• Title/Summary/Keyword: Heating Rate

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Stability and Isolation of Monacolin K from Red Yeast Rice (홍국 유래 Monacolin K의 안정성 및 분리)

  • 최무영;곽은정;임성일
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.6
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    • pp.1022-1027
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    • 2004
  • The monacolin K content was determined to investigate the stability of monacolin K from red yeast rice after heating (20∼8$0^{\circ}C$), adjusting the pH (2∼8) by adding 3 N HCl or 3 N NaOH, adding the organic acid (6.0% acetic acid, 0.6% citric acid, 1.5% lactic acid) to pH 4.0 and adding the water (0∼80%). And the monacolin K was isolated from red yeast rice by conducting open column chromatography using neutral aluminum oxide. As a result, the stability of monacolin K decreased with increasing the temperature. The stability for pH was in the order of the unadjusted pH (pH 5.9)>8>4 and pH 2>10. The stability for organic acid was high in the order of lactic acid>citric acid>acetic acid, and the stability of monacolin K under acid was different according to the acid type. The degradation rate of monacolin K increased with increasing the water content. Moreover monacolin K was able to isolate from red and pink pigments as well as the other noncoloric compounds in red yeast rice. The yield of monacolin K was found to be 70%.

Antioxidative Activity and Physiological Function of the Angelica dahurica Roots (백지의 항산화성 및 생리기능)

  • Lee, Yang-Suk;Jang, Sang-Min;Kim, Nam-Woo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.36 no.1
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    • pp.20-26
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    • 2007
  • We analyzed the contents of polyphenol compounds, the antioxidant activity and the physiological activity to investigate the functional effects of extracts from Angelica dahurica by the reflux water extraction (RW), reflux ethanol extraction (RE) and pressure heating water extraction (PW). The content of phenolic compounds of PW was the highest at 156.30 mg/g, and those of RW and RE were 31.69 mg/g and 26.34 mg/g, respectively. The electron donating ability (EDA) were in the range of 30.56% $\sim$ 52.74% and superoxide dismutase (SOD) like activity were 10.96% $\sim$ 23.24% at 1,000 ${\mu}g/mL$. The nitrite scavenging ability of PW at pH 1.2 was 61.47%, higher than those of RW (16.81%) and RE (17.78%). The xanthine oxidase inhibitory were 90.91% and tyrosinase inhibitory rate of RE was the highest (51.71%) at the concentration of 5,000 ${\mu}g/mL$. All extracts were increased with increments of the extract concentrations.

Affected Model of Indoor Radon Concentrations Based on Lifestyle, Greenery Ratio, and Radon Levels in Groundwater (생활 습관, 주거지 주변 녹지 비율 및 지하수 내 라돈 농도 따른 실내 라돈 농도 영향 모델)

  • Lee, Hyun Young;Park, Ji Hyun;Lee, Cheol-Min;Kang, Dae Ryong
    • Journal of health informatics and statistics
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    • v.42 no.4
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    • pp.309-316
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    • 2017
  • Objectives: Radon and its progeny pose environmental risks as a carcinogen, especially to the lungs. Investigating factors affecting indoor radon concentrations and models thereof are needed to prevent exposure to radon and to reduce indoor radon concentrations. The purpose of this study was to identify factors affecting indoor radon concentration and to construct a comprehensive model thereof. Methods: Questionnaires were administered to obtain data on residential environments, including building materials and life style. Decision tree and structural equation modeling were applied to predict residences at risk for higher radon concentrations and to develop the comprehensive model. Results: Greenery ratio, impermeable layer ratio, residence at ground level, daily ventilation, long-term heating, crack around the measuring device, and bedroom were significantly shown to be predictive factors of higher indoor radon concentrations. Daily ventilation reduced the probability of homes having indoor radon concentrations ${\geq}200Bq/m^3$ by 11.6%. Meanwhile, a greenery ratio ${\geq}65%$ without daily ventilation increased this probability by 15.3% compared to daily ventilation. The constructed model indicated greenery ratio and ventilation rate directly affecting indoor radon concentrations. Conclusions: Our model highlights the combined influences of geographical properties, groundwater, and lifestyle factors of an individual resident on indoor radon concentrations in Korea.

Infrared Spectroscopic Evidences for the Superconductivity of $La_2CuO_4$-related Compounds: A Superconductivity Probe

  • Park, Jeong Cheol;Jo, Seon Woog;Jeong, Jong Hak;Jeong, Gi Ho
    • Bulletin of the Korean Chemical Society
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    • v.21 no.10
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    • pp.1041-1043
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    • 2000
  • We present the effects of temperature (between 10 K and 298 K) and of hole concentration on the frequency and intensity of characteristic phonons in polycrystalline $La_2CuO_4-related$ compounds using FT-IR spectros-copy. The influences of the concentration of carrier doped on the phonon modes are prominent in the IR spectra of $La_2CuO_4-related$ compounds. For $La_2-xSrxCuO_4({\chi}=$ 0.00, 0.03, 0.07, 0.10, and 0.15) and electrochemically (or chemically) oxidized $La_2CuO_4$, the intensities of the transverse oxygen mode around 680cm $-^1$ which cor-responds mainly to Cu-O(1) stretching vibration in the basal plane of CuO6 octahedron, are decreased and dis-appeared depending on the Sr-substitution rate and the amount of excess oxygen, while the longitudinal oxygen mode around 510 cm $-^1$ corresponding to the Cu-O(2) stretching in the basal plane of CuO6 octahedron are near-ly invariable. In particular, after two cycles of cooling-heating between 10 K and 298 K for these sample, the phonons around 680 cm $-^1$ are blue shif 13-15 cm $-^1$, while the phonons around 510 cm $-^1$ are nearly constant. The introduction of the charge carrier by doping would give rise to the small contraction of CuO6 oc-tahedron as Cu $^3+$ requires a smaller site than Cu $^2+$, which results in the shortening of the Cu-O(1) bond length and Cu-O(2) bond length with the increased La-O(2) bond length. These results in the frequency shift of the characteristic phonons. The IR spectra of $La_2Li0.5Cu0.5O_4$ which exhibits an insulator behavior despite the $Cu^3+$ of nearly 100%, corroborate our IR interpretations. The mode around 710 cm $-^1$ corresponding to Cu-O(1) stretching vibration is still strongly remained even at low temperature (10 K). Thus, we conclude that the con-duction electrons formed within $CuO_2$ planes of $La_2CuO_4-related$ superconductors screen more effectively the transverse oxygen breathing mode around 680 $cm-^1$ depending on the concentration of the doped charge carrier in $La_2CuO_4-related$ compounds, which might use as a superconductivity probe.

A Study on Energy Efficiency Improvement through Building Insulation Diagnosis (건축물 단열 진단을 통한 에너지 효율 개선에 관한 연구)

  • Cho, Kwangmoon
    • Journal of Internet of Things and Convergence
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    • v.7 no.3
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    • pp.9-14
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    • 2021
  • This paper discovers the energy loss factors through the insulation diagnosis of houses or buildings, and proposes directions for energy efficiency improvement. The energy efficiency factor of a building consists of insulation diagnosis, thermal bridge diagnosis, window diagnosis, airtight diagnosis, and equipment diagnosis. Among the residents and facilities in the energy welfare blind spot, an energy efficiency diagnosis was conducted for one senior citizen building located in Naju-si, Jeollanam-do, and energy efficiency diagnosis was conducted after insulation was installed. Energy measurement, diagnosis and analysis were performed using the IoT-based integrated wired/wireless energy diagnosis platform, Energy Finder. As a result of comparison, an overall energy saving rate of 16.38% was achieved. Annual heating energy consumption per unit area decreased from 333.51kWh before construction to 277.35kWh after construction, and annual cooling energy consumption per unit area decreased from 5.51kWh before construction to 5.22kWh after construction. The annual primary energy consumption per unit area decreased from 464.52kWh before construction to 403.69kWh after construction, and the annual energy cost was reduced from 3,063,307.14 won before construction to 2,641,072.49 won after construction. The additional improvement work is needed on the standards affecting energy efficiency other than insulation.

Characteristics of Manufacturing for Special Cement Using High Chlorine by-product (고염소 부산물을 이용한 특수시멘트 제조 특성)

  • Moon, Kiyeon;Cho, Jinsang;Choi, Moonkwan;Cho, Kyehong
    • Resources Recycling
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    • v.30 no.6
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    • pp.68-75
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    • 2021
  • This study aims to investigate the manufacturing process of calcium chloride-based special cement, i.e., CCA (calcium chloro aluminate, C11A7·CaCl2), which uses limestone, by using one type of random industrial by-product, domestic coal ash, cement kiln dust. The manufacturing process of was examined in detail, and the results suggested that the amount of CCA synthesized increased with an increase in the firing temperature. The manufacturing process of CCA was investigated at 1200℃, which was determined as the optimum firing temperature. The results showed that in general, the amount of CCA synthesized tended to increase with an increase in the firing time; however, the clinker melted when the firing time was more than 30 min, thereby suggesting that a firing time of less than 20 min would be suitable for the clinkering process. The optimal firing conditions for manufacturing CCA were obtained as follows: heating rate of 10 ℃/min, firing temperature of 1200 ℃, and holding time of 20 min. The results also suggest that manufacturing CCA will be easier when high chlorine-containing cement kiln dust is used.

Eco-friendliness Evaluation of a Low-Noise and Dust-Recovery Type Pavement Cutter (저소음·분진회수형 도로절단기의 친환경성 평가)

  • Kim, Kyoon Tai
    • Ecology and Resilient Infrastructure
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    • v.8 no.4
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    • pp.194-203
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    • 2021
  • With the recent increase in maintenance works on water and sewer pipes as well as district heating supply pipes, pavement cutting work using pavement cutter is on the rise. The pavement cutting operation generates considerable dust (cutting sludge) as well as noise; therefore, it is necessary to apply eco-friendly technologies that have low noise and dust recovery capability. Thus far, various equipment for recovering dust have been developed; however, there is a limitation in that the environmental friendliness is not quantified. Therefore, in this study, we developed a low-noise, dust-recovery type pavement cutter that can fundamentally remove the causes of environmental hazards such as noise and dust and evaluated the eco-friendliness of the pavement cutting process performed by this cutter. To this end, an integrated water cooling-sludge recovery system composed of a vacuum device and a sludge suction unit was developed, and the developed system was applied to a pavement cutter. Subsequently, the developed equipment was applied to the test bed, and data related to its eco-friendliness were collected and evaluated. The results showed that the cutting sludge recovery rate of the developed equipment was greater than 83%, the noise level was approximately 82 - 83 dB, and the sound power level was 115 dB. The results of this study will be used as basic data to develop improved pavement cutters in the future with improved cutting sludge recovery performance and lower noise.

Co-firing Characteristics and Slagging Behavior of Sewage Sludge with Coal and Wood Pellet in a Bubbling Fluidized Bed (기포 유동층 반응기를 이용한 하수 슬러지와 석탄 및 우드 펠렛의 혼소 특성 및 슬래깅 성향 연구)

  • Ahn, Hyungjun;Kim, Donghee;Lee, Youngjae
    • Clean Technology
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    • v.24 no.4
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    • pp.323-331
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    • 2018
  • The results of an experimental investigation on the co-firing characteristics and slagging behavior of dried and hydrothermal carbonization sewage sludge, sub-bituminous coal, and wood pellet in a fluidized bed were presented. Combustion tests were conducted in a lab-scale bubbling fluidized bed system at the uniform fuel-air equivalence ratio, air flow rate, and initial bed temperature to measure bed temperature distribution and combustion gas composition. 4 different fuel blending cases were prepared by mixing sewage sludge fuels with coal and wood pellet with the ratio of 50 : 50 by the heating value. $NO_x$ was mostly NO than $NO_2$ and measured in the range of 400 to 600 ppm in all cases. $SO_2$ was considered to be affected mostly by the sulfur content of the sewage sludge fuels. The cases of hydrothermal carbonization sewage sludge mixture showed slightly less $SO_2$ emission but higher fuel-N conversion than the dried sewage sludge mixing cases. The result of fly ash composition analysis implied that the sewage sludge fuels would increase the possibility of slagging/fouling considering the contents of alkali species, such as Na, K, P. Between the two different sewage sludge fuels, dried sewage sludge fuel was expected to have the more severe impact on slagging/fouling behavior than hydrothermal carbonization sewage sludge fuel.

Design and Performance Analysis of Magnetic Resonant Wireless Power Transfer Receiver for Implant Medical Device (인체 삽입형 자기 공진 무선전력전송 수신기 설계 및 성능 분석)

  • Kim, Sungjae;Ku, Hyunchul
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.29 no.12
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    • pp.935-941
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    • 2018
  • In this study, we propose a suitable magnetic resonant wireless power transfer(WPT) system topology for size-limited implant medical devices(IMDs). The proposed modified series-parallel topology(mSPT) can be implemented by adding an inductor in series to the parallel-connected Rx coil and a capacitor. The topology achieves high efficiency when the Rx coil has a small inductance. The validity and operating conditions of the system are verified theoretically through circuit analysis. Experiments were conducted with bio-blocks, which are made of pork fat and muscle. When the Rx coils were inserted into the blocks at a depth of 2.5~10 mm, mSPT showed 17.79 % improved efficiency on average compared with the conventional series-series topology(SST). In the case of 32 dBm WPT in air, the Rx coil's heating rate for the mSPT was $0.18^{\circ}C/s$, whereas the SST was $0.75^{\circ}C/s$. It was confirmed that the mSPT is more suitable for an IMD-targeted WPT system.

Fe-doped beta-tricalcium phosphate; crystal structure and biodegradable behavior with various heating temperature (Fe 이온 치환 beta-tricalcium phosphate의 하소 온도에 따른 미세구조 및 분해 특성)

  • Yoo, Kyung-Hyeon;Kim, Hyeonjin;Sun, Woo Gyeong;Yoon, Seog-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.6
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    • pp.244-250
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    • 2020
  • β-Tricalcium phosphate (β-TCP, Ca3(PO4)2) is a kind of biodegradable calcium phosphate ceramics with chemical and mineral compositions similar to those of bone. It is a potential candidate for bone repair surgery. To improve the bioactivity and osteoinductivity of β-TCP, various ions doped calcium phosphate have been studied. Among them, Iron is a trace element and its deficiency in the human body causes various problems. In this study, we investigated the effect of Fe ions on the structural variation, degradation behavior of β-TCP. Fe-doped β-TCP powders were synthesized by the coprecipitation method, and the heat treatment temperature was set at 925 and 1100℃. The structural analysis was carried out by Rietveld refinement using the X-ray diffraction results. Fe ions existed in a different state (Fe2+ or Fe3+) with different heat treatment temperatures, and the substitution sites (Ca-(4) and Ca-(5)) also changed with temperature. The degradation rate was fastest at Fe-doped β-TCP with heated at 1100℃. The cell viability behavior was also enhanced with the substitution of Fe ions. Therefore, the substitution of Fe ion has accelerated the degradation of β-TCP and improved the biocompatibility. It could be more utilized in biomedical devices.