• Title/Summary/Keyword: Heat/Mass Transfer

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A study on the Optimization of Activated carbon Adsorbent Preparation condition and Evaluation of Application Supporting of K-Fe-Li ternary metal ions for Improving Adsorption Capacity of Hydrogen Sulfide (H2S) (황화수소(H2S) 흡착성능 증진을 위한 K-Fe-Li 3원계 금속이온물질이 담지된 활성탄 흡착제 제조조건 최적화 및 적용성 평가 연구)

  • Choi, Sung Yeol;Han, Dong hee;Kim, Sung Su
    • Clean Technology
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    • v.25 no.3
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    • pp.189-197
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    • 2019
  • In this study an optimization of the preparation conditions of activated carbon with a ternary metal ion material to treat $H_2S$, which is classified as a representative odor substance, was carried out. For a metal ion material for enhancing the adsorption performance of hydrogen sulfide, performance enhancement was confirmed by combining Li and Fe or a ternary combination (K, Li, Fe) based on KI, which is a substance promoting hydrogen sulfide adsorption performance. Also, it was determined by XRD analysis that the reaction of each active substance with $H_2S$ was because of binding. The adsorption performance increased more than 3 times with heat treatment of the adsorbent with nitrogen compared with heat treatment with air. The maximum adsorption constant ($q_m$) value of the optimum adsorbent was 97.07, which is 6 times higher than that of the existing K-based impregnated activated carbon. It was confirmed that the objective adsorption amount ($0.3g\;g^{-1}$) was secured by an equilibrium between the mass transfer rate and adsorption rate. From the results, it was confirmed that the performance improvement was noticeable even when activated carbon with a reagent grade activated carbon particle size was modified. It was confirmed that the adsorption performance exists at high relative humidity levels of 60 and 100%, and the optimized preparation can be applied to a wet process such as a scrubber downstream.

Barrier Techniques for Spinal Cord Protection from Thermal Injury in Polymethylmethacrylate Reconstruction of Vertebral Body : Experimental and Theoretical Analyses (Polymethylmethacrylate를 이용한 척추체 재건술에서 척수의 열 손상을 방지하기 위한 방어벽 기법 : 실험적 및 이론적 분석)

  • Park, Choon Keun;Ji, Chul;Hwang, Jang Hoe;Kwun, Sung Oh;Sung, Jae Hoon;Choi, Seung Jin;Lee, Sang Won;Park, Sung Chan;Cho, Kyeung Suok;Park, Chun Kun;Yuan, Hansen;Kang, Joon Ki
    • Journal of Korean Neurosurgical Society
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    • v.30 no.3
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    • pp.272-277
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    • 2001
  • Objective : Polymethylmethacrylate(PMMA) is often used to reconstruct the spine after total corpectomy, but the exothermic curing of liquid PMMA poses a risk of thermal injury to the spinal cord. The purposes of this study are to analyze the heat blocking effect of pre-polymerized PMMA sheet in the corpectomy model and to establish the minimal thickness of PMMA sheet to protect the spinal cord from the thermal injury during PMMA cementation of vertebral body. Materials & Methods : An experimental fixture was fabricated with dimensions similar to those of a T12 corpectomy defect. Sixty milliliters of liquid PMMA were poured into the fixture, and temperature recordings were obtained at the center of the curing PMMA mass and on the undersurface(representing the spinal cord surface) of a prepolymerized PMMA sheet of variable thickness(group 1 : 0mm, group 2 : 5mm, or group 3 : 8mm). Six replicates were tested for each barrier thickness group. Results : Consistent temperatures($106.8{\pm}3.9^{\circ}C$) at center of the curing PMMA mass in eighteen experiments confirmed the reproducibility of the experimental fixture. Peak temperatures on the spinal cord surface were $47.3^{\circ}C$ in group 2, and $43.3^{\circ}C$ in group 3, compared with $60.0^{\circ}C$ in group 1(p<0.00005). So pre-polymerized PMMA provided statistically significant protection from heat transfer. The difference of peak temperature between theoretical and experimental value was less than 1%, while the predicted time was within 35% of experimental values. The data from the theoretical model indicate that a 10mm barrier of PMMA should protect the spinal cord from temperatures greater than $39^{\circ}C$(the threshold for thermal injury in the spinal cord). Conclusion : These results suggest that pre-polymerized PMMA sheet of 10mm thickness may protect the spinal cord from the thermal injury during PMMA reconstruction of vertebral body.

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Numerical Study on the Performance Assessment for Defrost and De-Icing Modes (승용차의 제상 및 성에 제거 성능 평가를 위한 수치해석적 연구)

  • Kim, Yoon-Kee;Yang, Jang-Sik;Kim, Kyung-Chun;Ji, Ho-Seong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.2
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    • pp.161-168
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    • 2011
  • The heating, ventilating, air conditioning (HVAC) system is a very important part of an automotive vehicle: it controls the microclimate inside the passenger's compartment and removes the frost or mist that is produced in cold/rainy weather. In this study, the numerical analysis of the defrost duct in an HVAC system and the de-icing pattern is carried out using commercial CFX-code. The mass flow distribution and flow structure at the outlet of the defrost duct satisfied the duct design specification. For analyzing the de-icing pattern, additional grid generation of solid domain of ice and glass is pre-defined for conductive heat transfer. The flow structure near the windshield, streakline, and temperature fields clearly indicate that the de-icing capacity of the given defrost duct configuration is excellent and that it can be operated in a stable manner. In this paper, the unsteady changes in temperature, water volume fraction, and static enthalpy at four monitoring points are discussed.

Empirical Orthogonal Function Analysis on the Monthly Variation of Flow Pattern in the East Sea of Kore (경험적 고유함수법에 의한 한국동해 해황변동해석)

  • CHANG Sun-Duck;LEE Jong-Sup;SUH Jong-Moon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.21 no.6
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    • pp.323-330
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    • 1988
  • The spatial distribution of sea water temperature variation pattern in the South-eastern coastal region of Korea was studied by empirical orthogonal function (E. O. F) analysis in several depths from surface to 300m using the monthly mean water temperature averaged for 23 years, water mass analysis by T. S diagram and sectional diagram of water temperature. Typical type of water temperature variation in this area can be divided into surface (0m-50m), subsurface (100m-150m) and intermediate (200m-300m) layer. The first mode value of water temperature change on the surface layer showed $99\%$ of total variation, and decreased with the increase of the depth. It is deduced to be in the range of $60-70\%$ on the 300m layer. The representative type of water temperature fluctuation by the first mode in each layer is as follows. Water temperature change in the surface layer showed a seasonal variation. In the subsurface layer, it is governed by the interaction of the Tsushima Warm Current water with the cold water and by the heat transfer process from the upper layer. In the intermediate layer, water temperature variation seems to be governed by the advection of the bottom cold water.

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Basic Studies in Improvement of Freeze Concentration -(II) The Growth Rate and the Variety in Diameters of Ice Crystals- (동결농축(凍結濃縮)의 개선(改善)을 위한 기초적연구(基礎的硏究) -II. 빙결정(氷結晶)의 성장속도(成長速度)와 입경분포(粒徑分布)-)

  • Kong, Jai-Yul
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.14 no.4
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    • pp.359-364
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    • 1985
  • Being used the three kinds of aqueous solution of tobacco extracts as a new experimental material, experiment and theoretical analysis are performed. Measurements are made with a apparatus designed and constructed by the author.The average diameter of the ice crystals is 0.04-0.1cm between 0.2 and $0.6^{\circ}C$ of the subcooling temperature of the solution. The growth rate of ice crystals in direction of axies A, $V_a$ is in proportion to the subcooling temperature, viz; $v_a=0.058{\Delta}t_b,\;where\;{\Delta}t_b<0.1^{\circ}C$ The growth rate of ice crystal have to be considered not only the mass diffusion and the heat transfer of rate controlling but also the process in ice crystallization. The growth rate of ice crystal is found to be independent on the concentration of the solution and a diameter of ice crystal.

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Studies on Food Preservation by Controlling Water Activity 1. Measurement of Sorption Isotherm of Dried Filefish Muscle by Equilibration in Dynamic Stream of Conditioned Air (식품보장과 수분활성에 관한 연구 1. 조절기류에 의한 건조말쥐치육의 등온흡습곡선의 측정)

  • HAN Bong-Ho;CHOI Soo-Il
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.14 no.4
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    • pp.189-193
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    • 1981
  • An apparatus for continuous measurements of sorption isotherm of dried food was manufactured to shorten the time required for equilibration. The apparatus was so designed that the temperature, air velocity and relative humidity in the experimental chamber could be controlled. The use of dynamic stream of conditioned air with a velocity of 0.2m/sec, instead of static atmosphere, allowed a faster equilibration of dried filefish muscle at $25^{\circ}C$. The mean time necessary for the equilibration of dried filefish muscle at the water activity of a given state to a higher water activity was about 45 hours. The monolayer moisture content of dried filefish muscle calculated from BET-equation was 0.092 kg water /kg dry matter at $25^{\circ}C$.

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Simulation of Rough Rice Drying by Natural Air(I) (자연공기(自然空氣)에 의한 벼건조(乾燥) 시뮤레이션(I))

  • Chang, D.I.;Chung, D.S.;Pfost, H.B.;Calderwood, D.L.
    • Korean Journal of Agricultural Science
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    • v.10 no.1
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    • pp.118-128
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    • 1983
  • Simulation model of natural air grain drying was discussed and modified to predict the changes of grain moisture content and dry matter loss of rough rice drying. The modified simulation model was then validated using actual test data. A series of simulated drying tests using official weather data for 15 years from Beaumont, Texas, was taken to make minimum airflow rate and maximum bed depth of rough rice drying by natural air, under different conditions of initial moisture content of rough rice, airflow rate and harvest date.

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A Reaction Kinetic for Selective Catalytic Reduction of NOx with NH3 over Manganese Oxide (NMO, MnO2, Mn2O3) at Low Temperature (망간산화물(NMO, MnO2, Mn2O3)을 이용한 저온에서의 NH3-SCR의 반응속도 연구)

  • Kim, Min Su;Hong, Sung Chang
    • Clean Technology
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    • v.24 no.4
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    • pp.307-314
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    • 2018
  • In this study, NMO (Natural Manganese Ore), $MnO_2$, and $Mn_2O_3$ catalysts were used in the selective catalytic reduction process to remove nitrogen oxides (NOx) using $NH_3$ as a reducing agent at low temperatures in the presence of oxygen. In the case of the NMO (Natural Manganese Ore), it was confirmed that the conversion of nitrogen oxides in the stability test did not change even after 100 hours at 423 K. The Kinetics experiments were carried out within the range where heat and mass transfer were not factors. From a steady-state Kinetics study, it was found that the low-temperature SCR reaction was zero order with the respect to $NH_3$ and 0.41 ~ 0.57 order with the respect to NO and 0.13 ~ 0.26 order with the respect to $O_2$. As temperature increases, the reaction order decreases as a result of $NH_3$ and oxygen concentration. It was confirmed that the reaction between the $NH_3$ dissociated and adsorbedon the catalyst surface and the gaseous nitrogen monoxide (E-R model) and the reaction with the adsorbed nitrogen monoxide (L-H model) occur.

Study on the Storage of Chestnut (밤 저장(貯藏)에 관(關)한 연구(硏究))

  • Yim, Ho;Kim, Choung-Ok;Shin, Dang-Wha;Suh, Kee- Bong
    • Korean Journal of Food Science and Technology
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    • v.12 no.3
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    • pp.170-175
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    • 1980
  • A mass production of chestnut necessiates the development of economic long-term storage method. The main objective of this study was to confirm the technical aspect of the chestnut storage method which was developed by two year project and to review the method of commercial application. The chestnut used for the experiments were separated in brine $(5.5{\sim}6.0^{\circ}\:B{\acute{a}}ume)$ into matured and unmatured lots and fumigated with $CS_2$ at a 5 $lb/27\;m^3$ level for $25{\sim}30\;hrs.$ The chestnuts were packed in wooden boxes with sawdust (50% moisture) in the ratio of 1 : 1 by volume. The boxes were stored in the cold room $(1{\pm}1^{\circ}C,\;85{\sim}95%\;RH)$ and the cellar ($0{\sim}10^{\circ}C$, controlled only by circulating night cool air). The results obtained were as follows: 1. Fully matured chestnut could be successfully preserved $8{\sim}9\;months$ at a l0% decay level in the cold room and $4{\sim}5\;months$ months in cellar. 2. Immatured chestnuts wire inferior to the matured in storage stability. At the maximum storage period, its storage life was two months shorter. 3. The heat transfer equation of piled chestnuts with sawdust can be suggested as $T_{\infty}-T_0=(T_{\infty}-T_0){\cdot}10^{-t/320}$ and j and $f_h$ values were 1 and 320 min, respectively. 4. The chestnuts in the package of storage unit had longer shelf life than naked chestnut during the retail distribution at ambient temperature.

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