• Title/Summary/Keyword: H3 absorption

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A Study on Carbon Dioxide Capture Performance of KOH Aqueous Solution via Chemical Absorption (화학 흡수를 이용한 KOH 수용액의 이산화탄소 포집 성능에 관한 연구)

  • Yoo, Mi-Ran;Han, Sang-Jun;Shin, Ji-Yoon;Wee, Jung-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.1
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    • pp.55-62
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    • 2012
  • The present paper investigates the performance of the KOH aqueous solution as an absorbent to capture carbon dioxide ($CO_2$). The chemical absorption was carried out according to consecutive reactions that are generated in the order of $K_2CO_3$ and $KHCO_3$. The overall absorption was completed with following the physical absorption. When the absorption was conducted with the KOH as the limiting reactants in batch a reactor, $K_2CO_3$ production rate was the 1st order reaction for $OH^-$. However, $KHCO_3$ generation reaction was independent of the $CO_3^{2-}$ concentration and the rate was calculated to be $0.18gCO_2/min$ for all KOH absorbents, which is the same value of the reaction rate using $K_2CO_3$ aqueous solution as the absorbents. The overall $CO_2$ capture ratio of the 5% KOH absorbent was estimated to be 19% and the individual value in section 1 and 2 was 57 and 12%, respectively. The amount of $CO_2$ absorbed in the solution was very slightly less than the theoretical value, which was ascribed to the side reaction that produces $K_2CO_3{\cdot}KHCO_3{\cdot}1.5H_2O$ during the reaction and the consequent diminish in $CO_2$ absorption in the KOH solution.

Development of a Compression/Absorption Hybrid Heat Pump System Using $NH_3/H_2O$ Mixture for High Temperature Generation ($NH_3/H_2O$를 이용한 압축-흡수식 고온제조 하이브리드 히트펌프 시스템 개발)

  • Kim, Min-Sung;Baik, Young-Jin;Shin, Kwang-Ho;Park, Seong-Ryong;Chang, Ki-Chang;Lee, Young-Soo;Ra, Ho-Sang
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.1249-1254
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    • 2008
  • Industrial low temperature waste heat exists sparse in surroundings but its amount is huge. However, large portion of waste heat is discarded due to its poor recovery quality and inferior application technologies. The heat pump system in this research is based on the hybrid combination of compression cycle and absorption cycle in order to recycle various kind of industrial waste heat effectively. The prime objective is to design a compression absorption hybrid heat pump system which can produce high temperature above the level of $90^{\circ}C$ and low temperature of $20^{\circ}C$ at the same time using waste heat water of $50^{\circ}C$. A mathematical simulation was carried out as a basis to design a prototype 3 RT class hybrid heat pump. From the simulation results, fundamental parameters to design the system were obtained.

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The Uptake of Lead Ion with Staphylococcus epidermidis (Staphylococcus epidermidis 를 이용한 납 이온의 축적에 관한 연구)

  • 김종혜;김말남
    • Korean Journal of Microbiology
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    • v.30 no.4
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    • pp.310-315
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    • 1992
  • Absorption of $\textrm{Pb}^{2-}$ from aqueous solution was studied using Staphylococcus epidermidis. Cells of exponential phase were employed as absorbents. Uptake ratio defined as the ratio of amount of $\textrm{Pb}^{2+}$ absorbed to that of initial $\textrm{Pb}^{2+}$. Absorption of $\textrm{Pb}^{2+}$ increased with increase in cell concentration. while amount of $\textrm{Pb}^{2+}$ per unit cell mass decreased. Uptake ratio of $\textrm{Pb}^{2+}$ augmented and then diminished after exhibiting a maximum as the pH of the solution increased. Equilibrium absorption of $\textrm{Pb}^{2+}$ deviated from Freundlich isotherm especially at higher concentration of $\textrm{Pb}^{2+}$ due to the precipitation phenomena. HCI and EDTA were founded to desorb $\textrm{Pb}^{2+}$ more effectively than $\textrm{Na}_{2}\textrm{CO}_{3}$ or $\textrm{NaHCO}_{3}$. After 10 cycles of absorption and desorption. $\textrm{Pb}^{2+}$ absorption capability remained almost unchanged and the biomass had leaked out 30-40 wt/%. Uptake ratio of Pb2+ decreased in the presence of other heavy metal ions due to the competitive absorption The inhibition of $\textrm{Pb}^{2+}$ absorption appeared to have a strong correlation with ionic radius of the competing ions. Especially $\textrm{Cr}^{3-}$, $\textrm{Co}^{2+}$ or $\textrm{Fe}^{2+}$ having smaller ionic radius depressed more significantly the uptake of $\textrm{Pb}^{2+}$ than any other metal ions tested.

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Enhancement of $NH_3$ Bubble Absorption Performance in Binary Nanofluids (이성분 나노유체에서의 암모니아 기포 흡수 성능 향상)

  • Jung Jun Young;Kim Jin-Kyeong;Kang Yong Tae
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.4
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    • pp.312-317
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    • 2005
  • The objectives of this paper are to study the absorption characteristics of $NH_3$ bubbles in the binary nanofluids and to quantify the effects of surfactants and nano-particles on the bubble absorption performance. 2-Ethyl-1-Hexanol, n-Octanol, and 2-Octanol are used as the surfactants and nano-sized $Al_{2}O_3$ and Cu particles are added to make the binary nanofluids into $NH_3/H_{2}O$ solution. The concentration of $NH_3$ solution ($x_s$), the concentration of surfactants ($x_{SA}$), and the mass fraction of nano-particles ($w_{np}$) are considered as key parameters. The experimented ranges of $x_s,\;x_{SA},\;and\;w_{np}$ are $0{\sim}17.92\%,\;0{\sim}1,500\;ppm\;and\;0{\sim}0.2\%$, respectively. The absorption rates are calculated by measuring initial and final weights of test section and exposed time. In addition, the bubble absorption processes are visualized using the shadow graphic method. The results show that the absorption performance is significantly enhanced up to 4 times by adding the surfactants and up to 3 times in the binary nanofluids.

Enhancement of Porosity and Strength of Porous Al2O3 Ceramics by Al(H2PO4)3 Addition

  • Bai, Jiahai;Piao, Jiasi;Gao, Jie;He, Jing;Du, Qingyang;Li, Chengfeng
    • Journal of the Korean Ceramic Society
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    • v.56 no.4
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    • pp.350-353
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    • 2019
  • Porous alumina ceramics with addition of 0, 5, 10, 15, and 20 wt% Al(H2PO4)3 were sintered at 1300, 1350, and 1400℃. The effects of the Al(H2PO4)3 addition on crystal phases, water absorption, open porosity, pore size distribution, microstructures, and flexural strength were studied extensively. The experimental results revealed that only characteristic peaks of corundum were indexed in the XRD patterns of the as-prepared porous ceramics. The water absorption and open porosity of the porous Al2O3 ceramics increased remarkably with an increase in Al(H2PO4)3 addition. The flexural strength first increased to a maximum value when 5 wt% Al(H2PO4)3 was added and then decreased as additional Al(H2PO4)3 was further added. SEM images showed that the average Al2O3 grain size in the porous ceramics changed in an opposite way as the flexural strength. The porous Al2O3 ceramics with 10 wt% Al(H2PO4)3 addition exhibited comparable flexural strength to the ceramics without Al(H2PO4)3 addition, although the latter had much higher porosity.

Pharmacokinetics of Omeprazole-Resin by Crossover Design and the Variation of Absorption upon pH Change in the Guts of the Rat and the Rabbit (Omeprazole 수지염의 흰쥐와 토끼에서의 위장관내 산도변화에 따른 흡수변화 및 교차시험법에 의한 약물동태연구)

  • 권광일;심상호
    • YAKHAK HOEJI
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    • v.39 no.4
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    • pp.401-410
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    • 1995
  • Pharmacolinetic profiles of omeprazole enteric coated granules including Ramezole$^\circledR$, Losec$^\circledR$, omeprazole-Na and omeprazole-resin salt were studied using the crossover design in rats and rabbits. The absorption variance of the preparations at the altered pH condition of the gastrointestinal tract was also studied. After oral administration of four omeprazole enteric coated pellets (10mg/kg) with and without concomitant administration NaHCO$_{3}$ (5 mg/ml, 60 mM) in the rats, the differences of absorplion rate and extent were evaluated. In the NaHCO$_{3}$, administration group, the T$_{max}$ appeared to be 2~10 times shorter than water administration group, and the $C_{max}$ also increased to about 4 times, and the AUC increased to about 2.5 times. Pharmacokinetic parameters of four omeprazole enteric coated pellets in rats showed no statistical significance (ANOVA, P>0.05) in both groups. In the crossover study, the second dosed drug showed 4~5 times increased bioavailability than first dosed drug, which shows the strong carry-over effect of acid secretion of the first dosed drug. The differences of the pharmacokinetic parameters of the two test formulations (Losec$^\circledR$ and omeprazole-resin) showed no statistical significance.

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Synthesis and Physico-Chemical Properties of Dicalcium Phosphate Dihydrate for Dental Abrasive (치아 연마용 인산일수소칼슘의 합성 및 물리화학적 성질)

  • 서성수;황성주;이기명;이계주
    • YAKHAK HOEJI
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    • v.37 no.1
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    • pp.66-75
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    • 1993
  • Dental abrasive, dicalcium phosphate dehydrate (DCPD) was prepared and the several important factors affecting on the quality of toothpaste were investigated by means of set test, glycerine absorption, Coulter counter test, color difference, BET adsorption, mercury porosimetery, and rheogram comparing with two foreign DCPDs, MFO4 and Dentphos K. Sample DCPD was prepared by reaction between 85% H$_{3}$PO$_{4}$ and 15% milk of lime at $39^{\circ}C$ (pH6.5), and stabilized with TSPP and TMP. The physicochemical properties of Sample DCPD were obtained as follows: whiteness (98.99), average particle size (15.5 $\mu\textrm{m}$), pH (7.9), remainder particle weight (0.49w/w%), glycerine absorption value (64 ml), and set test (passed). N$_{2}$ adsorption curves (BET) of three kinds of DCPD showed non-porous type III isotherm. BET adsorption parameters of sample DCPD showed that surface area was 24.9 m$^{2}$/g, total pore volume 0.09 cm$^{3}$/g and average pore radius 72.0 $\AA$. The rheogram of the toothpaste containing each DCPD showed bulged plastic flow with yield vlaue and thixotropic behavior. These results meet standard requirements as abrasive standard, and suggested that synthesized sample DCPD could be used a dental abrasive such as a high quality grade in practice as foreign DCPDs.

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Optical detection of protein patterns using 1,3-bisdicyanovinylindane (1,3-bisdicyanovinylindane을 이용한 단백질 패터닝의 광학적 감지)

  • Park, Young-Min;Lee, Ji-Hye;Lee, Chang-Soo;Son, Young-A
    • Textile Coloration and Finishing
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    • v.19 no.4
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    • pp.32-37
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    • 2007
  • In this study, we have obtained the protein patterns using the membrane patterning of soft-lithography technique. The rapid detection of protein including bovine serum albumin (BSA) was resulted from the interaction with 1,3-bisdicyanovinylindane. For the proof of the interaction between BSA and dye, the UV-vis absorption spectra of BSA and dye were observed at 278 nm and 580 nm, respectively. As expected, the absorption spectrum of the interaction between BSA and dye was observed at 584nm. The absorption spectrum of the interaction was red-shifted. In addition, the optical images of the selectively reacted protein patterns showed the distinctive change of patterned color at different pH conditions. Because the dye has negative charges, the charge of BSA at different pH conditions could influence the interaction behavior between dye and BSA. Therefore, in the case of pH 7, the selectively patterned protein substrates obtained deep blue color pattern caused by electrostatic interaction between negative charges of the dye and positive charges of the BSA. However, in the case of pH 10, selectively patterned protein substrates obtained light blue color pattern because the electrostatic interaction was relatively lower than pH 7 due to the change of overall charge distribution of BSA.

Dynamic Performance of Guardrail System with Various Post Shapes Based on 3-D Soil Material Model (3차원 지반재료 모델기반의 다양한 지주형상을 갖는 노측용 가드레일의 동적성능 평가)

  • Lee, Dong Woo;Yeo, Yong Hwan;Yang, Seung Ho;Woo, Kwang Sung
    • International Journal of Highway Engineering
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    • v.16 no.5
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    • pp.19-28
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    • 2014
  • PURPOSES : This paper evaluates, using LS/DYNA-3D software, the vehicle impact performance of flexible barriers made of steel W-Beam supported by four different types of post configurations. These types include circular post, H-shape post, C-shape post, and square post. METHODS : The post-soil interaction has been investigated according to different impact angles. For this purpose, energy absorption, maximum displacements of post and rail, and occupant risk index of THIV have been compared each other. The three dimensional soil material model, instead of the conventional spring model based on Winkler and p-y curve, has been used to increase the correctness of computational model. RESULTS : It is noted the crash energy absorption has been increased with respect to the increase of impact angle. CONCLUSIONS : In particular, a post with open section(H-shape, C-shape) shows the greater crash energy absorption capability as compared with a post with closed section under the same level of impact conditions.

Cycle Analysis of Air-Cooled Double-Effect Absorption Cooling System Using H2O/LiBr+HO(CH2)3OH (H2O/LiBr+HO(CH2)3OH계 공냉형 이중효용 흡수식 냉방시스템의 사이클 해석)

  • Kwon, Oh-Kyung;Moon, Choon-Geun;Yoon, Jung-In
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.2
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    • pp.272-280
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    • 1999
  • A cycle analysis was achieved to predict the characteristics by comprehensive modeling and simulation of an air-cooled, double-effect absorption system using a new $H_2O/LiBr+HO(CH_2)_3OH$ solution. The simulation results showed that the new working fluid may provide the crystallization limit 8% higher than the conventional $H_2O/LiBr$ solution. With a crystallization margin of 3wt%(weight%), the optimal solution distribution ratio was found in the range of 36 to 40%. Variation of cooling air Inlet temperature has a sensitive effect on the cooling COP and corrosion problem. The simulation of heat exchangers with UA value revealed that the absorber and the evaporator are relatively important for an air-cooled system compared with the condenser and the low temperature generator. The effect of cooling air flow rate, circulation weak solution flow rate and chilled water inlet temperature were also examined. The new working fluid may provide the COP approximately 5% higher than the conventional $H_2O/LiBr$ solution.