• Economic and Environmental Geology
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• v.33 no.5
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• pp.391-404
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• 2000

This study investigated the geochemical characteristics of mine drainage discharged from an abandoned coal mine in the Hwasoon area. Surface water samples were collected from 23 locations along the Hancheon creek. The concentration of Zn and Cu in stream waters was highest at low pH (3.53), whereas the content of TDS and TDI was highest at high pH (7.78) due to the concentration of Ca, $HCO_3$ and $SO_4$. At the upstream site, the Ba, Fe, Mn, Zn, and $SO_4$ contents were relatively high but decreased significantly with the distance from the coal mine. On the contrary, the Na and $NO_3$ contents were low at the upstream site but increased downstream. Yellow precipitate material collected in the Hancheon consisted mainly of iron and LOI. This yellow precipitate was heated from 100 to $900^{\circ}C$ for 1 hour. With increasing temperature, the intensity of hematite peaks were sharply produced in X-ray pattern and the absorption band Fe-O of hematite increased in IR due to dehydration and melting. The yellow to brown precipitate and evaporite materials were collected by a air-dry from the acid mine water at the laboratory. After drying, the concentration of ions in the acid water samples increased progressively in oversaturation with respect to either gypsum, ferrohexahydrite or quenstedetite. The X-ray powder diffraction studies identified that the precipitated and evaporated materials after drying were well crystallized gypsum, ferrohexahydrite and quenstedetite. Diagnostic peaks used for identification of gypsum were the 7.65, 4.28, 3.03, 2.87 and 2.48$\AA$ peaks and those for ferrohexahydrite were the 5.46, 5.12, 4.89, 4.44, 4.05, 3.62, 3.46, 3.40, 3.20, 3.03, 2.94, 2.53, 2.28, 2.07, 1.88 and 1.86${\AA} peaks. The IR spectra with OH-stretching, deformation of $H_2O$and ${SO_4}^{2-}$stretching vibration include the existence of gypsum, ferrohexahydrite and quenstedetite in the precipitated and evaporite materials. In the SEM and EDS analysis for the evaporite material, gypsum with well-crystallized, acicular, and columnar form was distinctly observed.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.2
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• pp.185-191
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• 2017

The objective of this paper is to investigate the effect of waste refractory powder(WRP) and desulfurization gypsum(FGD) as activators on the flow properties and the strength development of high volume blast furnace slag mortar incorporating illite(BSM) having adsorption and deodorization. To fabricate the BSMs with 60% of W/B, blast furnace slag are incorporated with 45% and 65%, respectively. WRP and FGD are substituted from 5 to 10%. Test results indicate that the flow is decreased with increase of WRP and FGD, while increase of WRP and FGD enhance the compressive strength due to accelerated reaction of blast furnace slag, The use of illite results in a decrease of compressive strength. pH has increasing tendency until 7days, while it has reduction. In this paper, optimal dosages of WRP and FGD are believed to be around 5% each.

• KIEAE Journal
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• v.6 no.1
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• pp.11-16
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• 2006

This paper deals with the experimental for manufacturing the lightweight buildng materials with portland cement, fly ash, slag, lime, gypsum, and aluminum powder system. Aluminum powder was added an aerating agent. Specific gravity range of lightweight concrete specimens were 0.6~0.9g/cm3. These specimens properties studied by means of specific gravity, compressive strength, absorption coefficient, transmission loss and scanning electron microscopy. Cellular concrete with maximum compressive strength was 41kgf/cm2 by obtained Al=0.05wt.%. Moreover, the aeration lightweight concrete showed excellent sound absorption properties.

• Journal of the Korea Institute of Building Construction
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• v.2 no.3
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• pp.163-170
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• 2002

Recently, polishing tile(porcelain homogeneous polished tile) was used in the construction field as a finishing material. But, there happened some problems such as tile exfoliation by construction condition in early ages. Also, for use of polishing tile in the dry wall system which used to lightweight wall, the examination of adhesive stability of polishing tile is needed. In this study, adhesive strength of Polishing tile was investigated by tile bond types on gypsum board and non asbestos board coated by tar-urethane and Polymer modified cementitious waterproofing membrane(Series I). Then, the effect of heat stress and vibration was estimated on gypsum and non asbestos board(Series II). As the result of study are the follows; (1) Polishing tile(600$\times$400mm) construction on waterproofing layer : Both laboratory estimation and spot examination sieve were happened that fall of tile because their hardening speed is late. (2) To using powder style adhesives in the dry wail with waterproofing layer : Adhesive strength of tile is Influenced by interface bond area and base side condition. (3) Shock and heat stresses : obvious decline of adhesive strength is not happened

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.2
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• pp.157-164
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• 2016

In this research, based on the condition of using desulfurization gypsum(FGD) as a stimulator for high-volume blast furnace slag cement mortar, sieving and heating process methods of removing activated carbon in FGD were compared with the non-processed FGD and recycled and natural fine aggregates were compared for suitable aggregate to be used. According to the result of experiment, sieving with 0.3mm was more efficient than $500^{\circ}C$ heating for processing the FGD, and recycled fine aggregate showed more favorable result than natural fine aggregate at the FGD content was 5 to 10%. On the other hand, the mortar mixture including recycled fine aggregate had a high drying shrinkage, and absorption ratio, and thus specific limitations on applying recycled fine aggregate should be required.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.4
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• pp.395-403
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• 2020

CaO-based by-product, which consist of CaO, SO3, Al2O3 and so on, has being used to raw materials of CaO compound. When It was applied to recycling water of remicon, concrete performance can be enhanced because hydration reaction of powder material is accelerated. In this study, activated-sludge, which was putted desulfurization gypsum of CaO-based in recycling water, was manufactured to verify effect of them, and then they was investigated by characteristics of redy-mixde concrete. As a result of concrete tests, it was confirmed that there is no problem of strength or drying shrinkage while ensuring workability. Therefore, the possibility of specific application using activated sludge was confirmed.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.25-31
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• 2023

In this study, the basic properties of CO₂ immobilized desulfurized gypsum (CFBG) and the possibility of being used as a stimulus for slag cement were reviewed, and performance evaluation was conducted through a concrete mixing test. The main components of CFBG were CaO and SO₃, and CaO and SO₃ increased as the drying temperature increased. The moisture content of undried CFBG was 15.7 %, the drying temperature was 1.7 % and the drying temperature was 0.03 % at 105 ℃. Mortar using CFBG tended to have a lower flow value as the drying temperature increased, and the compressive strength was equivalent to that of the FGB use mixture. As a result of the concrete experiment using CFBG SC, both slump and air volume satisfied the target range after 60 minutes, and the compressive strength tended to increase overall compared to the ternary binder mixture.

• The Journal of Korean Academy of Prosthodontics
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• v.39 no.2
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• pp.220-229
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• 2001

This study was performed to evaluate the fracture resistance of three improved die stone materials according to water/powder ratio. There are lots of handling conditions which affect the physical properties of improved dental stone, and it's well known that the water/powder ratio significantly affect the strength of die stone. If water/power ratio was incorrect, following disadvantages were showed : (1) susceptibility to dimensional change due to abrasion, (2) limited reproduction of fine detail, (3) lack of strength. The maxillary master casts were made of additional silicone impressions(Exaflex, GC America. Inc. USA). Three type IV die stones such as Fuji Rock (GC Europe Intreleuvenlaan, Leuven, Belgium), Velmix(Kerr, Manufacturing company, USA), and Crytal Rock( Maruishi Gypsum Co. Ltd, Japan) were tested. A total of 160 casts were prepared, separated, and tested on the Instron Testing Machine(Model 4201, Co. USA). The obtained results of this study were as follows : 1. Fuji Reck and Velmix less 3ml than the water/power ratio of manufacturer's instruction showed the highest resistance to fracture. According to increasing water/powder ratio, fracture resistance was significantly increased(P<0.05). Crystal Rock showed the highest fracture value when it was mixed with the water/power ratio of manufacturer's instruction. 2. Water/powder ratio of the manufacturer's instructions and less 3ml than that showed lower fracture value of hand mix than that of vacuum mix. Water/powder ratio of more 3ml, 6ml than manufacturer's instructions was not significantly different between hand mix and vacuum mix(p>0.05). 3. Velmix had the highest viscoelastic value among three die materials when it was mixed with the manufacturer's instruction. Viscoelasticity was decreased according to increasing water/powder ratio.

• Journal of the Korea Concrete Institute
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• v.29 no.4
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• pp.399-406
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• 2017

CaO-based by-product, which consist of CaO, $SO_3$, $Al_2O_3$ and so on, has being used to raw materials of CaO compound. When It was applied to recycling water of remicon, concrete performance can be enhanced because hydration reaction of powder material is accelerated. In this study, activated-sludge, which was putted desulfurization gypsum of CaO-based in recycling water, was manufactured to verify effect of them, and then they was investigated by characteristics of cement matrix and mortar. As a results, they indicated reduction of setting time and high soundness in cement matrix, and acceleration of hydration reaction can be verified by XRD analysis. Also, it can be maintained good workability if water content by usage of desulfurization gypsum, which used for production of activated-sludge, was adjusted. In addition, it can be verified strength development by activated-sludge although cement content by usage of desulfurization gypsum was reduced.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2015.11a
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• pp.55-56
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• 2015

In this research the processing method of Desulfurized Plaster is changed to cyclotomy, 0.3mm sieve analysis and 500℃ heat exposure, and by changing the mix rate of the binding agent to 0~20%, it was applied to mortar that used natural aggregate and blast furnace slag for testing. The test results showed that the sieve analysis and high heat exposure of the flow and air volume increased according to the increase of mixing rate of FGD while the cyclotomy decreased. The setting time accelerated as the mixing rate of FGD increased, and the compression strength increased to its maximum when the mixing rate of FGD was right around 10%, and especially showed a high trend with cyclotomy and sieve analysis.