• Title/Summary/Keyword: Growth phase

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Phase change properties of BN doped GeSbTe films

  • Jang, Mun-Hyeong;Park, Seong-Jin;Park, Seung-Jong;Jeong, Gwang-Sik;Jo, Man-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.226-226
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    • 2010
  • Boron Nitride (BN) doped GeSbTe films were grown by the ion beam sputtering deposition (IBSD). The in-situ sheet resistance data and the x-ray diffraction patterns showed the crystallization is suppressed due to the BN incorporation. The phase change speed in BN doped GeSbTe films were investigated using the static tester equipped with nanosecond pulsed laser. The phase change speed for BN doped GST films become faster than the corresponding values for an undoped GST film. The Johnson-Mehl-Avrami(JMA) plot and Avrami coefficient for laser crystallization showed that the change in growth mode during the laser crystallization is a most important factor for the phase change speed in the BN doped GST films. The JMA results and the atomic force microscopy (AFM) images indicate that the origin of the change in the crystalline growth mode is due to an increase in the number of initial nucleation sites which is produced by the incorporated BN. In addition, the retension properties for the laser writing/erasing are remarkably improved in BN doped GeSbTe films owing to the stability of the incorporated BN.

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Superconducting Characteristics of Bi Thin Film by Co-Deposition (동시 스퍼터 법에 의한 Bi 박막의 초전도 특성)

  • Lee, Hee-Kab;Park, Yong-Pil;Lee, Joon-Ung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.278-280
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    • 2001
  • BSCCO thin films have been fabricated by co-deposition at an ultralow growth rate using ion beam sputtering(IBS) method. The growth rates of the films was set in the region from 0.17 to 0.27 nm/min. MgO(100) was used as a substrate. In order to appreciate stable existing region of Bi 2212 phase with temperature and ozone pressure, the substrate temperature was varied between 655 and $820^{\circ}C$ and the highly condensed ozone gas pressure($PO_3$) in vacuum chamber was varied between $2.0{\times}10^{-6}$ and $2.3{\times}10^{-5}$ Torr. Bi 2212 phase appeared in the temperature range of 750 and $795^{\circ}C$ and single phase of Bi 2201 existed in the lower region than $785^{\circ}C$. Whereas, $PO_3$ dependance on structural formation was scarcely observed regardless of the pressure variation. And high quality of c-axis oriented Bi 2212 thin film with $T_c$(onset) of about 90 K and $T_c$(zero) of about 45 K is obtained. Only a small amount of CuO in some films was observed as impurity, and no impurity phase such as $CaCuO_2$ was observed in all of the obtained films.

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The Effect of Y Addition on the Microstructure and Mechanical Property of Rapidly Solidified AZ91 Alloy (급속응고한 AZ91합금의 미세조직 및 기계적 특성에 미치는 Y첨가의 영향)

  • Choi, Jae-Young;Park, Hoon-Mo;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.20 no.6
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    • pp.386-394
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    • 2000
  • In the present study, the effect of yttrium addition on the microstructure and mechanical property of rapidly solidified AZ91 alloy by melt spinning process is estimated. As yttrium was added, the microstructure of RS ribbons and extrudates became finer than those of AZ91, and RE related phases $(Al_2RE)$ were formed. In the case of the addition of 3wt%Y, the microstructure of extrude showed the finest grain size. At room temperature, the AZ91 + 3wt%Y alloy showed the highest tensile strength, 352 MPA due to precipitation of ${\beta}(Mg_{17}Al_{12})$ phase and $Al_2RE$ phase. At the elevated temperature, the mechanical property of AZ91 + 3wt%Y alloy was higher than those of other Mg alloys. The reasons were that $Al_2Y$ compound was thermally stable and suppressed the grain growth. In contrast with $Al_2Y$ compounds, ${\beta}$ phase was thermally unstable and could not suppress the grain growth at the elevated temperature. Therefore, $Al_2Y$ phase contributed to improve the thermal stability of RS AZ91 alloy.

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Effect of Air Additions on the Growth Characteristics of the Compound Layer during Oxynitriding in50%NH3+Air+N2 Atmosphere (50% NH3-Air-N2가스분위기에서 Oxynitriding시 Compound Layer의 성장 특성에 미치는 공기첨가효과)

  • Kim, Y.H.;Lee, Y.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.3
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    • pp.206-218
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    • 1994
  • In 50%$NH_3+Air+N_2$ atmospheres, the effect of air additions on the growth characteristics of the compound layer during oxynitriding at $570^{\circ}C$ for 2hr in carbon and alloy steels has been investigated. The ammount of apparent residual ammonia during oxynitriding has shown to be increased with air additions(9~36 Vol. %) and X-ray diffraction analysis of case oxynitreded has shown that the compound layer consist of ${\varepsilon}-Fe_{2-3}$(N, C) phase and ${\gamma}^{\prime}-Fe_4$(N,C) phase. In the case of carbon steels, the thickness of oxide layer, compound layer and porous layer and the amount of ${\varepsilon}-Fe_{2-3}$(N,C) phase in the compound layer were increased with additions of air in 50%$NH_3+N_2$ atmospheres. At the same gas composition, the thickenss of oxide layer, compound layer and porous layer in alloy steels showed slightly thin layer thickness compared to those of carbon steels and the ${\gamma}^{\prime}-Fe_4$(N,C) phase in the compound layer of alloy steels was found barely. Therefore, the most obvious effect of air addition in the gas nitriding atmosphere has been found to in crease further kinetics of nitriding reaction.

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Superconducting Characteristics of Bi Thin Film by Co-deposition (동시 스퍼터 법에 의한 Bi 박막의 초전도 특성)

  • 이희갑;박용필;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.278-280
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    • 2001
  • BSCCO thin films have been fabricated by co-deposition at an ultralow growth rate using ion beam sputtering(IBS) method. The growth rates of the films was set in the region from 0.17 to 0.27 nm/min. MgO(100) was used as a substrate. In order to appreciate stable existing region of Bi 2212 Phase with temperature and ozone pressure, the substrate temperature was varied between 655 and 820$^{\circ}C$ and the highly condensed ozone gas pressure(PO$_3$) in vacuum chamber was varied between 2.0x10$\^$-6/ and 2.3x10$\^$-5/ Torr. Bi 2212 Phase appeared in the temperature range of 750 and 795$^{\circ}C$ and single phase of Bi 2201 existed in the lower region than 785$^{\circ}C$. Whereas, PO$_3$ dependance on structural formation was scarcely observed regardless of the pressure variation. And high quality of c-axis oriented Bi 2212 thin film with T$\sub$c/(onset) of about 70 K and T$\sub$c/(zero) of about 45 K is obtained. Only a small amount of CuO in some films was observed as impurity, and no impurity phase such as CaCuO$_2$ was observed in all of the obtained films.

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Study on Solvent Mediated Phase Transformation Kinetics of Hexanitrohexaazaisowurtzitane(HNIW) (용매를 매체로 한 Hexanitrohexaazaisowurtzitane(HNIW)의 상전이 속도에 관한 연구)

  • 김준형;임유진
    • Journal of the Korean Society of Propulsion Engineers
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    • v.4 no.4
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    • pp.9-17
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    • 2000
  • The crystal growth and dissolution rates were calculated by solving a model equation, which involved the dissolution of the metastable phase($\beta$-HNIW) and growth of the stable phase($\varepsilon$-HNIW), together with the mass balance equation. The model has been successfully used to simulate available kinetic data for the $\beta$$\longrightarrow$$\varepsilon$ polymorphic transformation via a solution phase. From the effectiveness factor based on the two-step model, it was found that the surface integration contribution to the process was comparatively small, and a diffusion dependency decreased with an increase of the mass fraction of chloroform in the mixed solvents of ethyl acetate and chloroform. Appling these kinetics in process simulation allowed for the prediction of the product size of $\varepsilon$-HNIW.

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AN ASSESSMENT SYSTEM OF ECO-FRIENDLINESS OF CONSTRUCTED FACILITY IN THE DESIGN PHASE USING VALUE ENGINEERING

  • Byung-Soo, Kim;Dong-Eun, Lee;Suk-Hyun, Kwon;Min-Kwon, Choe
    • International conference on construction engineering and project management
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    • 2009.05a
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    • pp.1625-1629
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    • 2009
  • The new paradigm called 'Low Carbon Green Growth' involved in reducing greenhouse gas is on the rise as a critical issue worldwide. The essential of Kyoto protocol issued in 1997 is to achieve the sustainable economic growth environments by converting existing production system to eco-friendly one. The protocol imposes the liability to reduce greenhouse gas to the countries joined to it. The paradigm is directly involved in the energy consumption and environmental pollution caused by construction activities. Value Engineering which are mainly applied in the design phase in practice is a measure to improve the value of a constructed facility by analyzing and/or appraising the functions and costs of it. However, an appropriate method which assesses eco-friendliness of constructed facility has not been propose by researchers. This paper proposes a method which assesses the performance involved in eco-friendliness of constructed facility using Value Engineering (VE) in the design phase. The method estimates the environmental cost relative to the amounts of energy consumption and environmental pollution occurred over the entire project life cycle. The database called "Life Cycle Inventory DB", which stores information about the amounts of environmental pollution, is used. The algorithm which retrieves the amounts of environmental pollutions from the DB and converts them into environmental costs is developed. The algorithm is implemented into a system which quantifies the eco-friendliness of constructed facility in the design phase using VE.

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Phase-Field Modelling of Zinc Dendrite Growth in ZnAlMg Coatings

  • Mikel Bengoetxea Aristondo;Kais Ammar;Samuel Forest;Vincent Maurel;Houssem Eddine Chaieb;Jean-Michel Mataigne
    • Corrosion Science and Technology
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    • v.23 no.2
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    • pp.93-103
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    • 2024
  • In the present work, a phase-field model for dendritic solidification is applied to hot-dip ZnAlMg coatings to elucidate the morphology of zinc dendrites and the solute segregation leading to the formation of eutectics. These aspects define the microstructure that conditions the corrosion resistance and the mechanical behaviour of the coating. Along with modelling phase transformation and solute diffusion, the implemented model is partially coupled with the tracking of crystal orientation in solid grains, thus allowing the effects of surface tension anisotropy to be considered in multi-dendrite simulations. For this purpose, the composition of a hot-dip ZnAlMg coating is assimilated to a dilute pseudo-binary system. 1D and 2D simulations of isothermal solidification are performed in a finite element solver by introducing nuclei as initial conditions. The results are qualitatively consistent with existing analytical solutions for growth velocity and concentration profiles, but the spatial domain of the simulations is limited by the required mesh refinement.

Growth, Behavior, and Carcass Traits of Fattening Hanwoo (Korean Native Cattle) Steers Managed in Different Group Sizes

  • Lia, S.G.;Yang, Y.X.;Rhee, Y.J.;Jang, W.J.;Ha, J.J.;Lee, S.K.;Song, Y.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.7
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    • pp.952-959
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    • 2010
  • This study was conducted to evaluate growth, behavior and carcass traits of fattening Hanwoo (Korean native cattle) steers managed in different group sizes. A total of 48 animals, 6 months of age, were allocated to one of three group sizes and the experiment was conducted from 12 to 30 months of age. Groups were balanced for weight and the group sizes consisted of 4, 8, or 12 steers which were named 4sG, 8sG and 12sG, respectively. When animals were 12 months of age, initial fasted body weight (BW, $304.51{\pm}12.40\;kg$) was measured. All animals were housed at a constant space allowance of $8.82\;m^2$ per animal, and a feeder and drinker were provided per 4 animals. The whole fattening stage was divided into three phases: phase I (from 12 to 18 month of age), phase II (from 19 to 24 month of age), and phase III (from 25 to 30 month of age). Steers managed in 12sG showed low (p<0.05) growth rate and feed conversion rate (FCR) in phase I and phase II when compared to other treatment groups. However, this difference was not observed for the whole fattening phase (p>0.05). Steers managed in 4sG had a thick (p<0.05) ultrasound back fat thickness at 15 and 18 months of age. However, group size had no effect on meat yield and quality traits of area and marbling score. Animals managed in 8sG yielded a better meat grade of "A" than the "B" grade in other treatment group sizes. Lean color, fat color, firmness and maturity scores did not differ among group sizes. Hanwoo steers housed under 12sG spent less time on eating concentrate, relevant higher eating rate, less frequency of allogrooming, and more time on walking (p<0.05). It could be concluded that a large group size retarded growth rate and back fat thickness in the fattening stage, which was mainly focused on 15 and 18 months of age.

Optimal Cultur Conditions for the Production of Insecticidal Toxin by Xenorhabdus nematophilus Isolated from Steinernema carpocapsae (Steinernema carpocapsae로부터 분리된 Xenorhabdus nematophilus에 의한 살충물질 생산을 위한 최적 배양조건)

  • 유연수;박선호
    • KSBB Journal
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    • v.15 no.1
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    • pp.100-105
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    • 2000
  • Optimal medium composition, culture conditions, characteristics of phase variation and activity of insecticidal toxin by Xenorhabdus nematophilus isolated and identified from Korean entomopathogenic nematode Steinernema carpocapsae were examined. Optimal medium composition of this strain was 50-70 g/L yeast extract, 3 g/L $K_{2}HPO_{4}$, 1g/L $NH_{4}H_{2}PO_{4}$, 2g/L ${MgSO}_4$$\cdot$${7H}_{2}O$, 10g/L NaCl and, these, yeast extract was found as a limiting nutrient for cell growth. When Monod equation was applied, maxmum specific growth rate and Monod constant were estimated as 0.13 $hr^{-1}$ and 20g/L, respectively. The pH of culture medium increased up to 8.5-9.5 regardless of initial pH 6-7 as the cells continued to grow. The specific growth rate in a 7 L fermentor was 0.18 $hr^{-1}$, which was enhancement 1.4 fold compared to a flask culture. In case of phase variation, phase I fraction was maintained above 90% at the stationary phase for both flask and fermentor cultures. According to oral toxicity test of Gallena mellonella by Xenorhabdus nematophilus, the addition of cell pellets into feed inhibited normal growth of insect larvae and killed completely then after 20 days cultivation. When culture supernatant of this strain was injected into hemolymph of insect larva, the toxicity was strongest at 24hr cultivation in the early exponential phase and gradually decreased as the culture time proceeded.

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