• 제목/요약/키워드: HFE

검색결과 57건 처리시간 0.025초

A Comparison of the Leaving Group Ability of Transition Metal Carbonyl Anions vs. Halides : Reaction of $MH^-$ with M'-R $(MH^-\;=\;HW(CO)_4\;-P(OMe)_3\;^-,\;HW(CO)_5\;^-,\;HCr(CO)_5\;^-,\;HFe(CO)_4\;^-;\;M'-R=CpMo(CO)_3(CH_3),\;CpMo(CO)_3{CH_2CH(CH_2)_2})$

  • Yong Kwang Park;Seon Joong Kim;Carlton Ash
    • Bulletin of the Korean Chemical Society
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    • 제11권2호
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    • pp.109-114
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    • 1990
  • The anionic transition metal hydrides $(HW(CO)_4P(OMe)_3\;^-,\;HW(CO)_5\;^-,\;HCr(CO)_5\;^-,\;HFe(CO)_4\;^-)$ react with transition metal alkyl $(CpMo(CO)_3(CH_3)$ to yield $CH_4\;and\;CH_3CHO$ in addition to the inorganic products $(CpMo(Co)_3\;^-$, etc.). The reaction of these anionic metal hydrides with CpMo(CO)3{CH2CH(CH2)2} may lead to an elucidation of the reaction mechanisms involved; the organic product distributions are among $CH_4,\;CH_2\;=\;CHCH_2CH_3$, and $CH_3CH(CH_2)_2$, depending upon the anionic metal hydride used. These anionic metal hydrides also are reported to undergo a hydride-halide exchange reaction with organic halides; therefore, these similar reactions have been compared in terms of leaving group ability $(CpMo(CO)_3\;^-\;vs.\;Br^-)$ and the mechanistic pathways.

Direct fault-tree modeling of human failure event dependency in probabilistic safety assessment

  • Ji Suk Kim;Sang Hoon Han;Man Cheol Kim
    • Nuclear Engineering and Technology
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    • 제55권1호
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    • pp.119-130
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    • 2023
  • Among the various elements of probabilistic safety assessment (PSA), human failure events (HFEs) and their dependencies are major contributors to the quantification of risk of a nuclear power plant. Currently, the dependency among HFEs is reflected using a post-processing method in PSA, wherein several drawbacks, such as limited propagation of minimal cutsets through the fault tree and improper truncation of minimal cutsets exist. In this paper, we propose a method to model the HFE dependency directly in a fault tree using the if-then-else logic. The proposed method proved to be equivalent to the conventional post-processing method while addressing the drawbacks of the latter. We also developed a software tool to facilitate the implementation of the proposed method considering the need for modeling the dependency between multiple HFEs. We applied the proposed method to a specific case to demonstrate the drawbacks of the conventional post-processing method and the advantages of the proposed method. When applied appropriately under specific conditions, the direct fault-tree modeling of HFE dependency enhances the accuracy of the risk quantification and facilitates the analysis of minimal cutsets.

천연가스의 임계유동함수 불확도 평가 (Estimation of Uncertainty in Critical Flow Function for Natural Gas)

  • 하영철
    • 대한기계학회논문집B
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    • 제38권7호
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    • pp.625-638
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    • 2014
  • 본 연구에서는 천연가스 유량 측정에 사용되는 임계유동함수(CFF)를 AGA8-dc 상태방정식으로 계산할 때 CFF 계산값의 불확도를 평가하였다. CFF 계산에 사용되는 엔탈피, 엔트로피, 음속 식은 불확도 분석이 가능하도록 무차원 헬름홀츠 자유에너지(Helmholtz free energy, HFE)와 이의 편도함수로 표현하였고, HFE의 불확도를 추정하였다. 압축인자의 불확도에 의해 유발되는 종속 변수의 불확도를 반영하기 위해 AGA8-dc 압축인자 식을 해당 불확도만큼 편차가 생기는 형태로 변형하였고, 각 불확도 요인별로 불확도 기여도 평가 모델을 만들었으며, 이를 CFF 계산 프로그램에 적용하였다. 그 결과 CFF의 불확도는 압력 10, 50, 100 bar 에서 각각 0.025, 0.055, 0.112 % 정도로 평가 되었고 압력에 비례하여 증가하는 것을 확인하였다. 또한 본 결과를 기존 CFF 국제비교시험결과(1999년)에 적용한 결과 각 기관별 CFF 값의 차이를 적절히 설명하는 것도 알 수 있었다.

영국의 배아관리체계와 공공정책의 선택 (Human Embryo Management System and Public Policy Options in the United Kingdom)

  • 황만성;한동운
    • 보건행정학회지
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    • 제14권3호
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    • pp.97-121
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    • 2004
  • Recently, human embryonic stem cell research raises exciting public expectation on medical possibilities as well as ethical debate. Embryo management has become an integral part of the management of infertility treatment, researches on embryo and human embryonic stem cells and so on. Britain has permitted the research on stem cells derived from human embryo which made the first nation to allow the cloning of human embryo for the stem cell research. However, new technologies such as the assisted reproductive technologies and human embryonic stem cell research continue to pose an increasing source of ethical dilemmas for physician, scientists, legislators, religious authorities and the general publics to deal with. None the less, the United Kingdom has adopted the most liberal policies regarding human embryo and human embryonic stem cell research. The implication of the British embryo management system are as follows: 1) the development of reproductive technologies and new stem cell research technologies continue to pose legal and ethical debates, since those involve several parties; 2) the UK has taken the legal and institutional approaches to cope with those serious issues; 3) the UK adopted most liberal policies regarding embryonic and human embryonic stem cell researches; 4) the British HFE Act is consistent with the existing Acts related to human embryo management and researches; 5) through amending the HFE Act to accomodate the changes of technologies, the UK try to minimize the legal and ethical burden on undertaking research regarding embryo. The debates about the researches on human embryo and human embryonic stem cells is likely to continue in the Korean society. Because of the controversy and competing ethical values, as well as the evolving technologies, so far no consensus exists in our society. It suggest that it is premature to bring closure by ruling out any particular approaches. Thus our society needs to make an efforts to find a basis which could resolve the societal controversies through enriching the societal conversation about the profound ethical issues regarding embryo management.

재한 중국유학생들을 대상으로 한 스트레스와 사회적 지지기반 및 건강식생활실천도 관련성 연구 (The Relationship between Stress, Social Support and Healthy Diet Score among Chinese University Students in Korea)

  • 이성희;풍진;이영미
    • 대한지역사회영양학회지
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    • 제20권4호
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    • pp.273-280
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    • 2015
  • Objectives: The study aimed to examine whether healthy diet score was associated with stress and social support among 472 Chinese college students in Korea. Methods: The study participants were 472 (187 male, 285 female) Chinese college students in Gyeong-gi area. From April 2013 to Oct 2013, participants were asked to fill out questionnaires on healthy diet score (20 questions), stress (20 questions), and social support (20 questions). Each question was scored by a 5-point Likert scale (total scores of each questionnaire were ranged from 20 to 100). Questions on healthy diet were sub-categorized as 'Healthy food eating (HFE)', 'Healthy eating habits (HEH)', and 'Avoidance of unhealthy food (AUF)'. Reliability test was conducted with Cronbach's ${\alpha}lpha$ (${\alpha}=0.79$). Results: Healthy diet score was higher in participants who stayed longer in Korea, who spoke Korean language fluently, and who assessed his or her own health status as very good. Adjusted means of healthy diet scores were estimated after adjusting for age, gender, body mass index, duration of staying, and Korean language fluency. According to tertile categories, participants with low tertile stress but high tertile social support showed the highest score of healthy diet ($72.59{\pm}1.45$), whereas participants with high tertile of stress but low tertile of social support had the lowest score of healthy diet ($59.22{\pm}1.54$). As for the three sub-categories of healthy diet score, the score of HFE increased as the score of social support increased. Conclusions: Our findings suggested that social support system is beneficial to alleviate stress and to improve healthy diet score.

PEG/γ-Al2O3 상이동 촉매상에서 니트로벤젠과 Fe(CO)5로부터의 아닐린 합성 (Synthesis of Aniline from Nitrobenzene and Fe(CO)5 with PEG/γ-Al2O3 as Phase Transfer Catalyst)

  • 오소영;이화수;박대원;박상욱;신정호
    • 공업화학
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    • 제4권1호
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    • pp.144-152
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    • 1993
  • ${\gamma}-Al_2O_3$, ${\alpha}-Al_2O_3$, $SiO_2$, $TiO_2$등에 고정화된 폴리에틸렌글리콜을 $Fe(CO)_5$에 의한 니트로벤젠의 상온 환원반응에 상이동 촉매로 사용하였다. 고정화된 PEG의 몰수는 담체의 비표면적에 따라 증가하였고 PEG/${\gamma}-Al_2O_3$가 가장 좋은 활성을 나타내었다. PEG의 사슬길이가 길고 NaOH 농도가 높을수록 반응속도가 증가하였다. 적외선분광기를 이용하여 반응기구에 대한 고찰도 함께 실시하였으며 폴리에틸렌글리콜 상이동 촉매는 본 반응의 활성물질로 알려진 $HFe(CO)_4{^{-}}$이온의 생성과 이의 유기상으로의 이동을 촉진시키는 것으로 판단되었다.

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맥아와 한약재추출물이 고지방 식이를 섭취시킨 흰쥐의 혈장지질 및 혈당농도에 미치는 영향 (Effect of Water Extract from Hordeum vulgare L. with Medicinal Herb on Plasma Lipid Status and Glucose in Rats Fed High Fat Diet)

  • 박현숙;양경미;정지욱
    • 대한본초학회지
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    • 제24권1호
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    • pp.15-21
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    • 2009
  • Objectives : This study was designed to investigate the effect of water extract from Paeonia Lactiflora Pasll. with medicinal herb on plasma lipid and glucose in rats fed high fat diet. Methods : Experimental groups were divided into control diet group(C), high fat diet group(HF), high fat diet and 5% water extracts from Paeonia Lactiflora Pasll. with medicinal herb group(HFE I), high fat diet and 10% water extract from Paeonia Lactiflora Pasll. with medicinal herb group(HFE II). Weight gain, food intake, food efficiency, plasma lipid concentration and glucose were determined for 10 weeks during high fat diet. Results : In this experiment, body weight and food efficiency were significantly increase in high fat diet. High fat diet group showed elevated levels of total cholesterol, LDL-cholesterol and free fatty acid. Consumption of 10% water extract Paeonia Lactiflora Pasll. with medicinal herb lowers level of total cholesterol, LDL-cholesterol and free fatty acid. But levels of plasma triglyceride, HDL-cholesterol and glucose did not affect by high fat diet and water extract Paeonia Lactiflora Pasll. with medicinal herb Conclusions : In these results, water extract Paeonia Lactiflora Pasll. with medicinal herb in high fat diet group decreased plasma total cholesterol, LDL-cholesterol and free fatty acid. Thus the Paeonia Lactiflora Pasll. with medicinal herb might be useful in the treatment of hyperlipemia.

ICHTHYS CPF(Central Processing Facility) LQ Piping Design 특이사항(유의사항) (Notice of LQ Piping Design for ICHTHYS)

  • 이재영;성현택
    • 대한조선학회 특별논문집
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    • 대한조선학회 2017년도 특별논문집
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    • pp.46-53
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    • 2017
  • We work for big offshore project in the Korean shipyards as a EPC contract. There are a lot of risks even though the FEED Engineering was taken in the famous engineering company. In case of ICHTHYS CPF, it worked on the FEED activity for several years. Here is mention that design modification was carried how to modify material and specification according to shipyards human resource and yard practice for your reference. Furthermore, I expect that this paper is used for Korean engineer for their reference.

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