• Tunnel and Underground Space
• /
• v.30 no.3
• /
• pp.242-255
• /
• 2020

The numerical simulations of Heater Experiment-D (HE-D) at the Mont Terri rock laboratory in Switzerland were performed to investigate an applicability of FLAC3D to reproduce the coupled thermo-hydro-mechanical (THM) behaviour in Opalinus Clay, as part of the DECOVLEX-2015 project Task B. To investigate the reliability of numerical simulations of the coupled behaviour using FLAC3D code, the simulation results were compared with the observations from the in-situ experiment, such as temperature at 16 sensors, pore pressure at 6 sensors, and strain at 22 measurement points. An anisotropic heat conduction model, fluid flow model, and transversely isotropic elastic model in FLAC3D successfully represented the coupled thermo-hydraulic behaviour in terms of evolution for temperature and pore pressure, however, performance of the models for mechanical behavior is not satisfactory compared with the measured strain.

• Journal of the Korean Society for Heat Treatment
• /
• v.36 no.6
• /
• pp.382-388
• /
• 2023

In this study, hydrogen embrittlement (HE) behavior of a SA-723 steel via controlling gaseous hydrogen pre-charging condition has been analyzed. The gaseous hydrogen charging of the SA-723 steel was performed under a constant pressure of 20 MPa of gaseous H₂ at 150℃ and 300℃ for 2 and 6h, and TDS, SSRT and Charpy tests were conducted to analyze the hydrogen embrittlement (HE) behavior of the SA-723 steel. Furthermore, prior to commencing the test, these specimens were coated with Zn to prevent hydrogen from diffusing out of a specimen during the tests. The TDS results showed that the 300℃-6h and 150℃-6h charged steels contain larger amounts of hydrogen than 300℃-2h and 150℃-2h charged steel. The SSRT and Charpy test results also showed the similar trends that the mechanical properties of the steels deteriorate as the amount of hydrogen charged in the steel increases. Therefore, this study suggests that, for SA-723 steel, the charging time parameter is more effective to charge more amount of hydrogen into SA-723 steel, rather than the charging temperature.

• Journal of the Korean Electrochemical Society
• /
• v.10 no.2
• /
• pp.126-131
• /
• 2007

The durability problem of Prussian blue in non-aqueous $Li_+$-based electrolytes has been due to the degradation of the Prussian blue electrode matrix during the insertion/extraction processes by $Li_+$. In this work, we designed and synthesised the Prussian blue without reducing the electrochromic performance in non-aqueous $Li_+$-based electrolytes. Prussian blue was electrodeposited on a glass which has ITO coating, and the coating solution is a mixture solution of $FeCl_3\;and\;K_3Fe(CN)_6$ with deionized water added HCl, KCl, and LiCl, respectively. The durability of Prussian blue was evaluated by an in-situ transmittance measurement during a continuous and pulse potential cycling test, and measured by electroactive layer thickness due to evaluating the degradation.