• Journal of Korean Society on Water Environment
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• v.26 no.5
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• pp.747-753
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• 2010

A series of experiments with a laboratory scale ultrasound treatment system for MTBE polluted groundwater was performed to increase the efficiency of MTBE degradation in groundwater. This study evaluated several factors to increase the efficiency of MTBE treatment for artificial and natural groundwater. The treated volume of groundwater, ultrasound frequency and power, and pollutant concentrations have been changed to evaluate its effects on the degradation efficiency of MTBE in batch and continuous flow reactor. For the specific experimental conditions on this paper, MTBE degradations are more efficient at 580 kHz than those at 1 MHz. The efficiency of MTBE degradation is proportional to the intensity of ultrasound power per unit volume of MTBE polluted groundwater. The concentration of ions in groundwater does not much affect the efficiency of MTBE degradation. The $1^{st}$ order degradation constant of MTBE for different power per unit volume at 580 kHz shows linear relationship at same concentration. The $1^{st}$ order degradation constant for 0.1 mM MTBE solution is higher than that for 1 mM MTBE solution. These experimental results could be helpful to seek optimal conditions for relatively large volume of polluted groundwater treatment.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.128-131
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• 2001

We evaluated natural attenuation of petroleum hydrocarbons in a shallow aquifer using a modeling study. The studied shallow aquifer was severely contaminated with petroleum hydrocarbons, especially toluene, ethylbenzene and xylenes (i.e, TEX). The exact spill history was not known. Therefor we used a contaminant level in May 1999 (the first sampling date of our integrated study) as an initial contaminant concentration. we calibrated required transport parameters using the contamination levels obtained from groundwater analyses in September of 1999. For fate and transport of the petroleum contaminants, five case 2 with sorption and degradation. case 3 with sorption and degradation (half decay constant compared with case 2), case 4 with degradation but no sorption, and case 5 with sorption but no degradation. For sorption and degradation, a linear sorption isotherm and first order irreversible decay was assumed, respectively and no additional contamination source to groundwater is also assumed.

• Journal of Environmental Health Sciences
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• v.20 no.1
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• pp.68-74
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• 1994

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.358-361
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• 2004

The photocatalytic degradation of Endocrine Discruptors, dibuthyl phthalate(DBP) has been investigated over TiO$_2$ photocatalysts irradiated with a ultraviolet (UV) light. The effect of operational parameters, i.e., reaction time, light intensity, pH and additive on the degradation rate of aqueous solution of Endocrine Discruptors has been examined. Results show that the employment of efficient photocatalysts and the selection of optimal operational parameters may lead to degradation of Endocrine Discruptors solutions.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1999.10a
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• pp.19-22
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• 1999

A microbial consortium derived from a gasoline-contaminated sites was enriched on toluene in 100-mL serum bottle and was found to degrade benzene(B), toluene(T), ethylbenzene(EB), and xylenes(X). Studies conducted to determine the temperature effects and BTEX concentration on BTEX degradation. The results indicated that lowering temperature significantly decreased BTEX degradation rates and varing the BTEX concentration also changed substrate degradation patterns.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.364-367
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• 2003

In this paper, we have examined the MTBE cometabolic degradation by pure culture, which is isolated gasoline contaminated aquifer. Propane was more effectively utilized as a growth substrate to oxidize MTBE. Specific substrate degradation rate was Increased with increasing initial propane amount. Respiking propane was enhanced and continued MTBE degradation and TBA observation was supported MTBE degradation. The mass balance of MTBE and TBA indicated that MTBE was oxidized to TBA as well as further oxidation of TBA.

• Journal of Soil and Groundwater Environment
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• v.26 no.6
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• pp.186-195
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• 2021

In Korea, groundwater quality is monitored through National Groundwater Quality Monitoring Network (NGQMN) administered by Ministry of Environment. For a given contaminant, compliance to groundwater quality standards is assessed on a annual basis by monitoring the number of incidents that concentration exceeds the regulatory limit. However, this approach provides only a fractional information about groundwater quality degradation, and more crucial information such as location and severity of the contamination cannot be obtained. For better groundwater quality management on a watershed, a more spatially informative and intuitive method is required. This study presents two statistical methods to convert point-wise monitoring data into information on groundwater quality status of a watershed by using a proposed grading scale. The proposed grading system is based on readily available reference standards that classify the water quality into 4 grades. The methods were evaluated with NO₃^-, Cl^-, and total coliform data in Geum River basin. The analyses revealed that groundwater in most watersheds of Geum River basin is good for domestic or/and drinking with no treatment. But, there was notable quality degradation in Bunam seawall and So-oak downstream standard watersheds contaminated by NO₃^- and Cl^-, respectively.

• Journal of Soil and Groundwater Environment
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• v.20 no.2
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• pp.32-40
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• 2015

Laboratory column experiments were conducted to evaluate the feasibility of injectable apatite method for the sequestration of Sr-90 in groundwater. The columns were tested to evaluate the rate of citrate biodegradation, the amounts of apatite formed, and the treatability of strontium by the sediment and apatite. The results showed the decreases in citrate, calcium, and phosphate concentrations and the increases in alkalinity and citrate degradation products (acetate and formate) in the columns, suggesting that the citrate degradation and formation of calcium phosphate are occurring. Although the calcium and phosphate were not completely consumed within the columns, some amounts of apatite were formed and it showed an ability to treat strontium in groundwater. This study provides a fundamental understanding of reaction mechanisms for the injectable apatite sequestration method for Sr-90 removal.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.04a
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• pp.179-182
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• 2002

The objective of this study was to evaluate petroleum hydrocarbon degradation processes governing natural attenuation at tile contaminated site and accomplished through conducting on investigation of degradation rate, capacity, and mechanism of the monitored natural attenuation. The monitoring results of the three years indicated that the concentrations of DO, nitrate, and sulfate in the contaminated area were significantly lower than these in the none-contaminated area. The results also showed a higher ferrous iron concentration, a lower redox potential and a neutral pH in the contaminated groundwater, suggesting that biodegradation of TEX is the major on-going process in the contaminated area. However, reduction of TEX in the groundwater was not only biodegradation but also dilution and reaeration during infiltration of uncotaminated surface and groudwater.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.53-56
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• 2001

The degradation of tetrachloroethene (PCE) and trichloroethene (TCE) by vitamin B$_{12}$, an electron mediator was examined when zero valent metals (ZVMs) were used as built electron donors. Dechlorination of PCE and TCE by iron and zinc in the presence of vitamin B$_{12}$ showed that the zinc and vitamin B$_{12}$ combination greatly enhances the reaction rates for both PCE and TCE, but iron and vitamin B$_{12}$ result in an increase in reactivity only for PCE degradation, not for TCE degradation in comparing with meta]s only. This result indicates vitamin B$_{12}$(I) Is active towards both PCE and TCE degradation while vitamin B$_{12}$(II) is active towards both PCE. Calculated activation energies for the dechlorination of PCE in the presence of Vitamin B$_{12}$ showed that vitamin B$_{12}$ lowered the activation energy about 40-60 kJ/㏖ for the both metals.the both metals.