• Title/Summary/Keyword: Heating Cycle

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Synthesis and Electrochemical Properties of Li[Ni1/3Co1/3Mn1/3]O2 Nanowire by the Electrospinning Method (전기방사법을 이용한 Li[Ni1/3Co1/3Mn1/3]O2 나노 섬유의 합성 및 전기화학적 특성)

  • Kang, Chung-Soo;Son, Jong-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.10
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    • pp.850-854
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    • 2011
  • Nano-fibers of the $Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O_2$ electrode were synthesized from a metal oxide precursor using the electrospun method. The XRD patterns of all prepared powders showed a hexagonal ${\alpha}$ - $NaFeO_2$ structure (space group: R-3 m, 166). Scanning electron microscopy showed that all the synthesized samples were comprised of nanofibers with a size of 100~800 nm. Among the samples tested, the calcined $Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O_2$ nanowires in oxygen heating atmosphere showed a high charge and discharge capacity of 239.22 and 172.81 $mAhg^{-1}$ at the $1^{st}$ cycle, respectively. In addition, the charge transfer resistance was also improved significantly compared to the other samples.

Effect of Training( SIM↔γ) on Shape Memory Effect of Fe-30%Mn-6%Si Alloy (Fe-30%Mn-6% Si 합금의 형상기억효과에 미치는 Training(SIM↔γ)의 영향)

  • Han, Sang Ho;Jun, Joong Hwan;Choi, Chong Sool
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.2
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    • pp.118-128
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    • 1994
  • Five alloys were selected randomly in the composition range showing the best shape memory effect in Fe-Mn-Si system reported by Murakami. The shape memory effects of those alloys were mainly investigated through the training treatment which consisted of the repetition of 2% tensile deformation at room temperature and subsequent annealing at $600^{\circ}C$ above $A_r$ temperature. At the same deformation degress in rolling $600^{\circ}C$-annealing for 1 hr. showed the best shape memory effect, and 10%-deformation degrees represented maxima of the shpae memory effects at all annealing temperatures, $500^{\circ}C$, $600^{\circ}C$ and $700^{\circ}C$. The shape memory effects of the alloys were increased by increasing training cycle up to 5 cycles. This was because a large number of dislocations introduced by training process gave rise to increase in the austenite yield stress, and acted as nucleation sites for stress induced ${\varepsilon}$ martensite. The thermal cycling treatment, repetition of cooling in nitrogen at $-196{\circ}C$ and heating to $300^{\circ}C$ for 5 min., did not improve the shape memory effect.

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Numerical simulations of mountain winds in an alpine valley

  • Cantelli, Antonio;Monti, Paolo;Leuzzi, Giovanni;Valerio, Giulia;Pilotti, Marco
    • Wind and Structures
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    • v.24 no.6
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    • pp.565-578
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    • 2017
  • The meteorological model WRF is used to investigate the wind circulation in Valle Camonica, Italy, an alpine valley that includes a large subalpine lake. The aim was to obtain the information necessary to evaluate the wind potential of this area and, from a methodological point of view, to suggest how numerical modeling can be used to locate the most interesting spots for wind exploitation. Two simulations are carried out in order to analyze typical scenarios occurring in the valley. In the first one, the diurnal cycle of thermally-induced winds generated by the heating-cooling of the mountain range encircling the valley is analyzed. The results show that the mountain slopes strongly affect the low-level winds during both daytime and nighttime, and that the correct setting of the lake temperature improves the quality of the meteorological fields provided by WRF significantly. The second simulation deals with an event of strong downslope winds caused by the passage of a cold front. Comparisons between simulated and measured wind speed, direction and air temperature are also shown.

Simulation on the Optimal Performance and Effective Operating Range of a 2-Stage Compression Heat Pump Using River Water (하천수 열원 이용 2단압축 열펌프의 최적성능 및 효용 운전범위에 관한 시뮬레이션 연구)

  • Jung, Tae-Hun;Park, Cha-Sik;Kim, Yong-Chan
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.20 no.5
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    • pp.295-303
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    • 2008
  • The objectives of this study are to predict actual system performance and effective operating range of the 2-stage compression heat pump system using river water. An electronic expansion valve was applied to the simulation to analyze the effects of operating conditions on the system performance. The developed program was verified by comparing the predictions with the measured data. The results from the present model showed a good agreement with the measured data. In addition, the heat pump simulation was conducted by increasing condenser reservoir inlet temperature to investigate the benefits of the 2-stage compression over the 1-stage compression in the heating mode. The performance of the 2-stage compression cycle was better than that of the 1-stage compression when the inlet temperature of the condenser reservoir was higher than $40^{\circ}C$.

Exergy and exergoeconomic analysis of hydrogen and power cogeneration using an HTR plant

  • Norouzi, Nima;Talebi, Saeed;Fani, Maryam;Khajehpour, Hossein
    • Nuclear Engineering and Technology
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    • v.53 no.8
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    • pp.2753-2760
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    • 2021
  • This paper proposes using sodium-cooled fast reactor technologies for use in hydrogen vapor methane (SMR) modification. Using three independent energy rings in the Russian BN-600 fast reactor, steam is generated in one of the steam-generating cycles with a pressure of 13.1 MPa and a temperature of 505 ℃. The reactor's second energy cycles can increase the gas-steam mixture's temperature to the required amount for efficient correction. The 620 ton/hr 540 ℃ steam generated in this cycle is sufficient to supply a high-temperature synthesis current source (700 ℃), which raises the steam-gas mixture's temperature in the reactor. The proposed technology provides a high rate of hydrogen production (approximately 144.5 ton/hr of standard H2), also up to 25% of the original natural gas, in line with existing SMR technology for preparing and heating steam and gas mixtures will be saved. Also, exergy analysis results show that the plant's efficiency reaches 78.5% using HTR heat for combined hydrogen and power generation.

Modified sigmoid based model and experimental analysis of shape memory alloy spring as variable stiffness actuator

  • Sul, Bhagoji B.;Dhanalakshmi, K.
    • Smart Structures and Systems
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    • v.24 no.3
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    • pp.361-377
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    • 2019
  • The stiffness of shape memory alloy (SMA) spring while in actuation is represented by an empirical model that is derived from the logistic differential equation. This model correlates the stiffness to the alloy temperature and the functionality of SMA spring as active variable stiffness actuator (VSA) is analyzed based on factors that are the input conditions (activation current, duty cycle and excitation frequency) and operating conditions (pre-stress and mechanical connection). The model parameters are estimated by adopting the nonlinear least square method, henceforth, the model is validated experimentally. The average correlation factor of 0.95 between the model response and experimental results validates the proposed model. In furtherance, the justification is augmented from the comparison with existing stiffness models (logistic curve model and polynomial model). The important distinction from several observations regarding the comparison of the model prediction with the experimental states that it is more superior, flexible and adaptable than the existing. The nature of stiffness variation in the SMA spring is assessed also from the Dynamic Mechanical Thermal Analysis (DMTA), which as well proves the proposal. This model advances the ability to use SMA integrated mechanism for enhanced variable stiffness actuation. The investigation proves that the stiffness of SMA spring may be altered under controlled conditions.

Study on the Atomic Layer Deposition System and Process of the MgO Thin Layer for the Thin Film Encapsulation of OLED (OLED의 Thin Film Encapsulation을 위한 MgO 박막의 원자층 증착 장치 및 공정에 관한 연구)

  • Cho, Eou Sik;Kwon, Sang Jik
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.3
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    • pp.22-26
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    • 2021
  • Thin-film encapsulation (TFE) technology is most effective in preventing water vapor and oxygen permeation in the organic light emitting diodes (OLED). Of those, a laminated structure of Al2O3 and MgO were applied to provide efficient barrier performance for increasing the stability of devices in air. Atomic layer deposition (ALD) method is known as the most promising technology for making the laminated Al2O3/MgO and is used to realize a thin film encapsulation technology in organic light-emitting diodes. Atomic layer deposited inorganic films have superior barrier performance and have advantages of excellent uniformity over large scales at relatively low deposition temperatures. In this study, the control system of the MgCP2 precursor for the atomic layer deposition of MgO was established in order to deposit the MgO layer stably by the injection time of second level and the stable heating temperature. The deposition rate was obtained stably to be from 4 to 10 Å/cycle using the injection pulse times ranging from 3 to 12 sec and a substrate temperature ranging from 80 to 150 ℃.

Effect of reaction temperature and time on the formation of calcite precipitation of recycled concrete aggregate (RCA) for drainage applications

  • Boo Hyun Nam;Jinwoo An;Toni Curate
    • Geomechanics and Engineering
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    • v.33 no.1
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    • pp.65-75
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    • 2023
  • Recycled concrete aggregate (RCA) is widely used as a construction material in road construction, concrete structures, embankments, etc. However, it has been reported that calcite (CaCO3) precipitation from RCA can be a cause of clogging when used in drainage applications. An accelerated calcite precipitation (ACP) procedure has been devised to evaluate the long-term geochemical performance of RCA in subsurface drainage systems. While the ACP procedure was useful for the French Drain application, there remained opportunities for improvement. In this study, key factors that control the formation of calcite precipitation were quantitatively evaluated, and the results were used to improve the current prototype ACP method. A laboratory parametric study was carried out by investigating the effects of reaction temperature and time on the formation of calcite precipitation of RCA, with determining an optimum reaction temperature and time which maximizes calcite precipitation. The improved ACP procedure was then applied to RCA samples that were graded for Type I Underdrain application, to compare the calcite precipitation. Two key findings are (1) that calcite precipitation can be maximized with the optimum heating temperature (75℃) and time (17 hours), and (2) the potential for calcite precipitation from RCA is not as significant as for limestone. With the improved ACP procedure, the total amount of calcite precipitation from RCAs within the life cycle of a drain system can be determined when RCAs from different sources are used as pipe backfill materials in a drain system.

Investigation on effect of neutron irradiation on welding residual stresses in core shroud of pressurized water reactor

  • Jong-Sung Kim;Young-Chan Kim;Wan Yoo
    • Nuclear Engineering and Technology
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    • v.55 no.1
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    • pp.80-99
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    • 2023
  • This paper presents the results of investigating the change in welding residual stresses of the core shroud, which is one of subcomponents in reactor vessel internals, performing finite element analysis. First, the welding residual stresses of the core shroud were calculated by applying the heat conduction based lumped pass technique and finite element elastic-plastic stress analysis. Second, the temperature distribution of the core shroud during the normal operation was calculated by performing finite element temperature analysis considering gamma heating. Third, through the finite element viscoelastic-plastic stress analysis using the calculated temperature distribution and setting the calculated residual stresses as the initial stress state, the variation of the welding residual stresses was derived according to repeating the normal operation. In the viscoelastic-plastic stress analysis, the effects of neutron irradiation on mechanical properties during the cyclic normal operations were considered by using the previously developed user subroutines for the irradiation agings such as irradiation hardening/embrittlement, irradiation-induced creep, and void swelling. Finally, the effect of neutron irradiation on the welding residual stresses was analysed for each irradiation aging. As a result, it is found that as the normal operation is repeated, the welding residual stresses decrease and show insignificant magnitudes after the 10th refueling cycle. In addition, the irradiation-induced creep/void swelling has significant mitigation effect on the residual stresses whereas the irradiation hardening/embrittlement has no effect on those.

Evaluation of Operational Performance and Carbon Emissions for the Feasibility of Air Source Heat Pump Application in Residential Buildings (공동주택의 공기열원 히트펌프 적용가능성 검토를 위한 운전성능 및 탄소배출량 평가)

  • Junseok Kim;Jongsoo Kim;Yongseok Jeon
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.20 no.2
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    • pp.24-36
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    • 2024
  • This study analyzed the feasibility of the air source heat pump in residential buildings based on operational performance and carbon emissions. The operational performance and carbon emissions were compared between a gas boiler and an air source heat pump by calculating the annual heating and hot water load based on the 21A and 36A models for actual residential buildings. For the operational performance of the air source heat pump, the lowest (2.3) and highest COP (5.9) were attained during the winter and summer seasons, respectively. The carbon emissions depend on the amount of energy consumed during operations. An air source heat pump consumed 65.10% and 65.4% less energy per year in the 21A and 36A models, respectively compared to the existing gas boiler. Consequently, for air source heat pump carbon emissions were also reduced by 13.3% and 15.1% per year for the 21A and 36A models, respectively. It shows the effectiveness of applying an air source heat pump compared to an existing gas boiler.