and Cu, and this contamination is particularly severe in the case of Cd because of its high bioavailability (25-57% of the total metal in the soil is exchangeable). The high concentrations of heavy metals in the shoots of Persicaria thunbergii and Artemisia princeps var. orientalis indicate that these plants (all perennial herbs) accumulate heavy metal efficiently. Further, these plants were found to contain more Cd in its shoots (＞60% of the total metal found in the plant) than any other plant; these results indicate that these native species are particularly suited to use in Cd phytoextraction.

• The Korean Journal of Ecology
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• v.21 no.3
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• pp.179-186
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• 1998

Effects of lead(Pb) and calcium(Ca) on growth responses, accumulation of heavy metals and nitrogen fixation activities of Melilotus suaveolens seedlings were quantitatively analyzed during growing period. Pb contents of the root treated with 30, 100 ppm Pb and 100 ppm Pb added 100 ppm Ca were 54.1, 90.9 and 26.1 folds higher than that of the control, respectively, at pH 4.2 in 28th days, and heavy metal content of plant increased with increasing of pH and Pb concentration. The melilot plant was classified as a Pb accumulator by higher accumulation of Pb in shoot than that of root. Pb treatments resulted in inhibiton of height and chlorophyll contet, and Ca treatment increased height and chlorophyll content insignificantly at pH 4.2 in 28 days. The plant biomass reduced 49, 60 and 54% at pH 4.2 and 47,53 and 50% at pH 6.5, respectively, by 30, 100 ppm Pb and 100 ppm Pb added 100 ppm Ca treatment. Specific nitrogen fixation of nodules reduced 68.4% and 46.6% by 100 ppm Pb treatment and 3.7% and 24.9% by 100 ppm Pb added 100 ppm Ca at pH 4.2 and pH 6.5, respectively, so Ca inhibited significantly Pb activity and toxicity in acdic pH. Nodule formation were reduced to 33, 33 and 50% at pH 4.2 and 50, 33 and 38% at pH 6.5 by 30, 100 ppm Pb and 100 ppm Pb added 100 ppm Ca, respectively.