• Title/Summary/Keyword: Heavy metal analysis

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Heavy Metal Risk Management: Case Analysis

  • Kim, Ji-Ae;Lee, Seung-Ha;Choi, Seung-Hyun;Jung, Ki-Kyung;Park, Mi-Sun;Jeong, Ji-Yoon;Hwang, Myung-Sil;Yoon, Hae-Jung;Choi, Dal-Woong
    • Toxicological Research
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    • v.28 no.3
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    • pp.143-149
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    • 2012
  • To prepare measures for practical policy utilization and the control of heavy metals, hazard control related institutions by country, present states of control by country, and present states of control by heavy metals were examined. Hazard control cases by heavy metals in various countries were compared and analyzed. In certain countries (e.g., the U.S., the U.K., and Japan), hazardous substances found in foods (e.g., arsenic, lead, cadmium, and mercury) are controlled. In addition, the Joint FAO/WHO Expert Committee on Food Additives (JECFA) recommends calculating the provisional tolerable weekly intake (PTWI) of individual heavy metals instead of the acceptable daily intake (ADI) to compare their pollution levels considering their toxicity accumulated in the human body. In Korea, exposure assessments have been conducted, and in other countries, hazardous substances are controlled by various governing bodies. As such, in Korea and other countries, diverse food heavy metal monitoring and human body exposure assessments are conducted, and reducing measures are prepared accordingly. To reduce the danger of hazardous substances, many countries provide leaflets and guidelines, develop hazardous heavy metal intake recommendations, and take necessary actions. Hazard control case analyses can assist in securing consumer safety by establishing systematic and reliable hazard control methods.

중금속으로 오염된 포화사질토의 저주파대에서의 유전특성

  • 방선영;오명학;김용성;박준범
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.289-292
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    • 2003
  • Laboratory tests were performed to investigate the dielectric property of saturated sands contaminated by heavy metals solution at low frequency. Differences of contamination and the real part of dielectric constant depend on heavy metal concentration was measured at low frequency, 100KHz below. The optimal frequency to develop the detection potentials of monitoring was 1KHz, 10KHz, 100KHz. At this frequency, Heavy metal contamination of saturated sands contamination can be recommended by analysis of complex dielectric constant.

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Evaluating Soil Respiration as Indicator of Heavy Metal Pollution in Agricultural Field

  • Choi, Won-Suk;Hong, Young-Kyu;Min, Kyung-Jun;Kim, Kwang-Jin;Kim, Sung-Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.5
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    • pp.472-481
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    • 2017
  • Agricultural field near at the abandoned metal mine and industrial area has a high possibility to be polluted by heavy metals. However, concern about chemical properties including heavy metal concentration has been increased and biological properties such as soil respiration has been minimal in heavy metal polluted field. Therefore, main objective of this research was to evaluate soil respiration as an indicator of heavy metal pollution in agricultural field. Total of 60 sampling sites including each 30 sites of abandoned metal mine and industrial area were selected and heavy metal concentration, soil respiration, and chemical properties were measured. Results showed that heavy metal concentration in metal mine area was ranged Cu: $6.21~85.23mg\;kg^{-1}$, Pb: $23.84{\sim}1,044.72mg\;kg^{-1}$, As: $1.88{\sim}691.44mg\;kg^{-1}$, Zn: $18.72{\sim}527.55mg\;kg^{-1}$, Cd: $0.58{\sim}4.27mg\;kg^{-1}$, and Cu: $0.29{\sim}30.62mg\;kg^{-1}$, Pb: $4.41{\sim}19.77mg\;kg^{-1}$, As: $2.23{\sim}11.76mg\;kg^{-1}$, Zn $39.98{\sim}109.59mg\;kg^{-1}$, Cd $0.29{\sim}0.57mg\;kg^{-1}$ for industrial area respectively. While no sampling site was exceed the threshold value of each heavy metals in industrial field, metal mine area was highly polluted with Pb, As, Zn, and Cd. Soil respiration in the metal mine and industrial area was ranged $12.05{\sim}299.80mg\;O_2\;kg^{-1}$ and $27.68{\sim}330.94mg\;O_2\;kg^{-1}$, respectively. Correlation analysis between heavy metal concentration in soil and soil respiration showed that negative correlation was observed in metal mine area while no correlation was observed in industrial area. This result might indicate that as heavy metal concentration was increased, microbial activity in soil was decreased resulting decrease of soil respiration rate. Overall, soil respiration can be used as indicator of heavy metal pollution in soil and more biological properties need to be evaluated to better understand heavy metal pollution in soil.

Influence of Heavy Metal on Riparian Vegetation in Downstream Areas of Disused Metal Mines (폐금속광산지역의 하천퇴적물에서 중금속이 식물에 미치는 영향에 관한 연구)

  • Ahn, Tae Woong;Lee, Joung An;Oh, Jong Min
    • Journal of Environmental Impact Assessment
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    • v.18 no.4
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    • pp.209-218
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    • 2009
  • The purpose of this study was to accumulation of the heavy metals by riparian vegetation throughout analysis of the heavy metal concentration in riparian vegetation, water, and sediment near mine drainage. According to analyzing concentration of the heavy metals in riparian vegetation, water, and sediment the heavy metal was indicated at the leaf significantly. Compared with the concentration of sediment soil, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 2.6, 2.6, 25, non-detect, and 15 times in leaf. Also those concentration have 9.6, 16.6, 25, 1.6, and 25 times in root. As the results, the author can know the sediment has a very relative to vegetation in mine drainage. because, the increasing of concentration of heavy metal in sediment gives the more accumulative concentration of heavy metal in vegetation. Compared with the concentration of conta minated site and non-contaminated site. As, Cd, CN, Pb, Zn the maximum concentration in sediment soil was higher 5.7, 258.1, 10.9, 370.0, and 298.3 times respectively. In case of vegetation, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 5.6, 62.3, 5.0, non-detect, and 30.6 times in leaf. Also those concentration have 8.5, 63.3, 2.6, 60.7, and 62.1 times in root. In this study, the author can surmise that there indicated a lot of adsorption with the heavy metal concentration in contaminated mine drainage.

Incidence of Multiple Heavy Metal Resistance in a Bacillus Species

  • Singh, Kusum-Lata;Kumar, Ashok
    • Journal of Microbiology and Biotechnology
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    • v.8 no.5
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    • pp.497-500
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    • 1998
  • A new strain of Bacillus capable of growing upto pH 11 was isolated from a local pond polluted with detergents. This strain elicited unimpaired growth in media supplemented with heavy metals such as As, Cu, Cd, Hg, Ni and Zn. A MIC value of 200, 3, 1.60, 2.25, 7.50 and 3.70 mM was noticed for As, Cu, Cd, Hg, Ni and Zn respectively. Analysis of total DNA revealed the presence of a plasmid of 26 kb. This plasmid was lost by acriflavine treatment to the cultures. Such cured strains were found sensitive to heavy metals. Our findings suggest that incidence of heavy metal resistance is widely distributed and resistant strains could be isolated from heavy metal unpolluted sites.

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Heavy Metal Concentrations in Soils and Stream around the Abandoned Mine Land (폐광산 주변 토양 및 하천의 중금속 함량)

  • 전관수;이철희;원양수;정진욱;박병삼;신덕구
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.197-204
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    • 1999
  • The extent of heavy metal pollution in agricultural in soils near the abandoned mine land site was investigated using their concentrations from the 47 sampling sites in B mine. Samples were prepared using 0.1N HCI - Korean Standard Methods - and then analysed for Cd, Cu, Pb, As and Cr by Inductively Coupled Plasma Spectrometer. In addition, soil and mine tailing samples were sequentially extracted to investigate the chemical speciation of heavy metals in them. The soils in the vicinity of mining area are highly contaminated by heavy metals ranging up to 5.96mg Cd/kg, 253.3mg Cu/kg, 76.7mg Pb/kg, and 15.45 mg As/kg, according to the analysis of Korean Standard Methods. The heavy metal levels by the sequential extraction are much higher than its level by Korean Standard Methods, and little correlated with each other. Based on the results, it is suggested that the As pollution in agricultural soils near the AMLS should be dealt as of prior significance in establishing reclamation strategies for the area.

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Evaluating Ecotoxicity of Surface Water and Soil Adjacent to Abandoned Metal Mines with Daphnia magna and Eisenia fetida

  • Kim, Dae-Bok;Choi, Won-Suk;Hong, Young-Kyu;Kim, Soon-Oh;Lee, Sang-Woo;Lee, Byung-Tae;Lee, Sang-Hwan;Park, Mi-Jung;Kim, Sung-Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.1
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    • pp.81-86
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    • 2016
  • Heavy metal pollution in agricultural fields at the abandoned metal mines has been serious problems in Korea. In order to manage heavy metal pollution in surface water and soil, numerous remediation strategies have been established. Therefore, main purpose of this research was to examine feasibility of ecological toxicity assessment for establishing management strategy in heavy metal polluted agricultural fields. Heavy metal concentration in surface water and soil was monitored along with ecotoxicity experiment with Daphnia magna and Eisenia fetida. Result showed that high toxicity was observed in heavily polluted agricultural field with heavy metals. In case of mortality of Daphnia magna (85%) and Eisenia fetida (6.7%), the highest ratio was observed when heavy metal concentration in surface and soil was high. Calculated ecotoxicity index (EI) ranged 0.06-0.30 and the highest EI was observed in heavily polluted sites among 5 abandoned metal mines. Overall, ecological toxicity assessment is necessary to evaluate heavy metal pollution in agricultural fields near at the abandoned metal mines along with chemical concentration analysis.

Contamination of Heavy Metals from Dongmyeong Au-Ag Mine Area (동명 금-은 광산 주변의 중금속 오염)

  • 이광춘;김세현;이승호;서용찬
    • Economic and Environmental Geology
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    • v.36 no.1
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    • pp.17-25
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    • 2003
  • Researches were carried out to investigate the characteristics and concentration of heavy metal elements of stream water through Dongmyoung abandoned metal mine and soil adjacent to the mine. The pH range of water was 5.9∼7.1 that implies the water environment was acidic to neutral. The contents and distribution aspects of heavy metals in water samples varied with geochemical characteristics of element, but the concentration of heavy metals has the tendency of increase closer to the mine in general. The results of soil analysis show that total heavy metal concentration of agricultural soil near mine was far lower than those of ore tailing and dumping site. Therefore, the effects of the abandoned mine on stream water and agricultural products were supposed to be insignificant, particularly because the portion of absorbed carbonates and reducible fractions among total heavy metal concentration was relatively lower than the other. Since, however total heavy metal concentrations of mining site were relatively higher than those of adjacent region, there is a possibility of heavy metal difussion when the chemical environment of the site changes due to migration of surface and underground water. It is suggested that the preventive measures for water and soil pollution by the heavy metals would be considered around the region.

Considerations of Acid Decomposition System for the Analysis of Heavy Metals in Packaging-grade Paper (포장용지류에서의 중금속 분석을 위한 산분해 전처리 방법의 탐색)

  • Lee, Tai-Ju;Ko, Seung-Tae;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.1
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    • pp.65-73
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    • 2011
  • The fibrous raw materials in packaging-grade paper production in Korea were mainly obtained from waste paper. The use of recycled paper has both positive and negative impacts in papermaking process. The primary positive impacts are the environmental protection and manufacturing cost reduction, and the negative impacts are the quality reduction in paper quality and the accumulation of heavy metals and other pollutants in wet- and dry-end process. This study was carried out to consider the optimum acid decomposition system with the highest recovery rate for the analysis of heavy metals in packaging-grade paper. The open digestion system using Kjeldahl apparatus and the closed digestion system using microwave oven for decomposing the organic materials in paper were compared. In both open and closed digestion method, the combination of nitric acid, hydrochloric acid and hydrogen peroxide showed higher recovery rate than using only nitric acid alone because the presence of Cl- ions in hydrochloric acid stabilizes ligand formation with metal ions. KOCC was observed to have the highest heavy metal content among the recycled paper samples. The heavy metal contents decomposed with the closed digestion system were relatively higher than with open digestion system.

A Study on the heavy metal contents in the soils and vegetables (중금속에 의한 토양오염과 그 작물함량에 관한 연구)

  • 김명미;고영수
    • Journal of Food Hygiene and Safety
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    • v.1 no.1
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    • pp.51-56
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    • 1986
  • In the particular area the heavy metal concentrations in the soil were determined and compared to the contents in vegetables which were grown on the soil. Simultaneously the degree of contamination was examined. Samples were collected from Chinese cabbage, radish and Altari-mu, together with the soil on which the three kinds of vegetables have grown. The sites of samples collection were Jinguan-sa(non-polluted area) and Sangaedong(polluted area). The contents of cadimium, copper, lead and zinc were determined by means of atomic absorption spectro-photometer. The results obtained were as follows; 1. In soils, the average contents of heavy metal in Jinguan-sa area (Cd; 0.15ppm, Cu; 0.15ppm, Zn; 11.5ppm) were lower than those in sangye-dong(Cd; 0.26ppm, Cu; 13.0ppm, Zn; 17.1ppm). 2. In vegetables, the average have metal contents in Jinguan-sa were cadmium; 0.11ppm, copper; 5.29ppm, zinc; 18.75ppm and the average contents in Sangye-dong were cadmium; 0.16ppm, copper; 6.64ppm, lead; 0.14ppm, zinc; 15.01ppm. 3. The contents of lead showed zero ppm in Jinguan-sa area(soil and vegetables). In vegetables difference in concentration of heavy metals was not observed between reclaimed area and non reclaimed area. Statistical analysis showed that no correlation in the heavy metal concentrations between those in soils and in vegetables.

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