• Title/Summary/Keyword: H2 absorption

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Design Parameters Estimations for Bubble Column Reactors to Remove Toxic Gases (독성가스 제거용 기포탑 반응기의 설계기법)

  • Oh, Junghwan;Hong, Min Sun
    • Korean Journal of Hazardous Materials
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    • v.6 no.2
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    • pp.95-104
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    • 2018
  • Gas-liquid bubble column reactors are extensively used in industrial processes. A detailed knowledge of bubble size distribution is needed for determining the mass transfer in gas-liquid film. Experimental data on bubble size distribution and liquid-side mass transfer coefficient($k_L$) were used to calculate the estimated time to saturation in bubble column reactor. Also, the gas flux was evaluated to the liquid-side mass transfer coefficient($k_L$) and solubility data for hydrogen sulfide($H_2S$) and chlorine($Cl_2$) absorption into water. Simulation results show that $H_2S$ absorption time to 50 % of saturation concentrations are 611 sec and 1,329 sec when bubble diameters are 0.5 mm and 4.5 mm, while absorbing 1 % $H_2S$ gas. In case of $Cl_2$, absorption time range 657 to 1,400 sec when bubble size range 0.5 mm to 4.5 mm, while absorbing 1 % $Cl_2$ gas. Calculated simulation results can be used in the design of emergency relief bubble reactors.

Influences of Extraction pH on the Functionality of Soybean Protein Isolate (추출 pH가 분리대두단백질의 기능성에 미치는 영향)

  • Bae, Song-Hwan;Rhee, Chul
    • Korean Journal of Food Science and Technology
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    • v.30 no.3
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    • pp.557-561
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    • 1998
  • This study was conducted to investigate the functionality of soybean protein isolates extracted in acidic range (pH 2.0 and 3.0), neutral range (pH 7.0) and alkaline range (pH 10.0 and 12.0). The protein content of soybean protein isolates extracted at pH 3.0 was maximum (93.31%), but that of pH 7.0 was minimum (73.93%). The extraction yield of soybean protein isolates extracted at pH 3.0 was minimum (0.36%), but that of pH 12.0 was maximum (47.54%). The functionality (solubility, water absorption, oil absorption, foam capacity, foam stability, emulsion capacity and gelation) of soybean protein isolates was significantly influenced by pH of extraction medium. The soybean protein isolates extracted at pH 2.0 and 3.0 were more soluble at acidic ranges and those of pH 3.0 and 7.0 were more soluble at neutral ranges, but those of pH 2.0, 3.0, 7.0, 10.0 and 12.0 were more soluble at alkaline ranges than other ranges. The soybean protein isolates extracted at pH 2.0 and pH 12.0 gave greater water absorption, oil absorption and foam capacity than those extracted at pH 3.0, pH 7.0 and pH 10.0. And the emulsion capacity of soybean protein isolates was increased by the increase of extraction pH.

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Diurnal Variation of Equivalent Width of H2O and O2 in Earth's Atmosphere (지구 대기 중 H2O, O2 등가폭의 일중 변화)

  • Kang, Dong-Il
    • Journal of the Korean earth science society
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    • v.31 no.4
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    • pp.348-353
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    • 2010
  • The scattered light of solar radiance near the infrared ray area was observed to measure $H_2O$ and $O_2$ absorption lines. The changes of $H_2O$ and $O_2$ equivalent width were calculated on the basis of the measurement. $O_2$ equivalent width showed negative correlation with the amount of solar radiance; $O_2$ equivalent width had a tendency to diminish as the amount of the solar radiance increased and to increase as the amount of the solar radiance decreased. On the other hand, $H_2O$ equivalent width showed the positive correlation with the amount of solar radiance. Especially it was noted that the sum of equivalent width of absorption lines created by $H_2O$ and $O_2$ in a day was fairly constant. It is implied that the constant equivalent width is caused by the complementary development of photodissociation and recombination in $O_2$ and $H_2O$.

A Kinetic Study of Phosphate Absorption by Rice Roots (벼에 의한 인산흡수의 기작에 관한 연구)

  • 장남기
    • Journal of Plant Biology
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    • v.21 no.1_4
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    • pp.33-38
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    • 1978
  • Phosphate absorption from a Na2H32PO4 solution by Oryza sativa L. was studied in order to elucidate kinetic mechanisms of ion transport. The rates of phosphate absorption from different concentraitons indicated the presence of dual mechanisms in root tips, one in the low (1$\times$10-6 to 8$\times$10-5M) and the other in the high (1$\times$10-4 to 8$\times$10-3M). A phosphate compensation point of phosphate transport was revealed with a 1$\times$10-6M solution of Na2H32PO4. The kinetic model that ion transport involves an exchange reaction of absorption and desorptin is prosposed as follows: where C represents an ionic-specific organic carrier in the membrane; M, Mo and Mi are the mineral ions, M-outside and M-inside; MC is a carrier-ion complex; and the K's represent rate constants. In this model, the Mi velocity, v, is given by: {{{{v= {dMi} over {dt}= {(K1K3Mo-K2K4Mi) Ct} over {(K2+K3)+K1Mo+K4Mi} }} where Ct is equal to C+MC, and t is time.

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Measurements of the Benzene Absorption Cross Section in the Range of Ultra Violet (UV) (UV 영역에서 벤젠의 흡수 단면적의 측정)

  • Lee, J.S.;Ryu, S.Y.;Kim, H.H.;Woo, J.C.;Kim, K.B.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.6
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    • pp.922-928
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    • 2006
  • An absolute absorption cross section of benzene was measured with a spectrometer system including a mono-chrometer and a grating in the wavelength region of $240{\sim}280nm$ under the atmospheric pressure and room temperature in the laboratory. A certificated reference benzene gas ($98{\mu}mol/mol$ in $N_2$) was used to measure its absorption cross section. A 710 mm cell with a quartz window and a 150 W Xe arc lamp were employed. The magnitude of absorption cross section of $1.41{\times}10^{-18}cm^2$ was lower than that of the reference spectra ($2.5{\times}10^{-18}cm^2$) of high resolution spectrometer, Total measurement uncertainty was estimated to be 4.0%.

Relation of pH value to the availability of P32 (인산흡수와 산성도와의 관계)

  • 차종환
    • Journal of Plant Biology
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    • v.10 no.1_2
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    • pp.36-40
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    • 1967
  • 1. The effect of the pH value on P32 absorption of leaves of three forest trees under the water culture is investigated. 2. The degree of the P32 absorption to the pH value is quite different in each forest tree. 3. The phosphorus contents are proved higher in the leaves of Quercus accutissima(the saw shaped oak) than in the leaves of Pinus densiflora(the red pine) and Lespedeza bicolar (bush clover). 4. Larger contents of phosphorus are found in acidity plots than in alkalinity. The leaves of treated plot of the pH 4 (red pine), of the pH 5.0 (bush clover), and of the pH 5.0-6.5 (saw shaped oak) have a higher nutrient capital as indicated by P32 compared with that of the other pH values. 5. It is also noticed that P32 absorption capacity is decreased with the higher pH values. 6. The content of P of leaves shows the lowest value in the plot of the pH 6.5 (pine), of the pH 7.5(bush clover), and of the pH 9.0(saw shaped oak). It is also noticed that the red pine is to do very well in acid cultivation and then follow bush clover and saw shaped oak in the order.

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A Study on Wet Process of $H_2S$ removal with MDEA (MDEA를 이용한 $H_2S$의 습식탈황 고찰)

  • Han, Keun-Hee;Jo, A-Ra;Lee, Jong-Seup;Min, Byoung-Moo
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.238-241
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    • 2008
  • In this study, absorption behaviors of absorbents and additives were measured for removing of $H_2S$ and COS from syn-gas in IGCC process, such as MDEA and HMDA. The experimental variables were concentration of absorbents and reaction temperature. From these experiments, the loading ratios of $H_2S$ were decreased with increasing of concentration of absorbents and absorption temperatures. These results will be applied to basic data for designing of $H_2S$ removal process in IGCC.

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The Comparison of Absorption Characteristics between High Absorbent Polymers and Cellulose (고흡수성(高吸水性) Polymer와 Cellulose의 흡수특성(吸水特性) 비교(比較))

  • Yang, In;Ahn, Won-Yung
    • Journal of the Korean Wood Science and Technology
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    • v.18 no.2
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    • pp.36-48
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    • 1990
  • This experiment was carried out to improve the quality of high absorbent polymer which has excellent absorptivity and water retention compared to pulp and absorption sheet, through absorption characteristics-absorptive power, water retention, absorption rate, gel strength, pH, particle size, and moisture content. - of six polymers, namely, anionic polyacrylamide, cationic polyacrylamide, polyacrylic, acid polyvinyle alcohol 500, and 1500, and a-cellulose. and to examine the possibility of substitution of amide groups for carboxyl group and/or hydroxyl group which were commercial high absorbent polymer by comparing the absorption characteristics of the polymers. Polyacrylamide has high absorptive power and water retention, but has low gel strength and poor absorption rate. The rest of polymers were similiar to ${\alpha}$-cellulose in every respect. Thus, polyacrylamides could be replaced with polyacrylic acid and polyvinyl alcohol which are presently a high absorbent polymers. In comparing the absorption characteristics and the absorptive power of the polymers-anionic polyacrylamide, cationic polyacrylamide, polyacrylic acid, polyvinyle alcohol. a-cellulose-the absorptive power was in inverse proportion to the gel strength and absorption rates, affected by the particle size and pH change.

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Simulation of Alcohol Absorption Heat Pumps for Heating Performance (알코올 흡수식 열펌프의 난방성능 예측)

  • Kim, Dong-Seon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.27 no.5
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    • pp.269-276
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    • 2015
  • Single-effect $CH_3OH-LiI-ZnBr_2$ and $C_2H_5OH-LiI$ absorption heat pumps are simulated to evaluate feasibility as heating device. These systems are predicted to give higher heating COPs in wide operating ranges compared to conventional systems. Among the two systems, the $C_2H_5OH-LiI$ system is found to be more advantageous for operating in extremely cold weather due to the large solubility of Lil in $C_2H_5OH$.

Hydride Generation-Atomic Absorption Spectrophotometric Determination of Total Selenium in Atmospheric Particulate (환원기화 원자 흡광광도법에 의한 대기분진중의 총 셀렌의 정량)

  • 이용근;최건형;이동수;황규자
    • Journal of Korean Society for Atmospheric Environment
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    • v.6 no.2
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    • pp.147-154
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    • 1990
  • A sensitive method for the determination of total selenium in aerosol particles is described. The method involves dissolution of aerosol particles by $HNO_3-HClO_4$ mixed acids, pre-reduction of Se (VI) to Se (IV) by boiling hydrochloric acid, and hydride generation followed by atomic absorption detection. Dissolved Se (IV) in 4M hydrochloric acid is reacted with $NaBH_4$ to form $H_2Se$, which is subsequently collected in an U-tube cooled in liquid nitrogen. Upon the completion of $H_2Se$ generation, the collected $H_2Se$ is rapidly vaporized into a quartz cuvette burner by removing the U-tube from liquid nitrogen, atomized, and then detected by an atomic absorption spectrophotometer. The absolute sensitivity of the method is 0.49 ng/0.0044 Abs. The accuracy of the method evaluated by analyzing standard reference materials for urban aerosol is better than 10%. Analytical results for urban and rural aerosol particles are reported.

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