• Journal of the Korean Institute of Gas
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• v.18 no.5
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• pp.85-90
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• 2014

Turbo chiller is widely used for the air conditioner and uses hydrochlorofluorocarbon 123 (HCFC-123) as a refrigerant. HCFC-123 is one of the chemicals being considered as a replacement for the chlorofluorocarbons. High concentrations of HCFC-123 cause a deficiency of oxygen with the risk of unconsciousness or death, the vapour is heavier than air and may accumulate in low ceiling spaces causing deficiency of oxygen. In this study, the concentration distribution of oxygen indoor was investigated by using computational fluid dynamics(CFD) as four workers were killed in HCFC-123 gas leaks at machine room of hypermarket in 2011.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.9
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• pp.2316-2327
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• 1995

Experimental results from nucleate pool boiling heat transfer with various finned tubes in CFC11, HCF123 and HCFC141b are reported. One plain tube and four low fin tubes of various fin densities were tested in an attempt to find out the optimum fin density in the heat flux range of 10-60 kW/m$^{[-992]}$ at near atmospheric pressure. The results indicated that CFC11 showed the highest heat transfer coefficients. Its alternatives, HCFC123 and HCFC141b, showed 3-5% lower heat transfer coefficients than those of CFC11 at the same heat flux. As the fin density increases, so does the heat transfer surface area. Measured heat transfer coefficients, however, do not necessarily always increase as the fin density increases. This unique phenomenon seems to be caused by the coalescence of the bubblers that prevent the cool liquid from entering into the fin valleys. For all the refrigerants tested, the optimum fin density yielding the highest performance was 28 fins per inch confirming the previous results by other researchers.

• Solar Energy
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• v.18 no.1
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• pp.69-79
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• 1998

This paper is concerned about the performance of HCFC22 alternative refrigerants used in heat pumps and industrial chillers. A water-to-water breadboard heat pump with counter-current heat exchangers and a hermetic compressor was built to carry out the experiments with various refrigerants. For each test, more than 40 temperatures, 4 pressures, power input, mass flow rates of the heat transfer fluids were measured. Refrigerants tested were HCFC22, R290(Propane), an azeotrope of 45%Propane/55%R134a mixture, and a nonazeotropic mixture of Calor 50. All tests were conducted under ARI test A condition. It is found that the COP and capacity of propane were 18% and 2.5% higher than those of HCFC22 while the COP and capacity of 45%Propane/55%R134a mixture were 3.5% and 5.3% higher than those of HCFC22 respectively. Also the COP and capacity of Calor 50 were 17% and 7.8% higher than those of HCFC22. Compressor discharge temperatures of alternative refrigerants were roughly $35^{\circ}C$ lower than that of HCFC22 indicating that these refrigerants are good from the view point of compressor reliability. The charging amounts for the alternative refrigerants were reduced by 40-60% as compared to that of HCFC22. Overall, it can be said that hydrocarbon containing alternative refrigerants are excellent in thermodynamic performance but should be used with considerable care due to their flammability.

• Fire Science and Engineering
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• v.33 no.3
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• pp.51-55
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• 2019

To prevent ozone depletion caused by CFCs, the replacement of Halon with clean agents has been developed in the fire protection field along with refrigerants, detergents, and foaming agents. The alternatives for Halon 1211 have been developed in the portable fire extinguisher area and HCFC-123 is used widely as a clean fire extinguishing agent. The type of expellant gas is important because their own vapor pressure is low. In this study, HCFC-123, HCFC-124, HFC-125, and Novec-1230 were selected as fire extinguishing agents and CO₂, which is expected to improve the fire extinguishing ability, was chosen as the expellant gas. For each agent, experiments changing the agent and CO₂ amount were carried out and HCFC-123 showed a good result, as expected. The extinguisher, HCFC-123 of 1.5 kg, showed the same ability to suppress a class A and B fire as the extinguisher, HCFC-123 of 2.5 kg, which is currently sold on the market. According to this result, the expellant gas has a subsidiary fire extinguish effect. This can reduce the amount of HCFC fire extinguishing agent, which is categorized in the phase-out alternatives, and is a more eco-friendly and economical fire extinguisher than the previous one. This study can also help solve the problems of CO₂ fire extinguishers for class B and C fires, and can be used to extinguish electric and electron facilities fire, which contains large amounts of class A fire combustibles.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.6
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• pp.830-840
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• 1997

In this study, condensation heat transfer coefficients(HTCs) of CFC-11, HCFC-123 and HCFC-141b are measured, which are used/or considered as working fluids in centrifugal chillers. The main objectives of this study are to measure and compare the HTCs of various refrigerants on plain and low fin tubes and also to find out the optimum fin density of the low fin tubes. To accomplish these goals, HTCs of three refrigerants are measured for the plain tube as well as 4 types of low fin tubes. All measurements are carried out at the vapor temperature of 39.deg. C with the wall temperature difference of 3 .deg. C ~ 8.deg. C. For all the refrigerants tested, a low fin tube of 28 fins per inch yielded the best performance among all the tubes tested. For the plain tube, the HTCs of CFC-11 and HCFC-141b were very similar and those of HCFC-123 were 10% lower than those of CFC-11.Thus, it can be concluded that HCFC-123 and HCFC-141b are acceptable as alternative refrigerants for CFC-11 from the view point of condensation heat transfer.

• Safety and Health at Work
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• v.9 no.3
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• pp.356-359
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• 2018

This case report attempts to present a case of acute toxic hepatitis in fire extinguisher manufacturing workers exposed to 2,2-dichloro-1,1,1-trifluoro-ethane (HCFC-123) in August 2017 in Korea. Twenty-two-year-old male workers were exposed to HCFC-123 for 1.5 hours one day and for 2.5 hours the other day, after which one worker died, and the other recovered after treatment. The workers were diagnosed with acute toxicity of hepatitis. However, exposure levels of HCFC-123 were not known with no work environment measurement done. Therefore, this study was conducted to estimate the exposure concentration of HCFC-123 via a job simulation experiment. In the simulation, the HCFC-123 exposure concentration was measured with the same working practice and working time as with the workers aforementioned. As a result, the workers who infused HCFC-123 into storage tanks were estimated to be exposed to HCFC-123 at a concentration of $20.65{\pm}10.81ppm$, and a mean concentration of area samples within a working radius were estimated as $70.30{\pm}18.10ppm$. Valve assembly workers working on valves of a fire extinguisher filled with HCFC-123 were exposed to HCFC-123 at concentrations of $91.65{\pm}4.03ppm$ and $115.55{\pm}7.28ppm$, respectively, in the simulation, and area samples simulated within the working radius were also found to be high with concentrations of $122.75{\pm}91.15ppm$ and $126.80{\pm}60.25ppm$, respectively. Nitrogen gas packing workers, who did not handle HCFC-123 directly, were exposed to the agent at a concentration of $71.80{\pm}8.49ppm$. These results suggest that exposure to HCFC-123 at high concentrations for 1.5-2.5 hours caused acute toxic hepatitis in two workers.

• Journal of the Korean Institute of Gas
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• v.9 no.1 s.26
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• pp.16-20
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• 2005

CFC-11 and HCFC-l4lb have been used as blowing agents for rigid polyurethane foam insulation of LNG storage tank. But CFC-11 and HCFC- l4lb deplete ozone layer in the stratosphere. So in leading countries, the use of CFC-11 has been prohibited since 1995 and the use of HCFC-l4lb will be prohibited from 2005. Much efforts and studies have been done about alternative blowing agents and insulations blown by alternative blowing agents. This paper deals with polyurethane foams (PUFs) blown by HFC-365mfc, shows their physical and mechanical characteristics and thermal performance. These data are compared with the results of PUFs blown by HCFC-l4lb. From these test results, PUFs blown by HFC-365mfc show good mechanical and thermal characteristics. It is possible to use PUFs blown by HFC-365mfc as main insulation of membrane type LNG storage tank.

• Applied Chemistry for Engineering
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• v.9 no.3
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• pp.372-376
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• 1998

Supported Pd($Pd/AlF_3$, $Pd/{\gamma}-Al_2O_3$) catalysts and solid-acid catalysts(${\gamma}-Al_2O_3$, ${\alpha}-Al_2O_3$, $AlF_3$) were used to perform dechlorination of HCFC-142b(1-chloro-1,1-difluoroethane) in the presence of excess hydrogen. In the reactions the effects of reaction temperature, the mole ratio(r) of $H_2$ to HCFC-142b and the amount of supported Pd on dechlorination of HCFC-142b into HFC-143a(1,1,1-trifluoroethane) or HFC-152a(1,1-difluoroethane) were investigated. The experimental results showed that the conversion of HCFC-142b to product gases were 60% and 92%, respectively, and the selectivity to HFC-143a in the product gases were 58% and 64% for $Pd/AlF_3$ and $Pd/{\gamma}-Al_2O_3$ catalysts, respectively. On these catalysts an optimum reaction condition was found at $200^{\circ}C$ with the space time of reactant gases as 1.05 second and the mole ratio of $H_2$ to HCFC-142b as 3. Solid-acid catalysts were also tested at the same reaction condition. The results showed that the conversions of HCFC-142b to product gases were 12%, 8% and 7%, and the selectivities to HFC-152a were 94%, 92% and 90% for ${\gamma}-Al_2O_3$, ${\alpha}-Al_2O_3$ and $AlF_3$ catalysts, respectively.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.28 no.1
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• pp.80-90
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• 2018

Objectives: This study was performed to propose a domestic occupational exposure limit(OEL) following a health hazard assessment, calculation of a non-carcinogenicity reference concentration worker($RfC_{worker}$) value, and examination of international agencies' exposure limits. It also recommends legal management within the Occupational Safety and Health Act for HCFC-123, which caused an acute hepatotoxicity incident. Methods: An acute hepatotoxicity incident due to the fire extinguishing agent HCFC-123 was investigated. Toxicological hazard and health hazard classifications were examined and a non-carcinogenicity $RfC_{worker}$ value was calculated for HCFC-123. An OEL and the necessity of legal management were recommended as well. Results and Conclusions: An OEL for HCFC-123 of 10 ppm($62.5mg/m^3$), which considered the $RfC_{worker}$ value, 5.56 ppm, produced in dose-response assessment and the exposure level of 19.1-20.9 ppm measured as an eight-hour TWA(time-weighted average) in the incident place, is recommended. HCFC-123 is urged to be included as a chemical requiring legal management in the Occupational Safety and Health Regulations. In addition, it is recommended that a peak exposure of ACGIH be adopted in the Notice of the Ministry of Employment and Labor.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.2
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• pp.234-248
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• 1995

A super-heat pump system composed of a suction line heat exchanger, low and high stage economizers, and a screw compressor is simulated to examine the energy performance and design options. CFC12, HCFC22, HFC134a, HCFC22/HCFC142b, HFC32/HFC134a, and HFC125/HFC134a are used as working fluids for comparison. The results indicate that the proposed system charged with appropriate mixtures is up to 33.4% more energy efficient than the normal system with CFC12. The performance of the super-heat pump system charged with mixtures was influenced by such factors as the temperature matching, heat source temperature difference, low stage economizer, and high stage economizer. The fluids with a larger liquid specific heat such as HFC134a would have more benefits when a suction line heat exchanger is installed. 40%HCFC22/60%HCFC142b mixture seems to be a good candidate to replace CFC12. On the other hand, 25%HFC32/75% HFC134a would be a good long term candidate to replace HCFC22.