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포항지역 지열수의 수리지구화학적 특성

  • 고동찬;염병우;하규철;송윤호
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.453-454
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    • 2004
  • Hydrogeochemical and isotopic characteristics were investigated for groundwater of Tertiary basin in southeastern part of Korea where deep drilling is in progress for geothermal investigation. According to geology, aquifer was distinguished as alluvial, tertiary sedimentary bedrock (bedrock groundwater), and fractured volcanic rock (deep groundwater). Groundwater of each aquifer is distinctively separated in Eh-pH conditions and concentrations of Cl, F, B and HCO$_3$. Deep groundwater has very low level 3H and 14C whereas alluvial groundwater has those of recent precipitation level. However one of deep groundwater show mixed characteristics in terms of hydrochemistry which indicates effect of pumping. Deep groundwater have temperature of 38 to 43$^{\circ}C$ whereas bedrock and alluvial groundwater have temperature less than 2$0^{\circ}C$. Fractured basement rock aquifer has different hydrogeologicalsetting from bedrock and alluvial aquifer considering hydrogeochemical and isotopic characteristics, and temperature.

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Origin and Hydrochemical Characteristics of Natural Carbonated Water at Seoqwipo, Jeju Island (제주도 서귀포지역 천연탄산수의 기원과 수리화학특성)

  • Jeong, Chan Ho;Lee, Yong Cheon;Lee, Yu Jin;Choi, Hyeon Young;Koh, Gi Won;Moon, Duk Chul;Jung, Cha Youn;Jo, Si Beom
    • The Journal of Engineering Geology
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    • v.26 no.4
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    • pp.515-529
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    • 2016
  • In this study, geochemical composition, CFCs (Chlorofluorocarbons), ${\delta}^{18}O$, ${\delta}D$, ${\delta}^{13}C$ isotopes and noble gases isotopes (He, Ne) were analyzed to determine their recharge age, source of $CO_2$ gas and noble gases of carbonated hot spring water and carbonated-water samples collected in the Seoqwipo of the Jeju. The pH of the carbonated waters ranges from 6.21 to 6.84, and the high electrical conductivity range ($1,928{\sim}4,720{\mu}S/cm$). Their chemical composition is classified as $Mg(Ca,\;Na)-HCO_3$ and $Na(Ca,\;Mg)-HCO_3$ types. As a result of the calculation of groundwater age using CFCs concentrations as an environmental tracer, the carbonated water and groundwater were estimated to be about 47.5~57.2 years and about 30.3~49.5 years, respectively. The ${\delta}^{13}C$ values of carbonated water range from -1.77 to -7.27‰, and are plotted on thr deep-seated field or the mixing field of the deep-seated and inorganic origin. Noble gases isotopic ($^3He/^4He$, $^4He/^{20}Ne$) ratio shows that helium gas of carbonated hot waters comes from deep-seated magma origin.

Extraction Process Optimization of Poncirus trifoliata and Prunus mume for Antibacterial Activity against Vibrio parahaemolyticus (장염비브리오 항균활성을 위한 탱자와 매실의 추출조건 최적화)

  • Lee, Young-Guen;Choi, Young-Whan;Joo, Woo-Hong
    • Journal of Life Science
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    • v.16 no.4
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    • pp.640-646
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    • 2006
  • The present investigation was carried out particularly to optimize the extraction process of Poncirus trifoliata and Prunus mume to develop a functional foodstuff having antibacterial activity against Vibrio parahaemolyticus. The extracts were prepared from the fruits under various conditions, and then optimum extraction conditions were decided in case maximal antibacterial activity was obtained. In extraction process by using hot water, the best antibacterial activity of Poncirus trifoliata was achieved at $80{\sim}100^{\circ}C$ for 30 min, while that of Prunus mume was achieved at $100^{\circ}C$ for 30 min, as showing 14.8 and 16.6 mm of inhibition diameter, respectively. The extraction process with addition of NaOH increased the activity of Prunus mume, but addition of $K_2CO_3$ and $NaHCO_3$ drastically decreased the activity. In the processes at high temperature up to $120^{\circ}C$ by using pressure extractor and with various concentrations of NaOH, the maximum activity was observed in the extract of Prunus mume at $120^{\circ}C$ for 30 min with 0.05 N NaOH. The fermented ethanol extract of the fruits showed less activity than those of the extracts with water and NaOH solution.

Damage Characteristics of Korean Traditional Textiles by Formaldehyde (포름알데히드에 의한 전통직물의 손상 특성)

  • Kim, Myoung Nam;Lim, Bo A;Lee, Sun Myung
    • Journal of Conservation Science
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    • v.30 no.4
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    • pp.353-364
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    • 2014
  • Formaldehyde(HCHO) may have a damage effect on Korean traditional textiles, because concentration is high and occurrence frequency is frequent at the exhibition room and storage area. Total 20 specimens were prepared using 4 different materials (silk, cotton, ramie, hemp) after dyeing with 5 colors (undyed, red, yellow, blue, black). The specimens were exposed to HCHO gas in the test chamber. The gas acceleration test was conducted to identify the deterioration of Korean traditional textiles according to HCHO concentration(0.5, 1, 10, 100, 500ppm), to temperature-humidity condition at HCHO 500ppm, and deterioration conditions at HCHO 500ppm. Optical, chemical, and physical evaluation was carried out after the exposure. The results, color difference, grey scale rating, formate($HCO_2{^-}$) of some textiles increased at 500ppm, while pH decreased at 500ppm. Also, color difference, grey scale rating, formate($HCO_2{^-}$) of some textiles increased double damage at high temperatures & humidity, high humidity condition. But, damages of accelerated degradation textiles were slight, because of degradation degree and degradation products. The results suggest that determined the damage to the korean traditional textile, damage level, damage-weighted condition, damage to accelerated degradation textiles. In addition, formaldehyde damaged to yellowing of red textiles, bleaching of accelerated degradation textiles, formic acid damaged to bleaching of total 20 specimens.

Purification and Structural Analysis of Antitumor Polysaccharides Obtained from Ganoderma lucidum IY 009 (Ganoderma lucidum IY 009로 부터 분리된 항암성 다당류의 정제 및 구조분석)

  • Lee, Kweon-Haeng;Jeong, Hoon;Lee, June-Woo;Han, Man-Deuk;Choi, Kyoung-Sook;Oh, Doo-Hwan
    • Microbiology and Biotechnology Letters
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    • v.22 no.2
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    • pp.190-196
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    • 1994
  • Alkali soluble(AS) fraction, revealed the highest antitumor activity of the alkali extracted fractions of G. lucidum IY 009, was loaded on DEAE cellulose(OH$^{-}$ form) column. AS-1, AS-2, AS-3, AS-4 and AS-5 were obtained by stepwise elution with H$_{2}$O, 0.1 M NaHCO$_{3}$, 0.3 M NaHCO$_{3}$, 0.5 M NaHCO$_{3}$ and 0.5 N NaOH respectively, and their antitumor activities(I.R. %) against the sarcoma 180 were 97.5%, 68.0%, 73.0%, 81.0% and 66.0% respectively. AS-1 observed highest antitumor activity was appeared as single peak on the Sepharose CL-4B column chromatography, and their molecular weight was about 580,000 dalton. The carbohydrate content of AS-1 was 98.9%, their monosaccharide consisted of 67.5% of mannose, 22.5% of xylose, 5.8% of glucose, 1.8% of galactose and 2.0% of ribose. AS-1 was assumed $\alpha $linkaged xylomannan having infrared absorption at 864.3 cm$^{-1}$. The main alditol acetates of AS-1 were identified as 1,5-Di-O-acetyl1-2,3,4-Tri-O-methylxylitol, 1,4,5-Tro-O-acety1-2,3,6-Tri-O-methylmannitol and 1,3,4,5-Tetra-O-acety1-2,6-Di-O-methylmannitol by methylation analysis, and their molar ratio was 1 : 2 : 1. The core portion of AS-1 might be $\alpha $-(1$\longrightarrow $ 4)mannopyranosyl unit branched with side chain, C1 of xylopyranosyl residue linked to C3 of every 3 mannopyranosyl units, and the degree of polymerization of structural unit in AS-1 was about 835.

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Water Chemistry and Age Dating of Thermal Spring in Chullabukdo Region (전라북도 온천수의 수질 화학적 특성과 연대 측정)

  • Kim, Jong Hun;Choi, Yong Wook
    • Journal of the Korean Chemical Society
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    • v.40 no.2
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    • pp.101-108
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    • 1996
  • The chemical characteristics and age dating of the thermal springwater developed recently in Chullabukdo were investigated. The temperature range of the thermal springwater was found 27∼29$^{\circ}C$, indicating a low temperature thermal springwater. The concentration of $F^-$ ion in the springwater was found relatively high in the range of 2∼3 ppm, but $NO_3^-$ ion was nearly not detected. The concentration range of $SO_4^{2-}$ ion was 0.02∼23 ppm, among which $SO_4^{2-}$ content of $Y_3$ was found very high compared to that of other springwater, since this site is known as a sulfur spring. $HCO_3^-$ ion content was found 2∼5 times higher than that of groundwater. $Y_1,\;Y_3,\;Y_5,\;Y_2,\;Y_4,\;and\;Y_8$, were classified as $HCO_3^-$ type, $Y_6$ as $CI^-$type, and $Y_7$, as no domonant type by classification diagram for anion and cation facies. From the results of age dating on the basis of the mean tritium level of precipitation and thermal springs, $Y_1$ was identified as the oldest thermal spring (-89 years) and $Y_7$ was identified as -89 years and $Y_7$ was -1 year using dispersive model. The results calculated by two models agreed well each other.

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Occurrence, Geochemistry and Origin of $Co_2$-rich Water from the Chungcheong Area, Korea (충청지역 탄산수의 산출양상, 지화학적 특성 및 생성기원)

  • 정찬호;김종근;이재영
    • Economic and Environmental Geology
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    • v.34 no.2
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    • pp.227-241
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    • 2001
  • Several $Co_2$-rich springs in the Chungcheong area, Le., the Angsung spring, the Chojung spring, the Myungam spring, the Bukang spring and the Daepyung spring have been long known for their particular water chemistry. The occurrences of these springs are closely related to the geologic structure of Mesozoic granite such as dyke swarms, fault zones and the geologic boundary between granite and its adjacent gneiss. The $Co_2$-rich water samples show a high $Co_2$ concentration ($P_{CO2}$ 0.25 atm to 0.99 atm), weak acidic pHs and the electrical conductivity ranging from 101 to 2,950 ${\mu}$S/cm. The $Co_2$-rich water samples are classified into the Ca-$HC0_3$ type and the Ca(Na)-$HCO_3$) type in chemical composition. Environmental isotopic data $^{2}H/^{1}H, ^{18}O/^{16}O$) indicated that $Co_2$-rich water was meteoric origin. The ${\delta}^{13}C$ values of $Co_2$-rich water range from -3.1$\textperthousand$ to -6.8$\textperthousand$ PDB. The values indicate that $H_2CO_3^0$ and $HC0_3^-$ of the water samples are mainly originated from a deep-seated source and partly contributed from carbonatc minerals. The major minerals determining the chemistry of $Co_2$-rich watcr arc probably the carbonate minerals which are present as veins and secondary minerals, and the plagiocalse in granite and gneiss.

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Optimum Culture Conditions for the Growth of Spirulina platensis NIES 39 (Spirulina platensis NIES 39의 성장을 위한 최적배양조건)

  • Kim, Young Min;Kim, Mi-Ryung;Kwon, Tae Ho;Ha, Jong-Myung;Lee, Jae-Hwa
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.285-289
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    • 2009
  • Recently, as the interest in the accelerated global warming and the food shortage problem is increased, the concerns for microalgae as photosynthetic microorganisms are also increased. Specially, photosynthetic microalgae, Spriulina platensis have been an attractive source for $CO_2$ gas fixations and for a vast array of valuable nutritious compounds. In this paper, to culture the microalgal Spirulina platensis NIES 39 in a batch culture with high mass, optimal conditions for the culture temperature, initial pH, light intensity and concentration of carbon and nitrogen, were tested. At the most favorable culture condition, $35^{\circ}C$, initial pH 9.5, 4500 lux and carbon and nitrogen concentration of 16.8 g/L $NaHCO_3$ and 2.5 g/L $NaNO_3$, the excellent yields of 2.10 g/L biomass and 29.53 mg/L chlorophyll were obtained.

Chemical properties of cores in different environments; the Orion A, B and λ Orionis clouds

  • Yi, Hee-Weon;Lee, Jeong-Eun;Tie, Liu;Kim, Kee-Tae
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.80.1-80.1
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    • 2017
  • We present preliminary results of KVN single dish telescope observations of 80 dense cores in the Orion molecular cloud complex which contains the Orion A, B, and ${\lambda}$ Orionis cloud. We investigate the behavior of the different molecular tracers and look for chemical variations of cores in the three clouds in order to systematically investigate the effects of stellar feedback. The most commonly detected molecular lines (with the detection rates higher than 50%) are N2H+, HCO+, H13CO+, C2H, HCN, and H2CO. The detection rates of dense gas tracers, N2H+, HCO+, H13CO+, and C2H show the lowest values in the ${\lambda}$ Orionis cloud. We find difference between molecular D/H ratios and N2H+/H13CO+ abundance ratios towards different clouds, and between protostellar cores and starless cores. Eight starless cores in the Orion A and B clouds exhibit high deuterium fractionations, larger than 0.10, while in the ${\lambda}$ Orionis cloud, no cores reveal the high ratio. These chemical properties could support that cores in the ${\lambda}$ Orionis cloud are affected by the photo-dissociation and external heating from the nearby H II region, which is a hint of negative stellar feedback on core formation. The striking difference between the [N2H+]/[H13CO+] ratios leads us to suggest that there are significant evolutionary differences between the Orion A/B and ${\lambda}$ Orionis clouds. In order to examine whether starless cores can be candidates of pre-stellar cores, we compared the core masses estimated from the 850 um emission to their Virial masses calculated from the N2H+ line data and find that most of them are not gravitationally bound in the three clouds.

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A comparison of the Effects of Intravenous Fluid Warming and Skin Surface Warming on Peri-operative Body Temperature and Acid Base Balance of Elderly Patients with Abdominal Surgery (수액가온요법과 피부가온요법이 개복술 환자의 저체온 예방에 미치는 효과 비교)

  • Park, Hyo-Sun;Yoon, Hae-Sang
    • Journal of Korean Academy of Nursing
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    • v.37 no.7
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    • pp.1061-1072
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    • 2007
  • Purpose: The purpose of this study was to compare the effects of intravenous fluid warming and skin surface warming on peri-operative body temperature and acid base balance of abdominal surgical patients under general anesthesia. Method: Data collection was performed from January 4th, to May 31, 2004. The intravenous fluid warming(IFW) group(30 elderly patients) was warmed through an IV line by an Animec set to $37^{\circ}C$. The skin surface warming(SSW) group(30 elderly patients) was warmed by a circulating-water blanket set to $38^{\circ}C$ under the back and a 60W heating lamp 40 cm above the chest. The warming continued from induction of general anesthesia to two hours after completion of surgery. Collected data was analyzed using Repeated Measures ANOVA, and Bonferroni methods. Results: SSW was more effective than IFW in preventing hypothermia(p= .043), preventing a decrease of $HCO_3{^-}$(p= .000) and preventing base excess(p= .000) respectively. However, there was no difference in pH between the SSW and IFW(p= .401) groups. Conclusion: We conclude that skin surface warming is more effective in preventing hypothermia, and $HCO_3{^-}$ and base excess during general anesthesia, and returning to normal body temperature after surgery than intravenous fluid warming; however, skin surface warming wasn't able to sustain a normal body temperature in elderly patients undergoing abdominal surgery under general anesthesia.