• 제목/요약/키워드: Heat of Fusion

검색결과 441건 처리시간 0.026초

Crystallization-induced Sequential Reordering in Poly (trimethylene to rephthalate)/Polycarbonate Blends

  • Bae, Woo-Jin;Jo, Won-Ho;Park, Yeun-Hum
    • Macromolecular Research
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    • 제10권3호
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    • pp.145-149
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    • 2002
  • Transesterification between poly(trimethylene terephthalate) (PTT) and bisphenol-A-polycarbonate (PC) is studied by differential scanning calorimetry (DSC) and nuclear magnetic resonance (NMR) spectroscopy. When the blend of PTT/PC is annealed at higher temperatures, the samples do not show any melting peak at an initial stage, indicating the samples completely lose their crystallinity due to the formation of random copolymers. However, when the random copolymer is annealed at temperatures lower than the melting temperature of PTT, a melting peak is observed, indicating that the random copolymers are sequentially reordered. The melting point and the heat of fusion of crystals formed from the crystallization-induced sequential reordering depend upon the annealing temperature and time. The average sequence length determined from NMR is increased as the blocks are regenerated.

관내권선(Cable-In-Conduit, CIC) 초전도 자석(Superconducting magnet)에서의 한계 자속 변화(ramp-rate limitation) 현상 (Ramp-rate limitation of CIC(Cable-In-Conduit) superconducting magnet)

  • 정상권
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 A
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    • pp.37-40
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    • 1996
  • Cable-In-Conduit Conductor(CICC) is widely accepted as an advanced superconductor configuration for large scale applications such as tokamak fusion reactors, MAGLEV (MAGnetic LEVitation), and SMES (Superconducting Magnetic Energy Storage). The stability of CICC cooled with supercritical helium can be very high if it is operated below a certain limiting current. This limiting current can be determined by Stekly type heat balance equation. The stability characteristic of CICC for AC operation is more complicated than that of DC because there are additional instability sources which are associated with local flux change. Ramp-rate limitation is a phenomenon discovered during US-DPC (United States-Demonstration Poloidal Coil) program, which showed apparent quench current degradation associated with high dB/dt. This paper describes recent experimental investigation results on the ramp-rate limitation and discusses current imbalance, induced current, current redistribution due to local quench of the strand in the cable.

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마찰교반용접에서 툴의 형상이 접합부 강도에 미치는 영향에 관한 연구 (The Effect of Strength by Changing Tool Shape in the Friction Stir Welding)

  • 천창근;김흥주;박인규;전시현;장웅성
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2009년도 춘계학술대회 논문집
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    • pp.1613-1617
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    • 2009
  • As demand regarding a recent energy-saving rises, the using ratio of the aluminum plate in manufacturing of a railroad vehicle has been increasing. The aluminum structure to be applied to a railroad vehicle is divided to single skin and double skin, and the main aluminum product is mainly Al 6005 extrude and Al 5083 rolled in domestic market. The Al 6005 alloy is applied heat treatment in order to improve the strength of material. Therefore there is the disadvantage that the strength of welding zone decreases compare with base material's if you apply to fusion welding like MIG(metal inert gas) welding. In this paper we tried to apply friction stir welding to solve these problems. In this study we investigated how tensile strength and fatigue strength were changed in case of changing the shoulder diameter of thread tool.

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9% 니켈강 후판 용접부의 강도 및 잔류응력 (Welding Residual Stress and Strength of Thick 9% Nickel Steel Plate)

  • 김영균;김영완;김재훈
    • 동력기계공학회지
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    • 제18권4호
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    • pp.85-90
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    • 2014
  • In this paper, the transient thermal and residual stress analysis of the welding of 9% Ni steel plates using the FEA software ABAQUS are presented. The 9% Ni steel plates are welded manually with welding consumables of 70% Ni based Inconel type super-alloys (YAWATA WELD B (M)), producing a multi-pass/multi-layer butt weld. For these materials, temperature dependant mechanical and thermal material properties are used in the analysis. The back gouging is considered in welding process simulation. The FE thermal results are validated by comparing the real fusion profile and heat affected zone (HAZ). In addition, the continuous indentation test was conducted to measure the strength of base metal, HAZ and weld metal.

질화처리된 저탄소강 레이저 용접부의 기공 감소 (Porosity Reduction in Laser Welding of Nitrided Carbon Steel)

  • 안영남;김철희;이원범;김정한
    • Journal of Welding and Joining
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    • 제31권6호
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    • pp.71-76
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    • 2013
  • Gas nitriding is a surface hardening process where nitrogen is introduced into the surface of a ferrous alloy. During fusion welding of nitrided carbon steel, the nitride inside weld metal is dissolved and generates nitrogen gas, which causes porosities - blow holes and pits. In this study, several laser welding processes such as weaving welding, two-pass welding, dual beam welding and laser-arc hybrid welding were investigated to elongate the weld pool to enhance nitrogen gas evacuation. The surface pits were successfully eliminated with elongated weld pool. However blowholes inside the weld metal were effective reduced but not fully disappeared.

하이브리드 용접과 레이저 용접에 의한 세립강 용접부의 미세조직변화에 관한 연구 (Microstructure Evolution of UFG Steel Weld by Hybrid and Laser Welding)

  • 동현우;이목영;안용식
    • 동력기계공학회지
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    • 제14권3호
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    • pp.58-63
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    • 2010
  • A laser beam welding and an electric arc welding were combined, and the positive points of each welding method are drawn such as high speed, low thermal load, deep penetration, and high productivity. The fiber laser-MIG conjugated welding. namely the hybrid welding has been studied mainly for the automation industry of a pipeline welding. In this study, the MIG welding was combined with a fiber laser welding to make up the hybrid welding. The weld shapes, microstructures and mechanical properties for weld zones after the hybrid welding or only fiber laser welding were investigated on the 700 MPa grade Ultra Fine Grained(UFG) high strength steel. The amount of acicular ferrite in weld metals and HAZ(heat affected zone) was observed larger after hybrid welding compared with after only laser welding. The Vickers hardness of the top area of the fusion zone after fiber laser welding was higher compared with after hybrid welding.

$60kg/mm^2$급 조질고장력강의 용접입열량에 따른 미세조직변화 (Microstructural Changes on Weld Heat Input in $60kg/mm^2$ Quenched and Tempered High Strength Steel)

  • 김은석;정인상;박경채
    • Journal of Welding and Joining
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    • 제11권4호
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    • pp.79-90
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    • 1993
  • Shielded metal arc welding, one-ploe and two-pole submerged arc welding were accomplished to investigate microstructure changes on phase transformation behavior in $60kg/mm^2$ quenched and tempered high strength steel. Microstructures were examined by optical micrograph and TEM. In shielded metal arc welding (oxygen 250ppm), the inclusions were small size (0.3-0.5$\mu\textrm{m}$)and small in number. In submerged arc welding (oxygen 430-529ppm), the inclusions were larger(0.7-2$\mu\textrm{m}$) than that of shielded metal arc welding and large in number. Microstructure mainly depends on number and distribution of inclusions in fusion zone of weld metal. It was noticed that a limited number of inclusions favors the formation of acicular ferrite.

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적외선 센서를 이용한 금속아크 용접 공정 모니터링 (Monitoring of the GMAW Process Using Infra-red Sensor)

  • 정영재;김일수;박창언;김수광
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 1996년도 특별강연 및 추계학술발표 개요집
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    • pp.142-144
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    • 1996
  • This paper discusses the application of infra-red thermography in monitoring the robotic arc welding process, and it's potential for weld bead dimension and seam tracking control. Thermal images illustrating weld pool formation dynamics and heat distribution phenomena are digitized and their characteristics are measured. At each sampling point the maximum depth of penetration is recorded together with additional information regarding weld bead placement in relation to the seam location. Deficiencies such as incomplete penetration and lack of side wall fusion are readily identified and can be remained during the process. The technique can help an increase in productivity and weld quality by minimizing the amount of post process rework and inspection efforts needed otherwise.

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계장형 압입시험법에 의한 원자력 구조재료 용접 물성치 측정 (Measurement of Mmechanical Properties in Weld Zone of Nuclear Material using an Instrumented Indentation Technique)

  • 송기남;노동성
    • Journal of Welding and Joining
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    • 제30권3호
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    • pp.51-56
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    • 2012
  • Different microstructures in the weld zone of a metal structure including a fusion zone and heat affected zone are formed as compared to the base material. Thus, the mechanical properties in the weld zone are different from those in the base material. As the basic data for reliably understanding the structural characteristics of welded nuclear material, the mechanical properties in the weld zone and base material for a Zircaloy-4 strap and Hastelloy${(R)}$-X alloy strap are measured using an instrumented indentation technique (IIT) in this study.

Manufacturing and testing of flat-type divertor mockup with advanced materials

  • Nanyu Mou;Xiyang Zhang;Qianqian Lin;Xianke Yang;Le Han;Lei Cao;Damao Yao
    • Nuclear Engineering and Technology
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    • 제55권6호
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    • pp.2139-2146
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    • 2023
  • During reactor operation, the divertor must withstand unprecedented simultaneous high heat fluxes and high-energy neutron irradiation. The extremely severe service environment of the divertor imposes a huge challenge to the bonding quality of divertor joints, i.e., the joints must withstand thermal, mechanical and neutron loads, as well as cyclic mode of operation. In this paper, potassium-doped tungsten (KW) is selected as the plasma facing material (PFM), oxygen-free copper (OFC) as the interlayer, oxide dispersion strengthened copper (ODS-Cu) alloy as the heat sink material, and reduced activation ferritic/martensitic (RAFM) steel as the structural material. In this study, a vacuum brazing technology is proposed and optimized to bond Cu and ODS-Cu alloy with the silver-free brazing material CuSnTi. The most appropriate brazing parameters are a brazing temperature of 940 ℃ and a holding time of 15 min. High-quality bonding interfaces have been successfully obtained by vacuum brazing technology, and the average shear strength of the as-obtained KW/Cu and ODS-Cu alloy joints is ~268 MPa. And a fabrication route for manufacturing the flat-type divertor target based on brazing technology is set. For evaluating the reliability of the fabrication technologies under the reactor relevant condition, the high heat flux test at 20 MW/m2 for the as-manufactured flat-type KW/Cu/ODS-Cu/RAFM mockup is carried out by using the Electron-beam Material testing Scenario (EMS-60) with water cooling. This paper reports the improved vacuum brazing technology to connect Cu to ODS-Cu alloy and summarizes the production route, high heat flux (HHF) test, the pre and post non-destructive examination, and the surface results of the flat-type KW/Cu/ODS-Cu/RAFM mockup after the HHF test. The test results demonstrate that the mockup manufactured according to the fabrication route still have structural and interfacial integrity under cyclic high heat loads.