• Bulletin of the Korean Mathematical Society
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• v.61 no.2
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• pp.401-419
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• 2024

Let K, H, K_II and H_II be the Gaussian curvature, the mean curvature, the second Gaussian curvature and the second mean curvature of a timelike tubular surface T_γ(α) with the radius γ along a timelike curve α(s) in Minkowski 3-space E³₁. We prove that T_γ(α) must be a (K, H)-Weingarten surface and a (K, H)-linear Weingarten surface. We also show that T_γ(α) is (X, Y)-Weingarten type if and only if its central curve is a circle or a helix, where (X, Y) ∈ {(K, K_II), (K, H_II), (H, K_II), (H, H_II), (K_II , H_II)}. Furthermore, we prove that there exist no timelike tubular surfaces of (X, Y)-linear Weingarten type, (X, Y, Z)-linear Weingarten type and (K, H, K_II, H_II)-linear Weingarten type along a timelike curve in E³₁, where (X, Y, Z) ∈ {(K, H, K_II), (K, H, H_II), (K, K_II, H_II), (H, K_II, H_II)}.

• Current Industrial and Technological Trends in Aerospace
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• v.4 no.2
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• pp.86-97
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• 2006

일본은 1954년 도쿄대학의 이도가와 교수가 로켓연구반을 구성하여 연구와 실험을 시작한 후 1955년 8월에 펜슬로켓을 제작하여 수평비행실험을 시작하였다. 이후 베이비 로켓, 카파 로켓, 람다 로켓으로 이어지는 개발과정에서 1970년 람다로켓인 L-4S-5 로켓으로 인공위성 ‘오수미’를 발사하는데 성공하여 자체 위성발사국의 지위를 얻었다. 그러면서 미국으로부터 발사체 기술을 받아 N-1 로켓을 개발하여 1975년에 성공적으로 발사하였다. 이후 자체적으로 기술개발에 성공한 H-I 로켓에 이어 일본의 기간 발사체가 된 H-II A 로켓에 이르기까지 일본은 우주발사체 개발을 지속적으로 꾸준히 발전시켜왔다. 본 논문에서는 일본의 기간 발사체가 된 H-II A 로켓 및 H-II B(H-II A 능력향상형 로켓)에 이르기까지 일본의 로켓 개발과정을 설명하고 또 H-II A 로켓이 어떻게 일본의 기간 로켓이 되었는지 또 H-II A 능력 향상형 로켓, H-II B 로켓의 향후 에 대하여 논의하고자 한다.

• Journal of the Korean Chemical Society
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• v.44 no.2
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• pp.127-137
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• 2000

Eleven new compounds that are composed of bis(p-substituted phenyl) terephthalate unitand the decyloxy pendant as lateral were synthesized and their thermal and liquid crystalline properties were studied by the differential scanning calorimetry (DSC) and on a hot-stage of a polarizing microscope. The ter-minal substituent groups of the compound were varied; X= -H(II-H), -F(lI-F), -CII(II-CI), -Br(ll-Br), -I(II-I), -$NO_2(lI-NO_2$), $-CF_3(II-CF_3$), -$OC_2H_5(II-OC_2H_5$), -$OC_4H_9(II-OC_4H_9$), -$C_6H_5(Il-C_6H_5$). The compounds of $II-OC_2H_5,\;II-OC_4H_9$ and $II-C_6H_5$ were monotropically nematic. In contrast, the compounds of Il-H, II-F, II-Cl, II-Br, II-I, $lI-NO_2$, $II-CF_3$, and II-CN did not show liquid crystalline properties.

• Journal of the Korean Chemical Society
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• v.18 no.3
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• pp.194-201
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• 1974

The tetradentate schiff base ligand, N,N'-bis(salicylaldehyde)-m-phenylenediimine has been prepared from salicylaldehyde and m-phenylenediamine by Duff-reaction. The schiff base ligand has been reacted with Cu(II), Ni(II), Co(II), and Zn(II) to form new complexes; Cu(II)$[C_{20}H_{14}O_2N_2]{\cdot}2H_2O, Ni(II)[C_{20}H_{14}O_2N_2]{\cdot}2H_2O, Co(III)[C_{20}H_{14}O_2N_2]{\cdot}2H_2O and Zn(II)2[C_{20}H_{14}O_2N_2]{\cdot}4H_2O$. It seems to be that the Cu(II), Ni(II) and Co(II) complexes have hexacoordinated configuration with the schiff base and two molecules of water, while Zn(II) complex has tetracoordinated configuration with the schiff base and four molecules of water. The mole ratio of tetradentate schiff base ligand to Cu(II), Ni(II) and Co(II) are 1:1 but to Zn(II) is 1:2. These complexes have been identified by visible spectra, infrared spectra, T.G.A. and elemental analysis.

• Journal of the Korean Chemical Society
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• v.24 no.2
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• pp.129-138
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• 1980

The formation constants of the mixed-ligand complexes in the Cd(II), Cu(II) and Pb(II)-Trien-OH system were studied by polarograph. The formation constant $(log{\beta}_{ij})$ was determined at $25^{\circ}C$ in the ionic strength of 0.1. It was also confirmed that the mixed ligand complexes in this system were formed above pH 10.2, 10.5 and 9.0 for Cu(II), Cd(II) and Pb(II) by the calculation of the distribution for complexes at the various pH. Masking of Cd(II) by conversion to anionic EDTA-complexes has been used to separate Cu(II) from Cd(II) through passage of a combined Trien-EDTA solution on an cationic resin column. The optimal condition for the separation of Cu(II) from Cd(II) is confirmed at the pH range above 9.0, not only by considering the theoretical equation of the conditional-exchange-constant of metal on the cation exchange resin,but also by calculating the distribution of the mixed ligand complexes in the resin at the various pH with computer. By analyzing the synthetic sample of Cu(II) and Cd(II) with a EDTA masking at pH 9.5, it is found that the results of the experiment are satisfied with the theoretical value.

• Journal of the Korean Chemical Society
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• v.31 no.6
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• pp.509-519
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• 1987

The tetradentate Schiff base ligand, 3,4-bis(salicylidene diimine) toluene, have been prepared by the reaction of salicylaldehyde with 3,4-diaminotoluene by Duff method. The Schiff base ligand reacts with Ni(II), Co(II), and Cu(II) ions to form new complexes, [Ni(o-BSDT)${\cdot}(H_2O)_2$], [Co(o-BSDT)${\cdot}(H_2O)$], and [Cu(o-BSDT)]. It seems that Ni(II) and Ni(II) complexes are hexacoordinated with the Schiff base ligand and two molecules of water, while the Cu(II) complexes are tetracoordinated with the Schiff base. The mole ratio of tetradentate Schiff base ligand to metals was found to be 1 : 1. The redox chemistry of these complexes was investigated by polarography and cyclic voltammetry with glassy carbon electrode in DMSO with 0.1M TEAP${\cdot}$[Ni(o-BSDT)${\cdot}(H_2O)_2$] hav EC reaction mechanisms which undergo a irreversible electron transfer followed by a fast chemical reaction. [Co(o-BSDT)${\cdot}(H_2O)_2$] undergoes a reduction of Co(II) to Co(I) and a oxidation of Co(II) to Co(III), and [Cu(o-BSDT)] undergoes a reduction of Cu(II) to Cu(I).

• Honam Mathematical Journal
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• v.38 no.3
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• pp.593-611
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• 2016

This paper is concerned with the classifications of quadric surfaces of first and second kinds in Euclidean 3-space satisfying the Jacobi condition with respect to their curvatures, the Gaussian curvature K, the mean curvature H, second mean curvature $H_{II}$ and second Gaussian curvature $K_{II}$. Also, we study the zero and non-zero constant curvatures of these surfaces. Furthermore, we investigated the (A, B)-Weingarten, (A, B)-linear Weingarten as well as some special ($C^2$, K) and $(C^2,\;K{\sqrt{K}})$-nonlinear Weingarten quadric surfaces in $E^3$, where $A{\neq}B$, A, $B{\in}{K,H,H_{II},K_{II}}$ and $C{\in}{H,H_{II},K_{II}}$. Finally, some important new lemmas are presented.

• Analytical Science and Technology
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• v.10 no.5
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• pp.370-377
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• 1997

The several fundamental parameters on the solvent extraction of Co(II), Cu(II) and Zn(II) with dithizone were investigated. The value of $K_{a1}/K_p$ of dithizone(at $25^{\circ}C$) between an aqueous phase and a chloroform was found to be $4.72{\times}10^{-11}$. And the mole ratios of metal ion to dithizone in its metal complexes were determined by mole ratio method. The extractibilities(%) for metal-dithizone chelates were obtained from the extraction equilibria of metal-dithizone complexes between an aqueous phase and a chloroform as follows. Co(II) : 92.3% at pH 8.0 : Cu(II) : 97.1% at pH 4.0 and Zn(II) : 99.0% at pH 7.0. And also, in optimum experimental conditions the extraction constants of Co(II), Cu(II) and Zn(II) were examined.

• Journal of the Korean Chemical Society
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• v.55 no.3
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• pp.418-429
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• 2011

Novel chromium(III), manganese(II), iron(III), cobalt(II), nickel(II), copper(II), ruthenium(III), and zirconyl(II) complexes of $N^1,N^2$-bis(3-((3-hydroxynaphthalen-2-yl)methylene-amino)propyl)phthalamide ($H_4L$, 1) have been synthesized and characterized by elemental, physical, and spectral analyses. The spectral data showed that the ligand behaves as either neutral tridentate ligand as in complexes 2-5 with the general formula $[H_4LMX_2(H_2O)]{\cdot}nH_2O$ (M=Cu(II), Ni(II), Co(II), X = Cl or $NO_3$), neutral hexadentate ligand as in complexes 10-12 with the general formula $[H_4LM_2Cl_6]{\cdot}nH_2O$ (M=Fe(III), Cr(III) or Ru(III)), or dibasic hexadentate ligand as in complexes 6-9 with the general formula $[H_2LM_2Cl_2(H_2O)_4]{\cdot}nH_2O$ (M = Cu(II), Ni(II), Co(II) or Mn(II), and 13 with general formula $[H_4L(ZrO)_2Cl_2]{\cdot}8H_2O$. Molar conductance in DMF solution indicated the non-ionic nature of the complexes. The ESR spectra of solid copper(II) complexes 2, 5, and 6 showed $g_{\parallel}$ >g> $g_e$, indicating distorted octahedral structure and the presence of the unpaired electron in the $N^1,N^2$ orbital with significant covalent bond character. For the dimeric copper(II) complex $[H_2LCu_2Cl_2(H_2O)_4]{\cdot}3H_2O$ (6), the distance between the two copper centers was calculated using field zero splitting parameter for the parallel component that was estimated from the ESR spectrum. The antibacterial and antifungal activities of the compounds showed that, some of metal complexes exhibited a greater inhibitory effect than standard drug as tetracycline (bacteria) and Amphotricene B (fungi).

• Korean Chemical Engineering Research
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• v.58 no.2
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• pp.301-306
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• 2020

We investigated the individual biosorption removal of lead, copper, and nickel ions from aqueous solutions using Chara sp. algae powder in a batch mode. The impact of several parameters, such as initial concentration of the metal ions, contacting time, sorbent dose, and pH on the removal efficiency, was investigated. The maximum removal efficiency at optimum conditions was found to be 98% for Pb(II) at pH = 4, 90% for Cu(II) at pH = 5, and 80% for Ni(II) at pH = 5. The isotherm study was done under the optimum conditions for each metal by applying the experimental results onto the well-known Freundlich and Langmuir models. The results show that the Langmuir is better in describing the isotherm adsorption of Pb(II) and Ni(II), while the Freundlich is a better fit in the case of Cu(II). Similarly, a kinetic study was performed by using the pseudo-first and second-order equations. Our results show that the pseudo-second-order is better in representing the kinetic adsorption of the three metal ions.