• Title/Summary/Keyword: HCFC

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Analysis of Trifluoroacetic acid by GC/ECD (GC/ECD를 이용한 Trifluoroacetic acid의 분석)

  • 노경록;홍영민;이보경;김만구
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.247-248
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    • 2002
  • CFCs는 가정제품과 공업의 생산과정에서 발포제와 냉매제로 오랜 기간 사용되었다. 1974년, CFCs는 Molina와 Rowland에 의해서 성층권 오존의 고갈 요인으로 인식하게 되었고, 최근에는 지구 온난화의 기여물질로써 사회적 관심이 증가하였다. CFCs의 세계적인 생산은 Montreal 의정서와 그 개정안으로 인해 점차 감소하면서 사용이 폐지되었고, 대체 물질로 HCFCS와 HFCs가 사용되고 있다. 대류권에서 HCFCs와 HFCs는 hydroxyl radicals에 의해 산화되고, 최종 분해산물로 무기산, 염, HF, $CO_2$, HC와 Trifluoroacetic acid(TFA)가 생성된다. (중략)

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Condensation heat transfer coefficients of alternative refrigerants for CFC11, CFC12 and HCFC22 (CFC11, CFC12, HCFC22 대체냉매의 응축 열전달계수)

  • 정동수
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.28 no.5
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    • pp.389-395
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    • 1999
  • 냉동공조설비, 발전설비, 화학플랜트설비 등에 사용되는 응축기는 주로 증기가 관의 외부에서 응축을 하고 냉각수가 관 내부로 흐르는 쉘-튜브(shell and tube)형 태를 취하고 있다. 초기투자비용 및 운전비용을 줄이기 위해서는 응축기의 열교환 성능을 향상시키는 일이 필수적이며 이를 위해 코팅 표면(coated surfaces), 거친 표면(rough surfaces), 코일 튜브(coiled tubes), 선회 흐름장치(swirl flow), 전열면적을 넓힌 낮은 핀관과 3차원 형상을 갖는 열전달 촉진관의 사용이 제시되고 있다.

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A Study of External Condensation Heat Transfer of Flammable Refrigerants (가연성 냉매의 외부 응축 열전달에 관한 연구)

  • 배동수;하종철;유길상;정동수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.6
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    • pp.522-529
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    • 2004
  • In this study, external condensation heat transfer coefficients (HTCs) of flammable refrigerants of propylene, propane, isobutane, butane, DME, and HFC32 were measured on a horizontal plain tube, 26 fpi low fin tube, and Turbo-C tube. All data were taken at the temperature of 39$^{\circ}C$ with a wall subcooling of 3∼8$^{\circ}C$. Test results showed a typical trend that condensation HTCs of flammable refrigerants decrease with increasing wall subcooling. HFC32 had the highest HTCs among the tested refrigerants showing 44% higher HTCs than those of HCFC22 while DME showed 28% higher HTCs than those of HCFC22. HTCs of propylene and butane were similar to those of HCFC22 while those of propane and isobutane were similar to those of HFC134a. Based upon the tested data, Nusselt's equation is modified to predict the plain tube data within a deviation of 3%. For 26 fpi low fin tube, Beatty and Katz equation predicted the data within a deviation of 7.3% for all flammable refrigerants tested. The heat transfer enhancement factors for the 26 fpi low fin and Turbo-C tubes were 4.6∼5.7 and 4.7∼6.9 respectively for the refrigerants tested indicating that the performance of Turbo-C tube is the best among the tubes tested.

Development of 1MW Organic Rankine Cycle System for Industrial Waste Heat Recovery Put English Title Here (산업배열회수용 1MW급 유기랭킨 사이클 시스템 개발)

  • Cho, H.C.;Park, H.S.;Lee, Y.K.
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.776-781
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    • 2001
  • To enhance thermal efficiency of thermal facility through recovery of low and medium temperature waste heat, 1MW organic Rankine cycle system was designed and developed. The exhaust gases of $175^{\circ}C$ at two 100MW power plants in pohang steel works were selected as the representative of low and medium temperature waste heat in industrial process for the heat source of the organic Rankine cycle system. HCFC-123, a kind of harmless refrigerant, was chosen as the working fluid for Rankine cycle. The organic Rankine cycle system with selected exhaust gases and working fluid was designed and constructed. From the operation, it was confirmed that the organic Rankine cycle system is available for low and medium temperature waste heat recovery in industrial process. The optimum operating manuals, such as heat-up of hot water, turbine start-up, and the process of electric power generation, were derived. However, electric power generated was not 1MW as designed but only 670kW. It is due to deficiency of pump capacity for supply of HCFC-123. So it is necessary to increase the pump capacity or to decrease the pressure loss in pipe for more improved HCFC-123 supply.

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Pool Boiling Heat Transfer Correlation for Pure Refrigerants (순수냉매의 풀비등 열전달 상관식)

  • 고영환;김종곤;송길홍;정동수;김영일
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.10
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    • pp.941-949
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    • 2000
  • Pool boiling heat transfer coefficients (HTCs) of HCFC123, CFC11, HCFC142b, HFC134a, CFC12, HFC22, HFC125 and HFC32 on a horizontal smooth tube have been measured. The experimental apparatus is specially designed to simulate the real heat transfer tube with the use of the secondary fluid of water as a heat source rather than a conventional electric heat source. Data were taken in the order of decreasing heat flux starting at $80 ㎾/m^2\; and \;ending\; at\; 5㎾/m^2\;in\; the\; poo\;l temperature\; at\; 7^{\circ}C$, Test results showed that HTCs of HFC125, and HFC32 are 50~67% higher than those of HCFC22. It is also found that some of the popular pool boiling heat transfer correlations in the literature are not good to predict the HTCs of newly developed alternative refrigerants. A new correlation was developed by a regression analysis which is based upon the consistent data obtained in this study and it showed an excellent agreement with all experimental data having an absolute mean deviation of less than 10%.

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A Study on Development of Alternative Non-aqueous Cleaning Agents to Ozone Depletion Substances and its Field Application (오존파괴물질 대체 비수계세정제 개발 및 현장 적용 연구)

  • Park, Yong-Bae;Bae, Jae-Heum;Lee, Min-Jae;Lee, Jong-Gi;Lee, Ho-Yeoul;Bae, Soo-Jung;Lee, Dong-Kee
    • Clean Technology
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    • v.17 no.4
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    • pp.306-313
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    • 2011
  • Flux or solder is used in soldering process for manufacturing electronic parts such as printed circuit boards (PCB). After soldering process, residual flux and solder paste on the parts should be removed since their residuals could cause performance degradation or failure of parts due to their corrosion and electric leakage. Ozone depletion substances such as 1,1,1- trichloroethane (TCE) and HCFC-141b have widely been using for removal of residual flux and solder paste after soldering process In manufacturing of electronic parts until now. In this study, non-aqueous cleaning agents without flash point were developed and applied to industrial field for replacement of cleaning agents with ozone depletion. In order to develop non-aqueous cleaning agents without ethers, esters, fluoride- type solvents. And their physical properties and cleaning abilities were evaluated, and they were applied to industrial fields for cleaning of flux and solder on the PCB. And vacuum distillation apparatus were operated to determine their operating conditions and recycling yields for recycling of used cleaning agents formulated in this study. As a result of physical properties measurement of our formulated cleaning agents, they were expected to have good wetting and penetrating power since their surface tensions were relatively low as 18.0~20.4 dyne/$cm^2$ and their wetting indices are relatively large. And some cleaning agents holding fluoride-type solvents as their components did not have any flash point and they seemed to be safe in their handling and storage. The cleaning experimental results showed that some cleaning agents were better in their cleaning of flux and solder paste than 1,1,1-TCE and HCFC-141b. And industrial application results of the formulated cleaning agents for cleaning PCB indicated that they can be applicable to industry due to their good cleaning capability in comparison with HCFC-141b. The recycling experiments of the used formulated cleaning agents through a vacuum distillation apparatus also showed that their 91.9~97.5% could be recycled with its proper operating conditions.

An Experimental Study on Application of Hydrocarbon Refrigerants for Heat Pump (히트펌프에서 탄화수소냉매 적용에 관한 실험적 연구)

  • Yoo, Seong-Yeon;Park, Dong-Seong;Kang, Tae-Seok;Lee, Je-Myo
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1264-1269
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    • 2004
  • This research describes the application of hydrocarbon refrigerants for heat pump system which is needed for fish farm. Tested refrigerants are HCFC-22 and hydrocarbon refrigerants(CARE 50 and ASR-20). CARE 50 is mixture of R-290 and R-170, and ASR-20 is mixture of R-152a, R-290 and other additives. Heat pump consist of shell and tube heat exchanger, scroll compressor, expansion valve and accumulator. Manual expansion valve is used for testing of wide range evaporating temperature. Hydrocarbon refrigerants show a good performance as an alternative for HCFC-22 in the range of evaporating temperature from $-6^{\circ}C$ to $6^{\circ}C$.

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External Condensation Heat Transfer Coefficients of Refrigerant Mixtures on a Smooth Tube

  • An, Kwang-Yong;Cho, Young-Mok;Seo, Kang-Tae;Jung, Dong-Soo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.9 no.3
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    • pp.1-9
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    • 2001
  • In this study, condensation heat transfer coefficients (HTCs) of nonazeotropic refrigerant mixtures of HFC32/HFC 134a and HCFC123 at various compositions were measured on a horizontal smooth tube. All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3~8K. Test results showed that HTCs of tested mixtures were 11.0~85.0% lowed than the ideal values calculated by the mass fraction weighting of the HTCs of the pure components. Thermal resistance due to the diffusion vapor film was partly responsible for the significant reduction of HTCs with these nonazeotropic mixtures. The measured data were compared against thc predicted ones by Colburn and Drew's film model and a good agreement was observed within a deviation of 15%.

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