• Title/Summary/Keyword: H1N2

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Corrosion of Fe-2%Mn-0.5%Si Steels at 600-800℃ in N2/H2O/H2S Atmospheres

  • Kim, Min-Jung;Park, Sang-Hwan;Lee, Dong-Bok
    • Journal of the Korean institute of surface engineering
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    • v.44 no.5
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    • pp.201-206
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    • 2011
  • Fe-2%Mn-0.5%Si alloys were corroded at 600, 700 and $800^{\circ}C$ for up to 70 h in 1 atm of $N_2$ gas, or 1 atm of $N_2/H_2O$-mixed gases, or 1 atm of $N_2/H_2O/H_2S$-mixed gases. Oxidation prevailed in $N_2$ and $N_2/H_2O$ gases, whereas sulfidation dominated in $N_2/H_2O/H_2S$ gases. The oxidation/sulfidation rates increased in the order of $N_2$ gas, $N_2/H_2O$ gases, and, much more seriously, $N_2/H_2O/H_2S$ gases. The base element of Fe oxidized to $Fe_2O_3$ and $Fe_3O_4$ in $N_2$ and $N_2/H_2O$ gases, whereas it sulfidized to FeS in $N_2/H_2O/H_2S$ gases. The oxides or sulfides of Mn or Si were not detected from the XRD analyses, owing to their small amount or dissolution in FeS. Since FeS was present throughout the whole scale, the alloys were nonprotective in $N_2/H_2O/H_2S$ gases.

The ab Initio Quantum Mechanical Investigation for the Weakly Bound $H^+_{2n+1}$(n=1-6) Complexes (약한 결합을 갖는 $H^+_{2n+1}$(n=1-6) complex들에 대한 순 이론 양자역학적 연구)

  • In, Eun Jeong;Seo, Hyeon Il;Kim, Seung Jun
    • Journal of the Korean Chemical Society
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    • v.45 no.5
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    • pp.401-412
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    • 2001
  • The geometrical parameters, vibrational frequencies, and dissociation energies for $H_{2n+1}^+$ (n=1~6) clusters have been investigated using high level ab initio quantum mechanical techniques with large basis sets. The equilibrium geometries have been optimized at the self-consistent field (SCF), the single and double excitation configuration interaction (CISD), the coupled cluster with single and double excitation (CCSD), and the CCSD with connected triple excitations [CCSD(T)] levels of theory. The highest levels of theory employed in this study are TZ2P+d CCSD(T) up to $H^+_g$ and TZ2P CCSD(T) for $H_{11}^+$ and $H_{13}^+$. Harmonic vibrational frequencies are also determined at the SCF level of theory with various basis sets and confirm that all the optimized geometries are true minima. The dissociation energies, $D_e$, for $H_{2n+1}^+$ (n=26) have been predicted using energy differences at each optimized geometry and zero-point vibrational energies(ZPVEs) have been considered to compare with experimental dissociation energies, $D_0$.

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Interpretation and Prospection of Influenza Virus through Swine-origin Influenza Virus (신종플루 바이러스를 통한 인플루엔자 바이러스의 해석 및 전망)

  • Chang, Kyung-Soo
    • Korean Journal of Clinical Laboratory Science
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    • v.42 no.1
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    • pp.1-15
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    • 2010
  • Swine influenza virus (SIV) or swine-origin influenza virus (S-OIV) is endemic in swine, and classified into influenza A and influenza C but not influenza B. Swine influenza A includes H1N1, H1N2, H3N1, H3N2 and H2N3 subtypes. Infection of SIV occurs in only swine and that of S-OIV is rare in human. What human can be infected with S-OIV is called as zoonotic swine flu. Pandemic 2009 swine influenza H1N1 virus (2009 H1N1) was emerged in Mexico, America and Canada and spread worldwide. The triple-reassortant H1N1 resulting from antigenic drift was contained with HA, NA and PB1 of human or swine influenza virus, PB2 and PA polymerase of avian influenza virus, and M, NP and NS of swine influenza virus, The 2009 H1N1 enables to transmit to human and swine. The symptoms and signs in human infected with 2009 H1N1 virus are fever, cough and sore throat, pneumonia as well as diarrhea and vomiting. Co-infection with other viruses and bacteria such as Streptococcus pneumoniae can occur high mortality in high-risk population. 2009 H1N1 virus was easily differentiated from seasonal flu by real time RT-PCR which contributed rapid and confirmed diagnosis. The 2009 H1N1 virus was treated with NA inhibitors such as oseltamivir (Tamiflu) and zanamivir (Relenza) but not with adamantanes such as amantadine and rimantadine. Evolution of influenza virus has continued in various hosts. Development of a more effective vaccine against influenza prototypes is needed to protect new influenza infection such as H5 and H7 subtypes to infect to multi-organ and cause high pathogenicity.

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Studies on the Molybdenum Complexes with Tridentate Schiff Base Ligand (I) (세자리 Schiff Base 리간드의 몰리브덴 착물에 관하여 (제1보))

  • Ki Hyung Chjo
    • Journal of the Korean Chemical Society
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    • v.17 no.3
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    • pp.169-173
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    • 1973
  • The tridentate schiff base ligand, salicyliden amino-o-hydroxy benzene, has derived from salicylaldehyde and o-amino phenol. This ligand reacts with a series of Mo (VI), Mo (V), Mo (IV), and Mo (III) oxidated states and forms a new complexes; [Mo O$_2(H_2O)\;(C_{13}H_9O_2N)]$, [MoO Cl$(H_2O)\;(C_{13}H_9O_2N)]$, [Mo(SCN)$_2(H_2O)\;(C_{13}H_9O2_N)]$$[Mo(H_2O)_2\;(C_{13}H_9O_2N)]_2O$. The Mo (VI), Mo(V) and Mo(Ⅳ) ions in these complexes are octahedron, hexa coordinate, and the mole ratio of these ions to the ligand are 1 : 1, but Mo (III) Complex is a Mo-O-Mo oxygen bridge bond and polynuclear, and the mole ratio of Mo (III) to the ligand 1 : 1 above facts are identified from the data of Infrared spectra, visible spectra, and elemental analysis.

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SOME RESULTS ON STARLIKE TREES AND SUNLIKE GRAPHS

  • Mirko, Lepovic
    • Journal of applied mathematics & informatics
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    • v.11 no.1_2
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    • pp.109-123
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    • 2003
  • A tree is called starlike if it has exactly one vertex of degree greate. than two. In [4] it was proved that two starlike trees G and H are cospectral if and only if they are isomorphic. We prove here that there exist no two non-isomorphic Laplacian cospectral starlike trees. Further, let G be a simple graph of order n with vertex set V(G) : {1,2, …, n} and let H = {$H_1$, $H_2$, …, $H_{n}$} be a family of rooted graphs. According to [2], the rooted product G(H) is the graph obtained by identifying the root of $H_{i}$ with the i-th vertex of G. In particular, if H is the family of the paths $P_k_1,P_k_2,...P_k_2$ with the rooted vertices of degree one, in this paper the corresponding graph G(H) is called the sunlike graph and is denoted by G($k_1,k_2,...k_n$). For any $(x_1,x_2,...,x_n)\;\in\;{I_*}^n$, where $I_{*}$ = : {0,1}, let G$(x_1,x_2,...,x_n)$ be the subgraph of G which is obtained by deleting the vertices $i_1,i_2,...i_j\;\in\;V(G)\;(O\leq j\leq n)$, provided that $x_i_1=x_i_2=...=x_i_j=o.\;Let \;G[x_1,x_2,...x_n]$ be characteristic polynomial of G$(x_1,x_2,...,x_n)$, understanding that G[0,0,...,0] $\equiv$1. We prove that $G[k_1,k_2,...,k_n]-\sum_{x\in In}[{\prod_{\imath=1}}^n\;P_k_i+x_i-2(\lambda)](-1)...G[x_1,x_2,...,X_n]$ where x=($x_1,x_2,...,x_n$);G[$k_1,k_2,...,k_n$] and $P_n(\lambda)$ denote the characteristic polynomial of G($k_1,k_2,...,k_n$) and $P_n$, respectively. Besides, if G is a graph with $\lambda_1(G)\;\geq1$ we show that $\lambda_1(G)\;\leq\;\lambda_1(G(k_1,k_2,...,k_n))<\lambda_1(G)_{\lambda_1}^{-1}(G}$ for all positive integers $k_1,k_2,...,k_n$, where $\lambda_1$ denotes the largest eigenvalue.

The Effect of RF Power and $SiH_4$/($N_2$O+$N_2$) Ratio in Properties of SiON Thick Film for Silica Optical Waveguide (실리카 광도파로용 SiON 후막 특성에서 RF Power와 $SiH_4$/($N_2$O+$N_2$) Ratio가 미치는 영향)

  • 김용탁;조성민;서용곤;임영민;윤대호
    • Journal of the Korean Ceramic Society
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    • v.38 no.12
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    • pp.1150-1154
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    • 2001
  • Silicon oxynitride (SiON) thick films using the core layer of silica optical waveguide have been deposited on Si wafer by PECVD at low temperature (32$0^{\circ}C$) were obtained by decomposition of appropriate mixture of (SiH$_4$+$N_2$O+$N_2$) gaseous mixtures under RF power and SiH$_4$/($N_2$O+$N_2$) ratio deposition condition. Prism coupler measurements show that the refractive indices of SiON layers range from 1.4663 to 1.5496. A high SiH$_4$/($N_2$O+$N_2$) of 0.33 and deposition power of 150 W leads to deposition rates of up to 8.67 ${\mu}{\textrm}{m}$/h. With decreasing SiH$_4$/($N_2$O+$N_2$) ratio, the SiON layer become smooth from 41$\AA$ to 6$\AA$.

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Solid-solid phase transitions of organic-inorganic perovskite hybrids (유기-무기 페로브스카이트 복합소재의 고체-고체 상전이)

  • Huh, Young-Duk;Kim, Ji-Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.2
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    • pp.86-91
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    • 2005
  • The layered structure of organic-inorganic perovskite hybrids, $(C_nH_{2n+1}NH_3)_2CuC1_4$ (n = 6, 8, 10, 12) have synthesized. In $(C_nH_{2n+1}NH_3)_2CuC1_4$ compounds, the long-chain protonated alkylammonium ions as tilted bilayer type are inserted into perovskite-type layers of corner sharing $CuCl_6$ octahedron. Three solid phases have been characterized in the perovskite layered compound $(C_nH_{2n+1}NH_3)_2CuC1_4$ using HT-XRD and DSC. The $(C_nH_{2n+1}NH_3)_2CuC1_4$ compounds shows solid-solid phase transitions with stepwise increasing of the layer distance. Three different structures are explained by the conformational change of the long-chain protonated alkylammonium ions.

Synthesis and Characterization of Palladium and Platinum Complexes of N,N'-Bis[2'-(diphenylphosphino)phenyl]propane-1,3-diamine. Single-Crystal Structures of $[Pd(Ph_2PC_6H_4NC_3H_6NC_6H_4PPh_2)]$ and $[Pt(Ph_2PC_6H_4NH)(SEt_2)Cl]$

  • 유동원;김은진;강상옥;고재정;이승희
    • Bulletin of the Korean Chemical Society
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    • v.19 no.5
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    • pp.565-568
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    • 1998
  • Novel mononuclear metal complexes with the formula $[M(Ph_2PC_6H_4NC_3H_6NC_6H_4PPh_2)]$ (M=Pd (1); M=Pt (2)) were obtained when N,N'-bis[2'-(diphenylphosphino)phenyl]propane-1,3-diamine, I was mixed with cisdichlorobis(diethylsulfide)palladium and platinum in the presence of NEt3. Two mononuclear metal compounds with the fomula [M(Ph2PC6H4NH)(SEt2)Cl] (M=Pd (3); M=Pt (4)) were synthesized from $M(SEt_2)2Cl_2$ and N-(2'-diphenylphosphinophenyl)-4-amino-1,1,1,5,5, 5-hexafluoro-3-penten-2-one, II by the elimination reaction of hexafluoro pentenone. The X-ray single crystal structures of 1 and 4 are described. X-ray single crystal diffraction analyses reveal that compound 1 is a mononuclear palladium compound with P,N,N,P-coordination mode and 4 is a mononuclear platinum compound with P,N-coordination mode.

Self-Assembly of Vanadium Borophosphate Cluster Anions: Synthesis and Structures of (NH4)(C2H10N2)5.5[Cu(C2H8N2)2]3[V2P2BO12]6·17H2O and (NH4)(C2H10N2)3.5[Cu(C2H8N2)2]5[V2P2BO12]6·18H2O

  • Jung, Kyung-Na;Cho, Yoon-Suk;Yun, Ho-Seop;Do, Jung-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.26 no.8
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    • pp.1185-1189
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    • 2005
  • Two new copper vanadium borophosphate compounds, $(NH_4)(C_2H_{10}N_2)_{5.5}[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6{\cdot}17H_2O,\;Cu-VBPO1\;and\;(NH_4)(C_2H_{10}N_2)_{3.5}[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6{\cdot}18H_2O$, Cu-VBPO2 have been hydrothermally synthesized and characterized by single crystal X-ray diffraction, thermogravimetric analysis, IR spectroscopy, and elemental analysis. The structure of Cu-VBPO1 contains a layer anion, {$[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6$}$^{12-}$, whereas Cu-VBPO2 has an open framework anion, {$[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6$}$^{8-}$. Crystal Data: $(NH_4)(C_2H_{10}N_2)_{5.5}[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6{\cdot}17H_2O$, monoclinic, space group I2/m (no. 12), $\alpha$ = 15.809(1) $\AA$, b = 31.107(2) $\AA$, c = 12.9343(8) $\AA$, $\beta$ = 104.325(1)$^{\circ}$, Z = 2; $(NH_4)(C_2H_{10}N_2)_{3.5}[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6{\cdot}18H_2O$, tetragonal, space group $P4_2$/mnm (no.136), $\alpha$ = 26.832(1) $\AA$, c = 18.021(1) $\AA$, Z = 4.

Performance Characteristics of New LNG Liquefaction Cycles with Temperature Differences in the Heat Exchangers (열교환기 온도차에 따른 새로운 LNG 액화사이클의 성능 특성)

  • Yoon, Jung-In;Son, Chang-Hyo
    • Journal of Power System Engineering
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    • v.18 no.1
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    • pp.51-56
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    • 2014
  • In this paper, the performance of the $CO_2-C_2H_6-N_2$ cascade liquefaction cycle with respect to temperature differences in the LNG heat exchangers is analyzed theoretically using HYSYS software and then compared the COP(coefficient of performance) of the cascade liquefaction cycles using $C_3H_8-C_2H_4-C_1H_4$ and $CO_2-N_2O-N_2$. In comparison of COP of three cycles, the cascade liquefaction cycles using $C_3H_8-C_2H_4-C_1H_4$ showed the highest COP. And the liquefaction cycle using $CO_2-C_2H_6-N_2$ and $CO_2-N_2O-N_2$ presented the second and third highest COP, respectively. In case of COP, the $C_3H_8-C_2H_4-C_1H_4$ cascade liquefaction cycle yields better COP. But, in terms of the environment and maintain, it is confirmed that the cascade liquefaction cycle using $CO_2-C_2H_6-N_2$ provides favorable characteristics.