• Bulletin of the Korean Chemical Society
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• v.18 no.8
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• pp.865-868
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• 1997

Second-order rate constants have been measured spectrophotometrically for the reactions of p-nitrophenyl phenylacetate (1) and benzoate (2) with a series of alicyclic amines in H2O containing 20 mole % DMSO at 25.0 ℃. 1 appears to be more reactive than 2 toward all the amines studied, although phenylacetic acid is a weaker acid than benzoic acid. The higher reactivity of 1 can be attributed to resonance and/or steric effect, since the ground state of 2 can be stabilized by resonance and 1 would experience less steric hindrance due to the presence of CH2 group between phenyl and C=O group. The reactivity of the amines increases with increasing their basicity. The Bronsted-type plots for aminolysis of 1 and 2 show good linearity with βnuc values of 0.81 and 0.85, respectively, indicating that the TS structures of the aminolyses of 1 and 2 are similar. Besides, the linear Bronsted plots obtained in the present system clearly suggest that there is no mechanism change for the given series of the amines and the reactions of 1 and 2 proceed in a same mechanism.

• Tunnel and Underground Space
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• v.28 no.6
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• pp.596-608
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• 2018

As urban infrastructure is aging, the possibility of accidents due to the failures or breakdowns of infrastructure increases. Especially, aging underground infrastructures like sewer pipes, waterworks, and subway have a potential to cause an urban ground sink. Urban ground sink is defined just as a local and erratic collapse occurred by underground cavity due to soil erosion or soil loss, which is separated from a sinkhole in soluble bedrock such as limestone. The conventional measurements such as differential settlement gauge, inclinometer or earth pressure gauge have a shortcoming just to provide point measurements with short coverage. Therefore, these methods are not adequate for monitoring of an erratic subsidence caused by underground cavity due to soil erosion or soil loss which occurring at unspecified time and location. Therefore, an alternative technology is required to detect a change of underground physical condition in real time. In this study, the feasibility of a novel magnetic resonance based monitoring method is investigated through laboratory tests, where the changes of path loss (S21) were measured under various testing conditions: media including air, water, and soil, resonant frequency, impedance, and distances between transmitter (TX) and receiver (RX). Theoretically, the transfer characteristic of magnetic field is known to be independent of the density of the medium. However, the results of the test showed the meaningful differences in the path loss (S21) under the different conditions of medium. And it is found that the reflection coefficient showed the more distinct differences over the testing conditions than the path loss. In particular, input reflection coefficient (S11) is more distinguishable than output reflection coefficient (S22).

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.47 no.6
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• pp.43-50
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• 2010

In this paper, we analyzed radiated emission generated by the split power/ground plane structures in order to reduce EMI in system modules. The magnetic fields and electric fields were simulated and measured on the test boards under various conditions. In order to reduce radiated emission, we have to determine spacing and location of the split ground gap so that input signal frequency does not coincide with the resonance frequency of the split power/ground plane structure and the phase of reflection coefficient is close to $0^{\circ}$ at input signal frequency. Moreover, we found that inserting a stitching capacitor could reduce the radiated emission. Low magnitude of reflection coefficient and the phase close to $0^{\circ}$ are required to reduce radiated emission. It is necessary to properly decide value and location of a stitching capacitor to fulfil those requirements.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.19 no.7
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• pp.785-790
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• 2008

In this paper, a new balun is proposed. This proposed balun has a DGS(Defected Ground Structure) pattern on the ground plane. The transmission-line is transformed by microstrip-to-slotline transition. DGS pattern on the ground plane and transition of the lines can be easily made a property of the balun. Resonance frequency of the DGS leads to operating frequency of the balun. Also the transition produces $180^{\circ}$ out-of-phase between two output ports without additional transmission line. In this paper, a new balun with VPDGS(Vertically Periodic Defected Ground Structure) effectively lower the operating frequency. To validate the proposed design method, the new balun is designed, fabricated and measured at 2 GHz.

• Journal of Advanced Navigation Technology
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• v.24 no.6
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• pp.627-632
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• 2020

In this paper, we have studied a development of a humidity sensor using a microwave sensor based on a microstrip defected ground structure coated with polyvinyl alcohol. A high-sensitivity microwave sensor, which is sensitive to the changes in the permittivity of the material under test, is designed by adding an interdigital capacitor-shaped defected ground structure to the ground plane of a microstrip line. Polyvinyl alcohol, a polymer material whose permittivity varies depending on humidity, is coated with a thin thickness on the defected ground structure of the proposed microwave sensor, and the changes in the resonance frequency and magnitude of the transmission coefficient for the microwave sensor according to humidity are measured. When relative humidity increases from 40% to 80% in 10% increments at a temperature of 25 degrees using a temperature/humidity chamber, the resonant frequency of the transmission coefficient decreases from 1.475 GHz to 1.449 GHz, and the magnitude is increased from -32.90 dB to -25.67 dB.

• Bulletin of the Korean Chemical Society
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• v.24 no.8
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• pp.1075-1080
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• 2003

We have investigated femtosecond coherent vibrational motions of Zn(II)-5,15-diphenylporphyrin in toluene using chirp-controlled ultrashort pulses. The oscillatory features superimposed on the temporal profiles of the pump-probe transient absorption signal are affected by the chirping and energy of excitation pulses. Using chirp- and excitation energy-controlled femtosecond pulses, we are able to obtain information on the structural changes between the electronic ground and excited states based on a comparative analysis of the Fouriertransformed frequency-domain spectra retrieved from the oscillatory components with the ground state resonance Raman spectra and normal mode calculations.

• The Journal of Engineering Geology
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• v.11 no.1
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• pp.25-35
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• 2001

For the ground resrxmse analysis, both in-situ and laboratory testing techniques such as downhole, SASW, resonant column and torsional shear tests were perlormed for Hong-Seong area. The grOlmd upper 30m is classified as SD since it has an average shear wave velocity as 209m/s. The response specLrums obtained by site-specific analyses generally satisfied the seismic code, but near the resonance period the motion was evaluated to be higher than the code.

• Journal of electromagnetic engineering and science
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• v.2 no.2
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• pp.68-74
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• 2002

In this paper, a pre-layout design approach for high-speed microprocessor is proposed. For multilayer PCB stark up configuration as well as selection and placement of decoupling capacitors, an effective solution for reducing SSN and EMI is obtained by modeling and simulation of complete power distribution system. The system model includes VRM, decoupling capacitors, multiple power and ground planes for core voltage, vias, as well as microprocessor. Finally, the simulation results are verified by measurements data.

• ETRI Journal
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• v.32 no.4
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• pp.610-613
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• 2010

This letter presents the design of a novel multiband USB dongle antenna with a compact ground plane. The radiating patch is composed of a modified meander-line monopole and a shorted loop to generate a dual-broadband resonance. The proposed antenna supports WiBro, Bluetooth, WLAN, WiMAX, and S-DMB services. The total dimensions of the fabricated antenna are 10 mm ${\times}$ 45 mm ${\times}$ 1 mm, the most compact size among multiband USB dongle antennas reported to date. The measured 10 dB reflection loss bandwidths are 20.8% (2.24 GHz to 2.76 GHz) and 20.2% (4.86 GHz to 5.95 GHz). The measured peak gain is 2.97 dBi, and efficiency is higher than 58%. In addition, the radiation pattern approximates an omnidirectional pattern.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.1436-1437
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• 2008

In this work, we investigate the electrical and electromagnetic behaviors of the power-bus with a variety of shapes of aperture, on the signal integrity, using a rigorous methods(Modal or MoM) along with Modal analysis method.