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INFLUENCES OF SILANE CONCENTRATION FOR FILLER SILANIZATION ON THE PROPERTIES OF COMPOSITES (필러의 실란처리농도가 복합레진의 특성에 미치는 영향)

  • 조태희;박상진
    • Restorative Dentistry and Endodontics
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    • v.26 no.1
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    • pp.23-31
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    • 2001
  • The purpose of this study was to search the optimal silane concentrations for filler- silanization of seven experimental composites. Silica filer was a 25micron crushed type. 0.0%, 0.5%, 1.0%, 1.5%, 2.0%, 2.5%, and 3.0% silane($\gamma$-methacrylooxypropyltrimethoxysilane)were added into silica-filler with weight percentage (wt%). Mixtures(silica filler/silane)were reacted at 6$0^{\circ}C$ for 72hours, and crushed into fine particles those were used as fillers for 7 experimental composites. Monomer was a 3 : 1 mixture of Bis-GMA and TEGDMA containing 0.2% tertiary amine and 0.4% camphoroquinone for light curability. A ratio for mixing the monomer and filler was 75% and 25% respectively. Seven experimental composites was classified with the concentration of silane treated, and the specimen number for each test was 10. Specimens with 6mm diameter and 3mm height dimension for measuring the diametral tensile strength were destroyed with 1mm/min cross-head speed on Instron universal testing machine (No. 4467, USA). Shear bond strength was measured on the specimens bonded to bovine enamel etched with 37% phosphoric acid solution for 1 minute Fractured surfaces were observed by SEM (Hitachi S-3200, Japan) among that of the highest values measured from each groups. Following results were obtained: 1. Experimental composites containing silanized filter showed the significantly higher diametral tensile strength and shear bond strength than the composites containing un-silanized fillers(Group1) (p<0.05). 2. In silanized filler composite resins(Group 2~7), Diametral tensile strength of Group 3 showed the significantly higher than that of Group 2 and Group 6(p<0.05). 3. Shear bond strength was higher in Group 3 than that of Group 7 (p<0.05)in silanized fillers composite resins. 4. Fracture surface was formed in resin matrixes on the specimens from composites containing the fillers treated with 0.5% 1.0%, and 1.5% silane. These results mean that the optimal silane concentrations are exist for each fillet with its size and surface area, and that 1.0% is a optimal value for concentration to coat the 25$\mu\textrm{m}$ filler with silane.

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INFLUENCES OF CAMPHOROQUINONE ON THE PROPERTIES OF COMPOSITES (Camphoroquinone이 복합레진의 특성에 미치는 영향)

  • 탁흥수;박상진
    • Restorative Dentistry and Endodontics
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    • v.26 no.1
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    • pp.41-50
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    • 2001
  • The purpose of this study was to examine the influences of camphoroquinone on the properties of five experimental composites. The contents of camphoroquinone were varied as 0.2%, 0.3%, 0.4%, 0.5%, and 0.6%, with silanized filler 75% and tertiary amine 0.2%. Five kinds of experimental composites were prepared, and diametral tensile strength, shear bond strength, depth of cure and yellowish discoloration were tested as a measurement. Specimen numbers of 10 were applied to all test items and experimental groups. Specimens for testing the diametral tensile strengths with internal diameter of 6mm in diameter and 3mm in height were filled with 5 experimental composites which were crushed with 1mm/min cross-head speed on Instron universal testing machine (Model No. 4467). Shear bond strength was measured on specimens attached to bovine teeth enamel etched with 37% phosphoric acid. Depth of cure was measured by the measurement of height of specimens which were removed the un-polymerized portion with acetone. Yellowness measurements were made by chromometer(Minolta Co. Japan) using L$^*$a$^*$b$^*$ values. ANOVA and Multiple range tests were used analyzed data with confidence level at 95%. The mean value of the shear bond strengths ranged from 31.03MPa to 39.49MPa. Following results were obtained ; 1. Diametral tensile strength was highest in experimental group 3, then was not affected by the contents of camphoroquinone ($r^2$=0.0422). 2. Composite resins containing 0.4% camphoroquinone showed the highest shear bond strength, but there was no statistical significance (p=0.3718). 3. Camphoroquinone reduces the depth of cure in the composite resins (p=0.0004, $r^2$=0.9483). 4. Camphoroquinone made the composites yellowish ($r^2$=0.9815). These results mean that increased content of camphoroquinone reduces the depth of cure, and that camphoroquinone make composites yellowish.

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AN EXPERIMENTAL STUDY ON THE BONDING FORCE OF GLASS IONOMER CEMENT (Glass Ionomer Cement의 접착력(接着力)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Lee, Myung-Jong
    • Restorative Dentistry and Endodontics
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    • v.7 no.1
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    • pp.77-83
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    • 1981
  • The purpose of this study was to observe the bonding strength between tooth surface (enamel and dentin) and restorative filling materials which are two composite resins (Clearfil and Concise) and Glass ionomer cement, after etching with 50% phoshoric acid and 37% citric acid. To measure the bonding strength in enamel, the labial surface of upper anterior tooth was cut flatly with using carborundum disk and polished with sand paper disk, and to measure in dentin, the dentin surface was prepared by grinding upper part of posterior tooth horizontally. After washing the tooth surface with water and drying with air blast, the prepared tooth surface was etched. In glass ionomer cement, 50% phosphoric acid and 37% citric acid were used, in Clearfil 40% phosphoric acid was used and in Concise, 50% phosphoric acid and 37% citric acid were used as etchant for 1 minute. After the copper band which is 5 mm in diameter and 5 mm in height was fixed on the prepared surface and each filling material was inserted into the copper band, the hooking loop was inserted into filled material in the copper band before setting to make it easily that the load is applied on the specimen. After all specimens were immersed in water at $37^{\circ}C$ for 1 week, this specimen was placed on the load cell of tensile test apparatus, and specimen was pulled at the cross-head speed of 0.8 mm per minute. The following results were obtained 1) In glass ionomer cement, the bond strength obtained by 37% citric acid was higher than one obtained by 50% phosphoric acid in enamel and dentin surfaces. The bond strength obtained in non-etched surface was much less than one by etchants in enamel and dentin surface. 2) In Clearfil, the bond strength obtained by 40% phosphoric acid was 4 times more than one obtained by non etch ant. 3) In Concise, the bond strength obtained by 50% phosphoric acid was almost same as one obtained by 37% citric acid, and the bond strength obtained by non etch ant was much less than one obtained by etchants.

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THE EFFECT OF HYBRID LAYER THICKNESS ON MICROTENSILE BOND STRENGTH OF THREE-STEP AND SELF-ETCHING DENTIN ADHESIVE SYSTEMS (혼성층의 두께가 three-step과 self-etching 상아질 접착제의 미세인장결합강도에 미치는 효과)

  • Lee, Hye-Jung;Park, Jeong-Kil;Hur, Bock
    • Restorative Dentistry and Endodontics
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    • v.28 no.6
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    • pp.491-497
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    • 2003
  • The purpose of this study was to evaluate the correlation between hybrid layer thickness and bond strength using confocal laser scanning microscope and microtensile bond strength test of two adhesive systems. The dentin surface of human molars. sectioned to remove the enamel from the occlusal surface. Either Scotchbond Multi-Purpose(3M Dental Product, St. Paul, MN, U.S.A) or Clearfil SE Bond (Kuraray, Osaka, Japan) was bonded to the surface. and covered with resin-composite. The resin-bonded teeth were serially sliced perpendicular to the adhesive interface to measure the hybrid layer thickness by confocal laser scanning microscope. The specimen were trimmed to give a bonded cross-sectional surface area of $1\textrm{mm}^2$, then the micro-tensile bone test was performed at a cross head speed of 1.0 mm/min. All fractured surfaces were also observed by stereomicroscope. There was no significant differences in bond strengths the materials(p>0.05). However. the hybrid layers of three-step dentin adhesive system, SM, had significantly thicker than self-etching adhesive system. CS(p<0.05). Pearson's correlation coefficient showed no correlation between hybrid layer thickness and bond strengths(p>0.05). Bond strengths of dentin adhesive systems were not dependent on the thickness of hybrid layer.

A STUDY ON THE SHEAR BOND STRENGTH OF THE PORCELAIN LAMINATE ACCORDING TO SURFACE ROUGHNESS OF THE CUT ENAMEL (삭제된 법랑질의 표면거칠기에 따른 도재 라미네이트의 전단결합강도에 관한 연구)

  • Park, Bong-Seok;Cho, Young-Gon
    • Restorative Dentistry and Endodontics
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    • v.19 no.1
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    • pp.159-168
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    • 1994
  • The purpose of this study was to evaluate the shear bond strength of the porcelain laminate specimens according to the surface roughness of the cut enamel of human anterior teeth. Flat enamel surfaces were prepared in 30 extracted human anterior teeth with diamond disc which were divided into two groups. Group 1 Coarse enamel surface group prepared with LVS-3 bur. Group 2 Fine enamel surface group prepared with superfine diamond bur. 30 teeth specimens of two group were stored in normal saline during 24 hours. 30 disk - type porcelain laminate specimens with diameter 4mm and thickness 1mm were made and sand - blasted on internal surface which were to cemented on enamel surface. Porcelain laminate specimens were cemented on enamel surface with Choice Veneer System (Bisco Dental, U.S.A) according to manufacture's instructions. All teeth specimens of two groups were manipulated with same method and stored In normal saline before testing. An Universal Testing machine (Model No.UTM-4206,Instron, U.S.A) was used to apply shear loads in the vertical directed, and the force required for separation was recorded with a cross head speed of 3mm/min and 500kg in full scale. The results were as follow ; 1. The mean shear bond strength of coarse surface group was 36.30kg and that of fine surface group was 44.39 kg, but there was no significant difference in breaking strength of two groups(p>0.05).

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A STUDY ON THE TENSILE BOND STRENGTH OF COMPOSITE RESIN INLAYS ACCORDING TO THEIR INTERNAL SURFACE TREATMENT AND TYPES OF LUTING CEMENT (복합레진 인레이의 내면처리와 합착용 시멘트의 종류에 따른 인장접합강도에 관한 연구)

  • Kim, Jin-Cheol;Cho, Young-Gon;Hwang, Ho-Keel
    • Restorative Dentistry and Endodontics
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    • v.18 no.1
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    • pp.103-113
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    • 1993
  • The purpose of this study was to evaluate the tensile bond strength of composite resin inlays according to the their internal surface treatment and types of luting cement and compared them with the conventional direct resin filling thchnique. Class II cavities were prepared in 50 extracted human molar teeth, and then equally divided into five groups. Group 1 : Cavities of control group were directly filled with P-50. Group 2 : Cavities of resin inlay group were luted with resin cement. Group 3 : Cavities of resin inlay group were luted with luting G-I cement. Group 4 : Cavities of resin inlay group were luted with resin cement after sandblasting. Group 5 : Cavities of resin inlay group were luted with luting G-I cement after sandblasting. All specimens were polished with same method and stored in normal saline for 24 hours before testing. An Universal Testing machine(Model No. AGS-100A, Shimadzu, Japan) was used to apply tensile loads in the vertical direction, and the force required for separation was recorded with a cross-head speed of 5mm/min and 100kg in full scale. The results were as follows : 1. The mean tensile bond strength was lowest in group luted with luting G-I cement, with measurements of $14.45{\pm}0.78(kg/cm^2)$ and highest in group luted with resin cement after sandblasting, with measurements of $49.6{\pm}2.74(kg/cm^2)$. 2. The tensile bond strength was greater in resin inlay groups luted with resin cement than in control group and resin inlay groups luted with luting G-I cement(P<0.05). 3. The tensile bond strength was lower in resin inlay groups luted with luting G-I cement than in control group(P<0.05). 4. The tensile bond strength was greater in resin inlay groups luted with resin cement or luting G-I cement after sandblasting than without that(P<0.05).

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Performance Analysis of Threshold-based Bernoulli Priority Jump Traffic Control Scheme (동적우선권제어함수 기반 TBPJ 트래픽 제어방식의 성능분석)

  • Kim, Do-Kyu
    • The Transactions of the Korea Information Processing Society
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    • v.7 no.11S
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    • pp.3684-3693
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    • 2000
  • In this paper, performance of a nonblocking high speed packet switch with switching capacity m which adopts a dynamic priority control function (DPCF) of a threshold- based Bernoulli priority jump (TBPJ) scheme is considered. Each input queue has two separate buffers with different sizes for two classes of traffics, delay-sensitive and loss-sensitive traffics, and adopts a TBPJ scheme that is a general state-dependent Bernoulli scheduling scheme. Under the TBP] scheme, a head packet of the delay-sensitive traffic buffer goes into the loss -sensitive traffic buffer with Hernoulli probability p according to systems states that represent the buffer thresholds and the number of packets waiting for scheduling. Performance analysis shows that TBPJ scheme obtains large performance build-up for the delay-sensitive traffic without performance degradation for the loss-sensitive traffic. In addition to, TBP] scheme shows better performance than that of HOL scheme.

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The Kinematic Analysis and the Study of Muscle Activities during Backhand Drive in Squash (스쿼시 백핸드 드라이브 동작 시 운동학적 분석과 근활성도에 관한 연구)

  • Cho, Kyu-Kwon;Kim, You-Sin
    • Korean Journal of Applied Biomechanics
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    • v.17 no.3
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    • pp.11-21
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    • 2007
  • The purpose of this study was to examine the differences of kinematics and muscle activities depending on the changes of angle approaching balls during backhand drive in squash. The results are as follows. Stride time took the longest at AD2 and step lengths were the biggest at AD1 of left foot contact and right foot contact and AD2 of impact and follow-through. The center of gravity and the speed of racket head were the highest at AD3 and at AD2. Angle of shoulder joint were the biggest at AD1 of left foot contact, right foot contact and impact and AD3 of follow-through. Angle of elbow joint were the biggest at AD3 of left foot contact, right foot contact and follow-through and AD2 of impact. Angle of pelvis joint were the biggest at AD2 of left foot contact, AD1 of right foot contact and AD3 of impact and follow-through. Angle of knee joint were the biggest at AD2 of left foot contact, AD1 of right foot contact and AD3 of impact and follow-through. Angle of ankle joint were the biggest at AD1 of left foot contact and AD3 of right foot contact, impact and follow-through. According to the analysis results of triceps brachii, latissimus dorsi, brachioradialis muscle and flexor carpi ulnaris muscle activities were high at AD1 of all phases. Analysis results of vastus lateralis, vastus medialis, tibialis anterior and gastrocnemius medial muscle activities were high at AD2 of phase1 and phase3. Those of vastus lateralis, vastus medialis and tibialis anterior, gastrocnemius medial were high at AD3 of Phase 2 and AD1 of phase2.

A Study on Microstructures and Cryogenic Mechanical Properties of Electron Beam Welds between Cast and Forged Inconel 718 Superalloys for Liquid Rocket Combustion Head (액체로켓 연소기용 Inconel 718 주조 및 단조 합금의 전자빔 용접부 미세조직 및 극저온 특성)

  • Hong, Hyun-Uk;Bae, Sang-Hyun;Kwon, Soon-Il;Lee, Je-Hyun;Do, Jeong-Hyeon;Choi, Baig-Gyu;Kim, In-Soo;Jo, Chang-Yong
    • Journal of Welding and Joining
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    • v.31 no.6
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    • pp.50-57
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    • 2013
  • Characterization of microstructures and cryogenic mechanical properties of electro beam (EB) welds between cast and forged Inconel 718 superalloys has been investigated. Optimal EBW condition was found in the beam current range of 36~39 mA with the constant travel speed of 12 mm/s and arc voltage of 120 kV for 10 mm-thick specimens. Electron beam current lower than 25 mA caused to occur the liquation microfissuring in cast-side heat affected zone (HAZ) of EB welds. The HAZ liquation microfissure was found on the liquated grain boundaries with resolidified ${\gamma}/Laves$ and ${\gamma}/NbC$ eutectic constituents. EBW produced welds showing a fine dendritic structure with relatively discrete Laves phase due to fast cooling rate. After post weld aging treatment, blocky Laves phase and formation of ${\gamma}^{\prime}+{\gamma}^{{\prime}{\prime}}$ strengtheners were observed. Presence of primary strengthener and coarse Laves particles in PWHT weld may cause to reduce micro-plastic zone ahead of a crack, leading to a significant decrease in Charpy impact toughness at $-196^{\circ}C$. Fracture initiation and propagation induced by Charpy impact testing were discussed in terms of the dislocation structures ahead of crack arisen from the fractured Laves phase.

The maneuvering characteristics of the research vessel NARA equipped with the azimuth thruster system (Azimuth thruster 시스템을 장착한 나라호의 조종성)

  • KIM, Jung-Chang;KANG, Il-Kwon;LEE, Jun-Ho;HAM, Sang-Jun;PARK, Chi-Wan;KIM, Su-Hyeng
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.53 no.3
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    • pp.276-285
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    • 2017
  • The research vessel NARA equipped with an azimuth thruster system was built in 2015. There are few vessels with this propulsion system in Korea. This vessel has two modes such as the normal for maneuvering and the power for investigation, and the other two modes as one axis and two axes on the operating. This type of vessels does not seem to have a clear grasp of the maneuvering character in comparison with the vessel with a conventional propulsion system. So the authors carried out the sea test for the turning, the zigzag and the inclination, and the results are as follows. In turning test, the case of using the two axes mode is much better than the case of using the one axis mode for the elements of turning, such as advance, transfer, tactical diameter and final diameter, but turning hard over the rudder in full speed is very vulnerable to capsize in both modes. In zigzag test, the yaw quicking responsibility index, T is very large excessively, which means a bad counter maneuvering ability, so an operator has to keep in mind that in turning operation. If necessary to avoid collision at head on situation, it may be a more effective method to use the crash astern stop than the turning according to the conditions and circumstances for the shortest stopping distance is very short.