• 제목/요약/키워드: Half cell potential

검색결과 163건 처리시간 0.025초

반전지-전위 측정방법을 활용한 슬래그 콘크리트의 철근 부식 저항성능 평가 (Evaluation of Steel Corrosion of Slag Concrete by Half-cell Potential Method)

  • 이보경;김규용;김래환;윤민호;이영욱;최경철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2014년도 추계 학술논문 발표대회
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    • pp.3-4
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    • 2014
  • There is high probability of steel corrosion on the reinforced concrete exposed to marine environment by penetration of chloride ion. When making concrete structure with slag as admixture in marine environment, salt damage can be prevented. Therefore, this paper presents experimental results of steel corrosion resistance of slag concrete considering marine environment through half-cell potential method which is one of the nondestructive test. As a result of half-cell potential experiment, it was assumed that every specimen exposed to marine environment was not corroded, and as a result of destroying specimens, it was confirmed that there was no corrosion in specimens.

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해양환경하에 방치한 콘크리트중의 철근의 부식 추정에 대한 연구 (A Study on the Estimation of Steel Corrosion in Concrete Exposed under the Environment of Seawater)

  • 문한영;김성수;류재석
    • 콘크리트학회지
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    • 제6권2호
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    • pp.129-137
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    • 1994
  • 해양환경하에 있는 콘크리트 구조물의 열화를 알아보고 철근의 부식 정도를 추정하기 위한 연구내용으로서 콘크리트 중에 철근을 묻은 공시체를 제작하여 간만의 차가 있는 해변에 1년 동안 노출시킨 상태로 시험을 실시 하여 콘크리트 중의 가용성 염분량, 철근의 자연전위값 및 철근의 부식정도에 대하여 고찰하였다. 본 연구 결과 콘크리트 중의 가용성 염분량은 물-시멘트비가 낮을수록, 혼화재를 혼입할 경우 적게 나타났으며 가용성 염분량이 클수록 철근의 부식이 크게 나타났다. 철근 부식의 정도가 심할수록 자연전위값이 감소하였으며 자연전위와 부식면적율과는 상관관계가 있음을 알 수 있었다.

IBEM analyses on half-cell potential measurement for NDE of rebar corrosion

  • Kyung, Je-Woon;Tae, Sung-Ho;Lee, Han-Seung;Alver, Yalcin;Yoo, Jo-Hyeong
    • Computers and Concrete
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    • 제4권4호
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    • pp.285-298
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    • 2007
  • Corrosion of Reinforcement (rebar) is nondestructively estimated by the half-cell potential measurement. As is the case with other nondestructive testings (NDT), understanding of the underlying principles should be clarified in order to obtain meaningful results. Therefore, the measurement of potentials in concrete is analytically investigated. The effect of internal defects on the potentials measured is clarified numerically by the boundary element method (BEM). Thus, a simplified inversion by BEM is applied to convert the potentials on concrete surface to those on rebars, taking into account the concrete resistivity. Because the potentials measured on concrete surface are so sensitive to moisture content, concrete resistivity and surface condition, an inverse procedure to convert the potentials on concrete surface into those on rebars is developed on the basis of BEM. It is found that ASTM criterion is practically applicable to estimate corrosion from the potential values converted. In experiments, an applicability of the procedure is examined by accelerated corrosion tests of reinforced concrete (RC) slabs. For practical use, the procedure is developed where results of IBEM are visualized by VRML (Virtual Reality modeling Language) in three-dimensional space.

실내의 저광도하에서 토양수분이 단풍나무의 생육에 미치는 영향 (Effects of Soil Moisture on the Growth of Acer Palmatum under Indoor Low Light Intensity)

  • 윤지영;김민수
    • 한국조경학회지
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    • 제28권4호
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    • pp.21-28
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    • 2000
  • This study is conducted to analyze effects of soil moisture on the growth of maple(Acer palmatum) under indoor low light intensity. Maples grew under three different light intensities such as sunny place(average 353.2W/$m^2$), half shade(average 7.7 W/$m^2$) and shade/(average 1.9W/$m^2$).Under half shady and shady condition, each 24 planters(2 maples planted in each planter) were used and divided into 3 groups treated with different watering points. Three levels of soil water potential were set for watering points, such as -200mbar, -300mbar or -500mbar. Under sunny condition, there were only group of 8 planters, as comparison. Watering was applied when soil water potentials reached -500maber. The results of plant growth experiment are as followed. 1. Under the shady condition, 32 maples died among 48 maples for 7 months. 9 maples survived, watered at soil water potential -200mbar, 5maples at -300mbar and 2maples at -500mbar. 2. Leaf water content ratios were higher under lower light intensity. For the cell wall became thinner under lower light intensity. 3. Maples in shady were easy to die due to having thin cell wall, therefore they were easy to loss the turgor pressure. 4. In case of half shady condition, the group, watered at soil water potential -200mbar, had much smaller amount of rootlet than -300mbar, because there were excessive soil water. The group, watered at soil water potential -500mbar, had smaller amount of rootlet than -300mbar and there was a remarkable difference in leaf water potential in spite of nearly same soil water potential, because leaves received the water stress under lower soil water potential. 5. When maples grew soundly, the leaf water potential was largely influenced by the soil water potential.

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충전용량점증분석법(GISOC)에 의한 리튬이차전지 Half Cell 및 Full Cell의 초기 충방전 특성 분석 (Analyses on the Initial Charge-Discharge Characteristics of Half and Full Cells for the Lithium Secondary Battery using by the Gradual Increasing of State of Charge(GISOC))

  • 도칠훈;진봉수;문성인;윤문수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제53권2호
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    • pp.53-61
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    • 2004
  • Characteristics of half cells of graphite/lithium and LiCoO$_2$/lithium, and full cells of graphite/LiCoO$_2$/ were analyzed by the use of GISOC(the gradual increasing of the state of charge). GISOC analyses generated IIE(the initial intercalation efficiency), which represents lithium intercalation property of the electrode material, and IIC$_{s}$(the initial irreversible capacity by the surface), which represents irreversible reaction between the electrode surface and electrolyte. Linear-fit range of graphite and LiCo/O$_2$electrodes were respectively 370 and 150 mAh/g based on material weight. IIE of graphite and LiCo/O$_2$electrodes were respectively 93∼94 % and 94∼95 %, and IICs of graphite and LiCo/O$_2$electrodes were 15∼17 mAH/g and 0.3∼1.7 mAh/g, respectively. IIE of graphite/LiCo/O$_2$full cell for GX25 and DJG311 as graphite showed 89∼90 %, which IIE value was lower than IIE of half cell of the cathode and the anode. Parameters of IIE and IIC$_{s}$ can also be used to represent not only half cell but also full cell. The characteristics of the full cell can be simulated through the correlative interpretation of potential profile, IIE, and IIC$_{s}$ of half cells.cells.

장기 염해에 노출된 RC 부재의 배합 특성을 고려한 반 전위의 정량화 (Quantification of Half Cell Potential with Mix Properties in RC Member under Long-Term Chloride Exposure Conditions)

  • 윤용식;정기찬;권성준
    • 한국건설순환자원학회논문집
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    • 제10권3호
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    • pp.307-313
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    • 2022
  • 본 연구에서는 3가지 수준의 물-시멘트 비, 상부 염수 농도, 피복 두께를 고려하여 반 전위와 영향인자들 간의 상관성을 분석하였다. 장기 부식 모니터링 결과 염수 농도 3.5, 7 %에서 초기에 모든 물-시멘트 비에서 임계부식전위(-350mV)에 근접하는 거동을 보였다. 통과 전하량 시험 결과 548일에서 모든 배합에서 'Moderate' 등급으로 개선된 통과 전하량이 평가되었다. 부식 영향인자와 반 전위 값 간의 상관성을 평가 하고자 다중 회귀분석을 수행하였는데, 염수 농도, 물-시멘트 비, 피복 두께 순으로 영향을 준 것으로 평가되었다. 반 전위와 통과 전하량간의 상관성 분석 결과는 0.9로 높은 수준의 결정계수를 보였으며, 통과 전하량과 반 전위 값 간에는 밀접한 상관성이 존재하는 것으로 판단된다.

Alteration of 4-Aminopyridine-Sensitive, Voltage-Dependent $K^+-Channel$ in Arterial Smooth Muscle Cells of One-Kidney, One-Clip Goldblatt Hypertensive Rats

  • Kim, Hoe-Suk;Kim, Se-Hoon;Jeon, Byeong-Hwa;Chang, Seok-Jong
    • The Korean Journal of Physiology and Pharmacology
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    • 제4권5호
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    • pp.385-391
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    • 2000
  • Using the patch-clamp technique, we investigated the alteration of 4-aminopyridine(4-AP)-sensitive, voltage-dependent $K^+$ channel (Kv) in the mesenteric arterial smooth muscle cell (MASMC) of renovascular hypertensive model, one-kidney one-clip Goldblatt hypertensive rat (GBH). To isolate $K_V$ current, internal pipette solution contained 5 mM ATP and 10 mM EGTA. Under these condition, MASMC was depolarized by 4-AP, but charybdotoxin did not affect membrane potential. Membrane potential of hypertensive cell $(-40.3{\pm}3.2\;mV)$ was reduced when compared to that of normotensive cell $(-59.5{\pm}2.8\;mV).$ Outward $K^+$ current of hypertensive cell was significantly reduced when compared to normotensive cell. At 60 mV, the outward currents were $19.10{\pm}1.91$ and $14.06{\pm}1.05$ pA/pF in normotensive cell and hypertensive cell respectively. 4-AP-sensitive $K^+$ current was also smaller in hypertensive cell $(4.28{\pm}0.38\;pA/pF)$ than in normotensive cell $(7.65{\pm}0.52\;pA/pF).$ The values of half activation voltage $(V_{1/2})$ and slope factor (k1) as well as the values of half inactivation voltage $(V_{1/2})$ and slope factor (k1) were virtually similar between GBH and NTR. These results suggest that the decrease of 4-AP-sensitive $K^+$ current contributes to a depolarization of membrane potential, which leads to development of vascular tone in GBH.

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해양환경 폭로에 의한 슬래그 콘크리트의 내구성 평가 (Evaluation of Durability of Slag Concrete by Marine Environment Exposure)

  • 김현진;김규용;최경철;김홍섭;이보경;김래환
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2015년도 추계 학술논문 발표대회
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    • pp.111-112
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    • 2015
  • There is high possibility of steel corrosion on the reinforced concrete exposed to marine environment by chloride ion penetration. And it show a big difference of concrete durability under conditions of splash zone, tidal zone, and immersion zone. Therefore, in this paper, half-cell potential and chloride ion penetration depth was measured to evaluate the durability of slag concrete by marine exposure experiment. As a result, SC70 specimen showed no steel corrosion, regardless of the marine exposed conditions. Also, a deterrent effect on chloride ion penetration by replacement of slag in tidal zone and immersion zone could be confirmed.

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부식촉진시험에 의한 콘크리트 내의 철근의 부식 모니터링에 관한 실험적 연구 (An Experimental Study on the Corrosion Monitoring of Reinforcing Steel in Concrete by the Accelerated Corrosion Test)

  • 배수호;정영수;김진영
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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    • pp.543-548
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    • 2001
  • The corrosion monitoring methods of reinforcing steel in concrete are the various methods such as half cell potential method, galvanic current method, resistivity method, polarization resistance method, AC impedance method and etc. In this study, the corrosion monitoring methods of reinforcing steel in concrete were investigated for the test specimens using corrosion inhibitors, zinc-mortar, zinc-plate, respectively. For this purpose, the accelerated corrosion tests for reinforcing steel were conducted according to the periodic cycles(140 days) of wetting($65^{\circ}C$, 90% R.H.) and drying period(15$^{\circ}C$ , 65% R.H.) for the test specimens. As a result, it can be concluded from the test that half cell potential and galvanic current method as monitoring techniques for corrosion were found to be relatively reliable and easily usable method in the field.

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고로슬래그 미분말을 사용한 콘크리트 내의 철근부식에 관한 실험적 연구 (An Experimental Study on the Reinforcement Corrosion in Concrete Using Granulated Blast Furnace Slag)

  • 이동혁;김은겸;김영웅;김영철
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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    • pp.761-766
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    • 2002
  • This paper was peformed to verify the effect that granulated blast furnace slag gets in reinforcement corrosion resistance about chloride ion that invade from outside. An experiment accelerated for the reinforcement corrosion through repeat of brine digestion and dry. Reinforcement corrosion investigated half cell potential method of measurement by ASTM C876 and corrosion area ratio. If granulated blast furnace slag metathesis ratio is high generally that looked the corrosion of reinforcement decreasing as a result that evaluate reinforcement corrosion by ASTM C876 canon in this research. It showed high resistance about reinforcement corrosion that use normal portland cement and increase the metathesis rate of granulated blast furnace slag, as a result that evaluate metathesis rate effect of granulated blast furnace slag according to cement kind. when the test piece split destroying, area rate of reinforcement corrosion showed about result of half cell potential measurement.

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