• Title/Summary/Keyword: HAp

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The study of Semen Persicae & Flos Carthami in Bang-Yak-Hap-Pyun (도인(桃仁) 및 홍화(紅花)를 포함하는 방약합편처방(方藥合編處方)에 대한 고찰(考察))

  • Hwang, Sang Joon;Oh, Min seok;Song, Tae won
    • Journal of Haehwa Medicine
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    • v.13 no.1
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    • pp.311-320
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    • 2004
  • In oriental medicine, Semen Persicae & Flos Carthami are frequently used materials for promoting blood circulation to remove blood stasis. Bang-Yak-Hap-Pyun(方藥合編) is widely used for clinical herbal prescription book. In Bang-Yak-Hap-Pyun(方藥合編), Semen Persicae is used 2g~6g. and Flos Carthami is used 1.2g~4g. the nuber of prescription Semen Persicae & Flos Carthami in Bang-Yak-Hap-Pyun is total 17. 2 in sang-tong(上統), 5 in jung-tong(中統), 10 in ha-tong(下統). The group of mostly used disease is about gynecology(婦人科) & five sense organs(五官科). The mostly quoted medical literature what prescription included Semen Persicae & Flos Carthami in Bang-Yak-Hap-Pyun is Dong-Yi-Bo-Gam.

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Amonia-Borane에서의 이종상 촉매인 Ru-HAP, Co-HAP를 이용한 수소 발생

  • Kim, Yeong-Yong;Gwon, Gi-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.194-194
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    • 2011
  • 지구상에서 화석 연료에 기초한 에너지가 고갈되어 가고 있는 지금, 여러 가지 대체 에너지들이 주목 받고 있는데 그 중에서도 수소는 친환경적 에너지원으로서 최근 많은 연구가 진행중이다. 여러 가지 저 분자 중에서 보레인은 수소 질량비가 큰 물질 중의 하나로서 이를 이용하면 적은 무게에 비하여 다른 유사한 질량의 분자들 보다 많은 수소를 발생할 수 있다. 그래서 우리는 이에 착안하여 촉매를 이용한 수소 발생 실험을 구상하게 되었다. Ru과 Co를 수산화인회석에 도입하여 우리는 이종상 촉매인 Ru-HAP와 Co-HAP를 만들었다. 이를 TEM을 이용하여 시료상의 이온교환 전후의 상을 관찰 하였고 SEM을 이용하여 촉매 표면 상의 붕소유리를 관찰 하였다. 높은 온도와 압력일수록 HAP에 더 많이 표면에 Ru과 Co가 흡착됨을 ICP를 통해서 알 수 있었다.

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Fabrication of Hydroxyapatite Compacts with Polymethyl Methacrylate (PMMA를 결합제로 한 수산화아파타이트 성형체의 제조)

  • Ryu, Su-Chak;Yoon, Su-Jong
    • Korean Journal of Materials Research
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    • v.16 no.4
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    • pp.272-275
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    • 2006
  • In order to evaluate the possibility of Polymethyl methacrylate (PMMA) as a binder on hydroxyapatite (HAp) which has good biocompatibility, the properties of HAp compacts with PMMA were examined. When adding 50 wt% of PMMA on HAp and pressed, the compression strength and the hardness of the compacting body were 168MPa and 55 Hv, respectively, and the strength of compacts was higher than that of cortical bone and the hardness was similar to the value of molar. We demonstrated that HAp ceramics can be obtained without additional heat treatment and machining of the ceramic was feasible. Therefore, the HAp compacts have potential to apply to implant or artificial bone after the clinical trials guarantees biocompatibility of it.

Setting and Hydroxyapatite Formation of Bioactive Glass Bone Cement (생체활성 유리 골 시멘트의 응결 및 수산화 아파타이트 형성)

  • Lim, Hyoung-Bong;Kim, Cheol-Young
    • Journal of the Korean Ceramic Society
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    • v.42 no.11 s.282
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    • pp.770-776
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    • 2005
  • Hardening and hydroxyapatite(HAp) formation behavior of the bioactive cements in the system of $CaO-SiO_{2}-P_{2}O_{5}$ glasses and the corresponding glass-ceramics were studied. DCPD (Dicalcium Phosphate Dihydrate: $CaHPO_4{\cdot}2H_2O$) and DCPA (Dicalcium Phosphate Anhydrous: $CaHPO_4$) were developed when the prepared glass and glass-ceramic powders were mixed with three different solutions. The DCPD and DCPA transformed to HAp when the cement was soaked in Simulated Body Fluid (SBF), and this HAp formation strongly depended on the releasing capacity of $Ca^{2+}$ ions from the cements. The glass-ceramic containing apatite showed fast setting, but no HAp formation was observed because no $Ca^{2+}$ ions were released from this glass-ceramics. The compressive strength of the cements increased with reaction time in SBF until all DCPD and DCPA transformed to HAp.

High-frequency Induction Heating Sintering of Hydroxyapatite-($ZrO_2+3%Mol\;Y_2O_3$) Bioceramics

  • Khalil, Khalil Abdel-razek;Kim, Sug-Won
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.924-925
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    • 2006
  • In this study, hydroxyapatite (HAp) and hydroxyapatite-yttria stabilized zirconia (HAp-3YSZ) with 20 vol.%-($ZrO_2+3%mol\;Y_2O_3$) nanopowders were consolidated very rapidly to full density by High-frequency induction heat sintering (HFIHS). Effects of temperature and the addition of 3YSZ on the toughness, hardness and microstructure properties have been studied. 3YSZ second phase toughening HAp composites with higher toughness were successfully developed at relatively low temperatures through this technique. Compared with hardness and toughness obtained for pure HAp, the hardness and toughness for HAp-20vol. % 3YSZ were much higher.

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Morphology Changes of E. coli in Ag-HAp Observed by TEM

  • Kim, T.N.;Feng, Q.L.;Kim, Y.J.;Yim, H.J.;Lim, D.Y.;Hwang, D.S.;Kim, J.W.;Cui, F.Z.
    • Journal of the Korean Vacuum Society
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    • v.7 no.s1
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    • pp.44-49
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    • 1998
  • The antimicrobial effects of HAp and Ag-HAp was observed using periprosthetic infection bacteria such as Pseudomonas Aeruginosa, Staphylococcus Epidermidis, Escherichia coli (DH5$\alpha$). Ag-HAp showed good antimicrobial effects. TEM study of E. coli with and without Ag treatment in HAp was experimented in order to find the mechanism of Ag in antimicrobial effects. It was observed that the shape of Ag-treated E. coli was changed, the cells walls became inhomogeneous. The vaculoes at cytoplasm formed into E. coli and finally it was discovered by EDAX that there were many dark granules which contain the Ag element inside the cells.

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Dental Properties of Hydroxyapatite Filled Polymer Composite (수산화인회석이 충전된 고분자 복합체의 치과적 물성)

  • Seo, Kitaek;Yoon, Jingu;Kim, Juhwan;Kim, Ohyoung
    • Applied Chemistry
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    • v.9 no.2
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    • pp.25-28
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    • 2005
  • To evaluate the dental restorative application of polymer composites filled with hydroxyapatite (HAP) which is an inorganic component of human bone material, dental properties of the polymer composites were investigated. A visible light system was utilized to activate the acrylate resin matrix of the composites. Maximum loading percentage of HAP in composite was 65 wt% and the depth of cure was 6.0 mm which can be applicable for dental restoration. With increasing the HAP content, degree of conversion of polymer composites was slightly decreased, however, polymerization shrinkage value was not varied. Diametral tensile strength value was enhanced with an increase of HAP content, however, there was no strict trend between flexural strength and HAP concentration. Anyhow, polymer composites prepared herein have superior mechanical properties sufficient specifications applicable to dental materials.

Hydroxyapatite-Zirconia Composite Thin Films Showing Improved Mechanical Properties and Bioactivity

  • Kim, Min-Seok;Ryu, Jae-Jun;Sung, Yun-Mo
    • Korean Journal of Materials Research
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    • v.19 no.2
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    • pp.85-89
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    • 2009
  • Nano-crystalline hydroxyapatite (HAp) films were formed at the Ti surface by a single-step microarc oxidation (MAO), and HAp-zirconia composite (HZC) films were obtained by subsequent chemical vapor deposition (CVD) of zirconia onto the HAp. Through the CVD process, zero- and one-dimensional zirconia nanostructures having tetragonal crystallinity (t-ZrO2) were uniformly distributed and well incorporated into the HAp crystal matrix to form nanoscale composites. In particular, (t-$ZrO_2$) was synthesized at a very low temperature. The HZC films did not show secondary phases such as tricalcium phosphate (TCP) and tetracalcium phosphate (TTCP) at relatively high temperatures. The most likely mechanism for the formation of the t-$ZrO_2$ and the pure HAp at the low processing temperature was proposed to be the diffusion of $Ca^{2+}$ ions. The HZC films showed increasing micro-Vickers hardness values with increases in the t-$ZrO_2$ content. The morphological features and phase compositions of the HZC films showed strong dependence on the time and temperature of the CVD process. Furthermore, they showed enhanced cell proliferation compared to the $TiO_2$ and HAp films most likely due to the surface structure change.

Mobile Base Station Placement with BIRCH Clustering Algorithm for HAP Network (HAP 네트워크에서 BIRCH 클러스터링 알고리즘을 이용한 이동 기지국의 배치)

  • Chae, Jun-Byung;Song, Ha-Yoon
    • Journal of KIISE:Computing Practices and Letters
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    • v.15 no.10
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    • pp.761-765
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    • 2009
  • This research aims an optimal placement of Mobile Base Station (MBS) under HAP based network configurations with the restrictions of HAP capabilities. With clustering algorithm based on BIRCH, mobile ground nodes are clustered and the centroid of the clusters will be the location of MBS. The hierarchical structure of BIRCH enables mobile node management by CF tree and the restrictions of maximum nodes per MBS and maximum radio coverage are accomplished by splitting and merging clusters. Mobility models based on Jeju island are used for simulations and such restrictions are met with proper placement of MBS.

Effect of Ti Intermediate Layer on Properties of HAp Plasma Sprayed Biocompatible Coatings

  • Take, Seisho;Otabe, Tusyoshi;Ohgake, Wataru;Atsumi, Taro
    • Corrosion Science and Technology
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    • v.19 no.2
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    • pp.51-56
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    • 2020
  • The objective of this study was to improve properties of plasma sprayed HAp layer to titanium substrate by introducing an intermediate layer with two different methods. Before applying Zn doped HAp coating on titanium substrate, an intermediate layer was introduced by titanium plasma spray or titanium anodization. Heat treatments were conducted for some samples after titanium intermediate layer was formed. Zn doped HAp top layer was applied by plasma spraying. Three-point bending test and pull-off adhesion test were performed to determine the adhesion of Zn doped HAp coatings to substrates. Long-term credibility of Zn doped HAp plasma sprayed coatings on titanium was assessed by electrochemical impedance measurements in Hanks' solution. It was found that both titanium plasma sprayed and titanium anodized intermediate layer had excellent credibility. Strong adhesion to the titanium substrate was confirmed after 12 weeks of immersion for coating samples with titanium plasma sprayed intermediate layer. Samples with titanium anodized intermediate layer showed good bending strength. However, they showed relatively poor resistance against pulling off. The thickness of titanium anodized intermediate layer can be controlled much more precisely than that of plasma sprayed one, which is important for practical application.