• Title/Summary/Keyword: Hazardous air pollutants

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Emission Characteristics and Hazard Assessment of Polycyclic Aromatic Hydrocarbon (PAHs) from Solid Fuel Facilities (고형연료제품 사용시설에 따른 다환방향족탄화수소 (PAHs)의 배출특성 및 유해성 평가)

  • Heo, Sun-Hwa;Lim, Seung-Young;Kang, Dae-Il;Kim, Dae-Gon;Jeon, Ki-Joon;Jang, Kee-Won
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.4
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    • pp.333-341
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    • 2017
  • Recently, the earth has shown the limit of environmental capacity. It is also experiencing an environmental crisis with rising energy prices and depletion of coal. Therefore, development of renewable energy is very important solution. However, waste fuel solid are renewable fuels, but they cause environmental problems. In this study, the emission characteristics of hazardous air pollutants were analyzed through measurements at the facilities using solid fuels (SRF, BIO-SRF). Analysis method of PAHs are based on the Korea Standard Methods for Examination. The analysis of PAHs showed that the concentration much higher in Naphthalene, and Benzo(a)pyrene showed at a higher concentration incertain sources. As a result of gas phase and particle phase PAHs, most of Benzo(a)pyrene appeared to be particulate. Through the results of this study will provide basic data for atmospheric environmental management.

Nano Particle Precipitation and Residual Ozone Decomposition of a Hybrid Air Cleaning System Comprising Dielectric Barrier Discharge Plasma and MnO2 Catalyst or Activated Carbon (활성탄 또는 촉매가 장착된 배리어 유전체 방전 하이브리드. 공기청정 시스템의 나노입자 및 잔류 오존 제거 특성)

  • Byeon, Jeong-Hoon;Hwang, Jung-Ho;Ji, Jun-Ho;Kang, Suk-Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.4
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    • pp.524-533
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    • 2003
  • DBD(Dielectric Barrier Discharge) plasma in air is well established for the production of large quantities of ozone and is more recently being applied to aftertreatment processes for HAPs(Hazardous Air Pollutants). Aim of this work is to determine design and operating parameters of a hybrid air cleaning system. DBD and ESP(Electrostatic Precipitator) are used as nano particle charger and collector, respectively. Pelletized MnO$_2$ catalyst or activated carbon is used fer ozone decomposition or adsorption material. AC voltage of 7~10 KV(rms) and 60 Hz is used as DBD plasma source. DC - 8 KV is applied to the ESP for particle collection. The overall particle collection efficiency for the hybrid system is over 85 % under 0.64 m/s face velocity. Ozone decomposition efficiency with pelletized MnO$_2$ catalyst or activated carbon packed bed is over 90 % when the face velocity is under 0.4 m/s in dry air.

A statistical prediction for concentrations of Manganese in the ambient air (통계적 모형을 이용한 대기중 망간 농도 예측)

  • Kwon, Hye Ji;Kim, Yongku
    • Journal of the Korean Data and Information Science Society
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    • v.27 no.3
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    • pp.577-586
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    • 2016
  • Hazardous air pollution caused by heavy metals in the air is at a serious level. Although manganese(Mn), one of the heavy metals, is a non-carcinogenic substance, it has a harmful influence on the human body. It is partially measured because automatic monitoring technologies have not yet be fully established. We introduced a statistical model for the daily concentration of manganese. Incorporating a linkage between Mn and meteorology, the proposed model is formulated in way to identify meteorological effects and to allow for seasonal trends, enabling not only accurate measurement of manganese concentration, but also information about the evaluation on a Hazard Quotient (non-cancer risk).

The Characteristic of Volatile Organic Compounds(VOCs) Emission from the Type of Indoor Building Materials as the Temperature and Humidity (온.습도에 따른 건축 내장재별 휘발성유기화합물의 방출특성)

  • Seo, Byeong-Ryang;Kim, Shin-Do;Park, Seong-Kyu
    • Journal of Environmental Health Sciences
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    • v.32 no.4 s.91
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    • pp.292-303
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    • 2006
  • The Volatile Organic Compounds(VOCs) are emitted from various sources and have lots of different form. Recently human are spending the many times at indoor area and indoor air pollution is issued the important social problem. The emission sources of indoor air pollutants are very various, also indoor building materials are composed of very complex chemical compounds, these indoor building materials discharge very much VOCs and other hazardous compounds. In this study, we performed the small chamber test to investigate the VOCs emission concentration and characteristics involving five kinds of the indoor building materials(furniture material, wooden floor, wall paper, paint and tile) under different conditions of four temperature and relative humidity as account of the air flow rate(AFR), air exchange rate(AER), loading factor and air velocity respectively. As the result, It was showed that building materials are emitted the highest VOCs concentration at the beginning of experiment and furniture material is emitted the highest VOCs concentration. Most of the materials were affected by temperature, but paint and tile material were affected by humidity.

A Study on the Spatiotemporal Characteristics of a Hazard-based Index using the Pollutant Release and Transfer Register Data (화학물질 배출·이동량 자료를 이용한 유해기반 지수의 시공간 특성 연구)

  • Kim, Shijin;Lim, Yu-ra;Bae, Hyun-Joo
    • Journal of Environmental Health Sciences
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    • v.47 no.2
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    • pp.144-154
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    • 2021
  • Objectives: This study was intended to identify hazard contribution by region, media, and chemical by calculating a hazard-based index using pollutant release and transfer register (PRTR) data. Methods: PRTR data for the period 2011 to 2016 was analyzed to examine the regional trends in toxic releases in terms of quantity and to create a corresponding hazard-based index. For the hazard-based index, the Risk-Screening Environmental Indicators (RSEI) Model was used. Results: The results of the trend analysis show that total releases decreased slightly, but health hazard levels increased consistently. According to the outcome of regional contribution analysis of the hazard-based index, Chungcheongnam-do, Jeollabuk-do and Gyeonggi-do Provinces showed a high ratio in the index for air and water release pollutants, while Gyeongsangbuk-do and Gyeongsangnam-do Provinces showed a high ratio in the index of soil release and waste transfer pollutants. Also, as a result of the analysis of the top ranked substances in the hazard-based index, it was found that chromium, cobalt and its compounds, and ethylene oxide contributed greatly to air release substances, while chromium, benzene, and lead and its compounds contributed greatly to water release substances. Conclusion: These results showed considerable disparities between total release and health hazard levels, especially in the analysis of contribution by regions and by chemical substance. Therefore, the hazard-based index should be used both to support a more comprehensive and robust approach to screening of chemicals for environmental health policy and for management.

Air Pollutant Emission Factors from Composite Wood Products Manufacturing in Korea

  • Lee, Eun-Jung;Jung, Dong-Il;Kim, Dai-Gon;Lee, Sue-Been;Kang, Kyoung-Hee;Hong, Ji-Hyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.E2
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    • pp.57-65
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    • 2007
  • In Korea, there is a general lack of information available on air emissions from industry. The reasons for this include the lack of regulatory requirements for emission monitoring, limited information on specific industries, and difficulties in monitoring certain sources. This paper presents the first detailed air pollutant emission factors from composite wood product manufacturing in Korea. This study introduced emission factors for wood-based panels such as plywood, particle board (PB), and medium density fiberboard (MDF). The emission factors of particulate matters (PM) and hazardous air pollutants (HAPs) from MDF were higher than that from other wood products. The concentration of total volatile organic compounds (TVOCs) for hot press from wood-based panels was higher than drying or gluing processes. Emissions data from NPIP were compared to the data from the suggested emission factors in this study and the US EPA's. The data from our emission factors were closer to the observed results than the data using the US EPA's emission factor.

Characteristics of Hazardous Air Pollutant Level in Road Tunnels in Seoul (서울시 터널의 유해대기오염물질 농도변화 특성 분석)

  • Park, Jin-A;Lee, Won-Young;Kim, Jin-A;Kim, Ik-Su;Kim, Hyun-Su;Jeong, Jong-Heup;Yun, Jung-Seop;Jung, Kweon;Eom, Seog-Won
    • Journal of Environmental Health Sciences
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    • v.39 no.6
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    • pp.541-549
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    • 2013
  • Objectives: We analyzed the characteristics of hazardous air pollutants (HAPs) in road tunnels in Seoul. Methods: Particle matter ($PM_{10}$), elemental carbon (EC), organic carbon (OC), and 16 species of polycyclic aromatic hydrocarbons (PAHs) in two road tunnels (NS tunnel and HJ tunnel) were sampled and analyzed from 2007 to 2011. Results: Levels of $PM_{10}$ and carbon ingredients which were mainly emitted from diesel-fueled vehicles showed a declining tendency in both road tunnels. PAHs levels in HJ were declining slightly while PAHs levels in the NS tunnel fluctuated considerably and showed an increasing tendency. Conclusions: These results suggested that the abatement project of diesel vehicle emissions by the Seoul metropolitan government from 2007 has had an impact on the reduction of DVE into the air, though there exist many things to consider for analyses.

Characteristics of Heavy Metal Emissions from Stationary Sources (고정오염원에서의 중금속 배출특성 연구)

  • Park, Jung-Min;Lee, Sang-Bo;Cha, Jun-Seok;Kwon, Oh-Sang;Lee, Sang-Hak
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.5
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    • pp.574-583
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    • 2008
  • The results of HAPs emission data using TRI (Toxic Release Inventory), SODAM (Source Data Management system) were investigated and the emissions of 7 heavy metals from their sources and emission processes were also analyzed. Questionnaire for source data analysis as well as the stack sampling were carried out for 17 factories among 6 selected industrial types. The annual amount of emissions was estimated based on the measured concentration and flow rates. All sources were operated with high efficiency control devices and the concentration levels of all heavy metals were shown to be below 0.1 to of regulation standard. The highest emission source of heavy metals was steel manufacturing industry with the annual emission of 342.9 kg/yr and followed by hazardous waste incinerator, paint manufacturing, nonferrous metal manufacturing, rolling & press goods manufacturing and storage battery manufacturing. In the case of Hg, the emissions were quite significant from electric acros of steel manufacturing industry, although the concentration level was below the emission standard, showing the necessity of specific care for its management.

Effect of Electrode Process Variables in case of Decomposition of $NO_{x}$ by SPCP (연면방전에 의한 질소산화물의 분해시 전극 공정변수에 대한 영향)

  • 안형환;강현춘
    • Journal of the Korea Safety Management & Science
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    • v.1 no.1
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    • pp.241-258
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    • 1999
  • For hazardous air pollutants(HAP) such as NO and $NO_{2}$ decomposition efficiency, power consumption, and applied voltage were investigated by SPCP(surface induced discharge plasma chemical processing) reactor to obtain optimum process variables and maximum decomposition efficiencies. Decomposition efficiency of HAP with various electric frequencies(5~50 kHz), flow rates(100~1,000 mL/min), initial concentrations(100~1,000 ppm), electrode materials(W, Cu, Al), electrode thickness(1, 2, 3 mm) and number of electrode windings(7, 9, 11) were measured. Experimental results showed that for the frequency of 10 kHz, the highest decomposition efficiency of 94.3 % for NO and 84.7 % for $NO_{2}$ were observed at the power consumptions of 19.8 and 20W respectively and that decomposition efficiency decreased with increasing frequency above 20 kHz. Decomposition efficiency was increased with increasing residence times and with decreasing initial concentration of pollutants. Decomposition efficiency was increased with increasing thickness of discharge electrode and the highest decomposition efficiency was obtained for the electrode diameter of 3 mm in this experiment. As the electrode material, decomposition efficiency was in order : tungsten(W), copper(Cu), aluminum(Al).

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An Estimation of Age-, Power-, and Type-Specific Emission Inventories for Construction Equipments Using Improved Methodologies and Emission Factors (배출계수 개발 및 배출량 산정 체계 고도화를 통한 건설기계의 연식, 출력 및 기종별 대기오염물질 배출량 산정)

  • Jin, Hyungah;Lee, Taewoo;Park, Hana;Son, Jihwan;Kim, Sangkyun;Hong, Jihyung;Jeon, Sangzin;Kim, Jeongsoo;Choi, Kwangho
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.6
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    • pp.555-568
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    • 2014
  • The construction equipment is one of the major sources for hazardous air pollutants in Korea, and the its management has been of great concern recently. The objective of this study was to estimate each contribution of emission of construction equipments according to their production year, electric power consumption and type. To achieve this goal, we developed pollutant emission factors for the machineries manufactured after 2009, which are excluded from the present framework of Korean air pollutants inventory, CAPSS. More than 800 data obtained from emission investigations were utilized for the estimation. Compared with the previous estimation, the scheme used this study was modified to incorporate new emission factors as well as to include the corresponding activity data. Such improvement allow us to gain more detailed emission informations which are better characterized by specifications of construction equipments. The total amount of pollutants emitted from construction equipments in 2011 were estimated as 126.8, 7.0, 58.3, and 17.0 kton for $NO_x$, PM, CO, and VOC, respectively. The estimation results indicate that the increase in the emission of equipments is significantly related to their age and power consumption. The emissions of the older ones manufactured from 1992~1996 were estimated to be the contribution ranged from 23.7% to 26.8%, whereas the newer ones (2009~2011) showed the attributions of 11.3~21.5%. In addition, the results show that the emission of each equipment was increased with the increase in the electric power consumption of engine, probably due to their average output power. Among the nine types of machinery compared, excavators and forklifts were investigated to contribute relatively higher emissions in the level of 39.8~44.0% and 32.0~34.2%, respectively.