• Title/Summary/Keyword: HPPF

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A Study of Design Parameter for the Field Application of High Performance Permanent Form (HPPF) Using Stainless Steel Fiber (스테인레스 강섬유를 이용한 고성능 영구거푸집적용 벽체구조물의 설계변수 연구)

  • Sim, Jong Sung;Oh, Hong Seob;Ju, Min Kwan;Ha, Woo Jin
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.2
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    • pp.59-66
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    • 2008
  • In the construction site, to improve the man-dependent form work, non-stripping form has been studied but the developed non-stripping form was hard to applied with respect to the cost, form size and performance. This study is for evaluating the adaptability of the developed non-stripping form named as high performance permanent form (HPPF). To do this, the analytical approach and parametric study were performed based on the research for fundamental material characteristic of the HPPF. The target concrete structure is a wall structure because of its effectiveness of HPPF. To evaluate the structural efficiency of the HPPF applied wall structure, FEM analysis was performed to decide the maximum placing height at one time then it was applied to design the wall structure. In the result of the analysis, the HPPF applied wall structure showed the lots of advantages that it can reduce the cost resulted from reducing concrete and steel rebar even if it has same structural performance to the conventional concrete wall structure with same dimension. With this analysis result, it can be evaluated that the HPPF applied concrete structure can be a concrete structure with the long term durability in site.

Direct Electrochemistry and Electrocatalysis of Myoglobin with CoMoO4 Nanorods Modified Carbon Ionic Liquid Electrode

  • Zhao, Zengying;Cao, Lili;Hu, Anhui;Zhang, Weili;Ju, Xiaomei;Zhang, Yuanyuan;Sun, Wei
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.475-481
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    • 2013
  • By using ionic liquid 1-hexylpyridinium hexafluorophosphate ($HPPF_6$) based carbon ionic liquid electrode (CILE) as the substrate electrode, a $CoMoO_4$ nanorods and myoglobin (Mb) composite was casted on the surface of CILE with chitosan (CTS) as the film forming material to obtain the modified electrode (CTS/$CoMoO_4$-Mb/CILE). Spectroscopic results indicated that Mb retained its native structures without any conformational changes after mixed with $CoMoO_4$ nanorods and CTS. Electrochemical behaviors of Mb on the electrode were carefully investigated by cyclic voltammetry with a pair of well-defined redox peaks from the heme Fe(III)/Fe(II) redox center of Mb appeared, which indicated that direct electron transfer between Mb and CILE was realized. Electrochemical parameters such as the electron transfer number (n), charge transfer coefficient (${\alpha}$) and electron transfer rate constant ($k_s$) were estimated by cyclic voltammetry with the results as 1.09, 0.53 and 1.16 $s^{-1}$, respectively. The Mb modified electrode showed good electrocatalytic ability toward the reduction of trichloroacetic acid in the concentration range from 0.1 to 32.0 mmol $L^{-1}$ with the detection limit as 0.036 mmol $L^{-1}$ ($3{\sigma}$), and the reduction of $H_2O_2$ in the concentration range from 0.12 to 397.0 ${\mu}mol\;L^{-1}$ with the detection limit as 0.0426 ${\mu}mol\;L^{-1}$ ($3{\sigma}$).