• 설비공학논문집
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• 제13권8호
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• pp.710-719
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• 2001

Pool boiling heat transfer coefficients (HTCs) of HCFC123, HFC134a, HCFC22, HFC407C, HFC410A and HFC32 wre measured on a horizontal smooth tube, 26 fpi low fin tube, Turbo-B and Thermoexcel-E enhanced tubes. AN experimental apparatus was designed such that all tubes heated by cartridge heaters could be installed at the same time to save the refrigerant. Data were taken in the pool of $7^{\circ}C$ with the heat flux decreasing from 80 kW/$m^2\;to\;5kW/m^2$. Test results showed that HTCs of pure refrigerants and those of a azeotrope were greatly influenced by reduced pressure. HTCs of HFC407C were 21~25% lower than those of HCFC22 due to mass transfer resistance. For all refrigerants, enhanced tubes with sub-surface and sub-tunnels showed the largest heat transfer enhancement. Especially the largest heat enhancement was obtained for HCFC123 whose reduced pressure is the lowest among al the refrigerants tested. This indicates that either Turbo-B or Thermoexcel-E enhanced tube would be the best choice when used with a low vapor pressure refrigerant.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집B
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• pp.776-781
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• 2001

To enhance thermal efficiency of thermal facility through recovery of low and medium temperature waste heat, 1MW organic Rankine cycle system was designed and developed. The exhaust gases of $175^{\circ}C$ at two 100MW power plants in pohang steel works were selected as the representative of low and medium temperature waste heat in industrial process for the heat source of the organic Rankine cycle system. HCFC-123, a kind of harmless refrigerant, was chosen as the working fluid for Rankine cycle. The organic Rankine cycle system with selected exhaust gases and working fluid was designed and constructed. From the operation, it was confirmed that the organic Rankine cycle system is available for low and medium temperature waste heat recovery in industrial process. The optimum operating manuals, such as heat-up of hot water, turbine start-up, and the process of electric power generation, were derived. However, electric power generated was not 1MW as designed but only 670kW. It is due to deficiency of pump capacity for supply of HCFC-123. So it is necessary to increase the pump capacity or to decrease the pressure loss in pipe for more improved HCFC-123 supply.

• 월간산업보건
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• 통권357호
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• pp.23-34
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• 2018

• International Journal of Air-Conditioning and Refrigeration
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• 제9권3호
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• pp.1-9
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• 2001

In this study, condensation heat transfer coefficients (HTCs) of nonazeotropic refrigerant mixtures of HFC32/HFC 134a and HCFC123 at various compositions were measured on a horizontal smooth tube. All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3~8K. Test results showed that HTCs of tested mixtures were 11.0~85.0% lowed than the ideal values calculated by the mass fraction weighting of the HTCs of the pure components. Thermal resistance due to the diffusion vapor film was partly responsible for the significant reduction of HTCs with these nonazeotropic mixtures. The measured data were compared against thc predicted ones by Colburn and Drew's film model and a good agreement was observed within a deviation of 15%.

• 설비공학논문집
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• 제12권12호
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• pp.1049-1056
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• 2000

In this study, condensation heat transfer coefficients(HTCs) of 2 nonazeotropic refrigerant mixtures of HFC32/HFC134a and HFC134a/HCFC123 at various compositions were measured on a horizontal smooth tube. All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3~8K. Test results showed that HTCs of tested mixtures were 11.0~85.0% lower than the ideal values calculated by the mass fraction weighting of the pure components HTCs. Thermal resistance due to the diffusion vapor film was partly responsible for the significant reduction of HTCs with these nonazeotropic mixtures. The measured data were compared against the predicted ones by Colburn and Drew\`s film model and a good agreement was observed.

• 설비공학논문집
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• 제10권5호
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• pp.569-580
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• 1998

In this study, condensation heat transfer coefficients(HTCs) of a plain tube, low fin tube, and Turbo-C enhanced tube for CFC-11, HCFC-123, CFC-12, HFC-l34a are measured and compared against each other. All data are taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling temperature 3~8$^{\circ}C$. Test results show that HTCs of a low vapor pressure refrigerant, HFC-123, for a plain, low fin, and Turbo-C tubes are 10.5~20.5%, 8.2~12.2%, 16.5~19.2% lower than those of CFC-11, respectively. On the other hand, HTCs of a medium vapor refrigerant, HFC-l34a, for a plain, low fin, and Turbo-C tubes are 20.6~31.8%, 0.0~8.0%, 13.2~20.9% higher than those of CFC-12, respectively. For all refrigerants tested, HTCs of Turbo-C tube are the highest among the three tubes showing almost 8 times increase in HTCs as compared to those of a plain tube. Nusselt's prediction equation for a plain tube yielded 12% deviation for all plain tube data while Realty and Katz's prediction equation for a low fin tube yielded 20% deviation for all low tube data.

• 대한설비공학회지:설비저널
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• 제28권5호
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• pp.368-374
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• 1999

최근 세계적으로 환경보호에 대한 관심이 고조됨에 따라 기술개발 방향이 환경을 고려한 규정 및 장치에 제한을 받고 있다. 따라서 냉동 공조 기기에 사용되는 기존의 CFC계열 냉매가 오존층 파괴의 주 원임이 판명됨에 따라 환경 문제가 없는 HCFC계열인 R123와 HFC R134a로의 대체가 불가피하게 되었다.

• 설비공학논문집
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• 제12권10호
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• pp.941-949
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• 2000

Pool boiling heat transfer coefficients (HTCs) of HCFC123, CFC11, HCFC142b, HFC134a, CFC12, HFC22, HFC125 and HFC32 on a horizontal smooth tube have been measured. The experimental apparatus is specially designed to simulate the real heat transfer tube with the use of the secondary fluid of water as a heat source rather than a conventional electric heat source. Data were taken in the order of decreasing heat flux starting at $80 ㎾/m^2\; and \;ending\; at\; 5㎾/m^2\;in\; the\; poo\;l temperature\; at\; 7^{\circ}C$, Test results showed that HTCs of HFC125, and HFC32 are 50~67% higher than those of HCFC22. It is also found that some of the popular pool boiling heat transfer correlations in the literature are not good to predict the HTCs of newly developed alternative refrigerants. A new correlation was developed by a regression analysis which is based upon the consistent data obtained in this study and it showed an excellent agreement with all experimental data having an absolute mean deviation of less than 10%.

• 한국방재안전학회논문집
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• 제10권2호
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• pp.35-41
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• 2017

최근 소화약제 취급 관련 중독사고가 다발하고 있다. 산업이 발전하고 건물이 고층화됨에 따라 다양한 소화약제가 개발되고 있으며, 이에 따라 소화약제의 안전한 사용의 문제가 중요하게 대두되고 있다. 본 연구에서는 소화약제(HCFC-123, HFC-125)에 대한 화학물질 위험성평가를 안전보건공단에서 개발한 CHARM기법을 통해 실시해보았고, 의미 있는 결과를 얻을 수 있었다. 동 연구 자료가 향후 화학물질 안전관리 체계수립에 도움이 될 수 있기를 바란다.

• 대한화학회지
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• 제38권9호
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• pp.695-700
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• 1994

여러가지 불균일 촉매$(Rh/Al_2O_3,\;Pd/C,\;Ni,\;Al_2O_3,\;Active\;carbon)$를 이용하여 CFC-113a의 가수소 분해반응을 액상과 기상에서 각각 조사하였다. 액상반응에서는 각 촉매에 따라 반응성은 차이가 났지만, 95% 이상의 높은 선택성으로 $HCFC-123(CF_3CHCl_2)$을 주었다. 특히 $Al_2O-3$가 액상반응에서 상당히 높은 반응성과 선택성을 보인 것은 주목할 만하다. 기상반응의 경우, 전이금속이 포함된 촉매(Pd/C, Pt/C)를 사용하였을 때에는 과수소화물인 $HCFC-133a(CF_3CH_2Cl)$와 HFC-143a(CF_3CH_3)$가 생성되었다. 한편, 액상반응에서 활성을 보이던 $Al_2O_3$는 기상반응에서는 거의 반응성을 보이지 않았다. $Al_2O_3$의 경우 용매로 THF를 사용하였을 경우에는 비교적 부반응 없이 깨끗하게 반응이 진행되었지만, MeOH를 사용하였을 때는 용매로 부터 $CH_3OCH_3$과 $CH_3CH_2OCH_3$ 등이 생성되면서 가수소 분해반응이 진행되었다. 따라서 액상반응에서는 용매의 역할이 중요한 것으로 해석하였다.