• Bulletin of the Korean Chemical Society
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• v.32 no.6
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• pp.1907-1911
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• 2011

A kinetic study is reported for nucleophilic substitution reactions of 4-pyridyl X-substituted benzoates 7a-e with a series of alicyclic secondary amines in H2O. The Br${\o}$nsted-type plot for the reactions of 4-pyridyl benzoate 7c is linear with ${\beta}_{nuc}$ = 0.71. The corresponding reactions of 2-pyridyl benzoate 6, which is less reactive than 7c, resulted in also a linear Br${\o}$nsted-type plot with ${\beta}_{nuc}$ = 0.77. The fact that the more reactive 7c results in a smaller ${\beta}_{nuc}$ value appears to be in accord with the reactivity-selectivity principle. The aminolysis of 7c has been suggested to proceed through a stepwise mechanism in which breakdown of the intermediate is the rate-determining step (RDS). The Hammett plot for the reactions of 7a-e with piperidine consists of two intersecting straight lines, i.e., ${\rho}_X$ = 1.47 for substrates possessing an electron-donating group (EDG) and ${\rho}_X$ = 0.91 for those possessing an electron-withdrawing group (EWG). In contrast, the corresponding Yukawa-Tsuno plot exhibits excellent linear correlation with ${\rho}_X$ = 0.79 and r = 0.56. Thus, it has been concluded that the nonlinear Hammett plot is not due to a change in the RDS but is caused by stabilization of the ground state of the substrates possessing an EDG through resonance interaction between the EDG and the C=O bond of the substrates.

• Bulletin of the Korean Chemical Society
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• v.32 no.4
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• pp.1153-1157
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• 2011

A kinetic study is reported for aminolysis of S-4-nitrophenyl X-substituted thiobenzoates 3a-g in 80 mol % $H_2O$/20 mol % DMSO at $25.0{\pm}0.1^{\circ}C$. Thiol esters 3a-g are 7.8-47.6 fold more reactive than the corresponding oxygen esters (i.e., 4-nitrophenyl X-substituted benzoates 1a-g). Such reactivity order appears to be in accordance with the expectation that 4-nitrothiophenoxide in 3a-g is a better nucleofuge than 4-nitrophenoxide in 1a-g since the former is 2.64 pKa units less basic than the latter. Hammett plot for the reactions of 3a-g exhibit poor correlation coefficients ($R^2$ = 0.977-0.986) with negative deviation by substrates possessing an electrondonating group (EDG), while the Yukawa-Tsuno plots result in excellent linear correlation ($R^2$ = 0.995-0.997) with ${\rho}$ = 0.93-1.23 and r = 0.57-0.67, indicating that the negative deviation shown by substrates possessing an EDG is caused by ground-state stabilization through resonance interactions but not due to a change in ratedetermining step upon changing the nonleaving-group substituent X. The ${\rho}$ value increases as the incoming amine becomes more basic and more reactive, indicating that the RSP is not operative in the current reactions.

• The Journal of the Petrological Society of Korea
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• v.23 no.2
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• pp.119-138
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• 2014

There are various ways to monitor active volcanoes, such as the method of observing the activity of a volcano with the naked eye, the method of referring to the past eruptive history based on the historic records and the method of monitoring volcanoes by using observation equipment. The most basic method from the observation equipment-using methods to monitor volcanoes is seismic monitoring. In addition to this, the ways to monitor volcanoes are as follows: resonance observation which may be effective to remove artificial noises from the seismic activities that are recorded in the seismograph, ground deformation by using precision leveling, electronic distance measurement, tiltmeter, GPS, and InSAR observation method, volcanic gas monitoring, hydrologic and meteorological monitoring, and other geophysical monitoring methods. These monitoring methods can make volcanic activities effectively monitored, determine the behavior of magmas in magma chambers and help predict the future volcanic eruptions more accurately and early warning, thus, minimize and mitigate the damage of volcanic hazards.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.21 no.1
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• pp.1-7
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• 2017

In this paper, a design method for a compact stepped open slot antenna for an operation in the UWB band is studied. The proposed antenna is miniaturized by inserting L-shaped slots on the ground plane of the stepped open slot antenna through the creation of a resonance in the low frequency, and a strip director is appended to the antenna in order to increase the gain in the middle and high frequency regions. The effects of varying the length of the L-shaped slots, the distance between the director and the slot antenna, and the director length on input reflection coefficient and realized gain characteristics of the proposed antenna are analyzed. The optimized antenna with the size of $30mm{\times}30mm$ is fabricated on an FR4 substrate, and the experiment results show that the antenna has a frequency band of 3.02-11.04 GHz for a VSWR < 2, which assures the operation in the UWB band.

• Proceedings of KOSOMES biannual meeting
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• 2007.11a
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• pp.211-214
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• 2007

In this paper, we have designed microstrip antenna if 800[MHz] band It will be able to integrate TRS(Trunked Radio System), GSM(Global System for Mobile telecommunication) band including the CDMA(Code Division Multiple Access) band we designed repeater and a base station antenna which is possible at the ship and marine of safety. It is improves a narrow bandwidth problem of microstrip antenna. It had U-shaped feeding structure at a rectangular patch And ground or feeding structure used between dielectric constant(${\varepsilon}_T$ = 2.1), patch or feeding structure used between dielectric constant(${\varepsilon}_T$ =1). So it used a duplex resonance effect Designed frequency bandwith(V5WR 2:1) if the antenna showed good characteristic of $780[MHz]{\sim}1.83[GHz]$ to 2.61[GHz]. Also the E-plan and H-plan all profit 9.4[dBi] above, the 3[dB] beam width showed the characteristic over the E-plan and H-plan $60^{\circ}$ to be improved.

• Journal of Navigation and Port Research
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• v.38 no.6
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• pp.623-627
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• 2014

In recent years, wireless communication technologies in human body have received an increasing attention and the research on an antenna that can be worn also has been actively conducted. In this paper, an wearable antenna that can receive GPS signal frequency is proposed. The antenna was manufactured by using a copper polyester fabric with thickness of 0.08mm as a radiator and a ground plate, and a goatskin with thickness of 0.7mm as dielectric substrate. Cutting edges placed in diagonal direction of square patch in order to obtain a circular polarization characteristic, and the conductive cloth and leather was laminated by using a conductive epoxy. First, goatskin dielectric constant was obtained through the simulation and measurement of resonance frequency of the three square patch antennas with different size. On the basis of the results, an antenna operating in the GPS band was designed and the performance of the antenna was validated by making the experiment. The change of the characteristic of the antenna that is located on the shoulder parts of the clothing and wearing person were measured. And it was confirmed that the reception sensitivity has a similar level as compared to the commercially produced ceramic GPS antenna.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2007.10a
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• pp.849-852
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• 2007

In this paper, the high gain and the broadband microstrip patch antenna, which is applicable to 5 GHz band wireless LAN, is designed in order to integrate IEEE 802.11a's detailed standards($a:5.15{\sim}5.25$, $b:5.25{\sim}5.35$, $c:5.725{\sim}5.875$ [GHz]). Designed patch antenna has settled resonance frequency by insert substance(polyurethane: ${\varepsilon}_r=6.5$) between the separated parasitic patch and radiation patch for the purpose of miniaturize. And the form (${\varepsilon}_r=1.03$) were to fix the separated radiation patch and ground plans by air. Designed frequency bandwidth(VSWR 2:1) of the antenna showed broadband characteristic of $4.9[GHz]{\sim}6.1[GHz]$ to about 1.2[GHz]. Also the E-plan and H-plan profit 12[dBi] above, the 3[dB] beamwidth showed the characteristic over the E-plan $30^{\circ}$ and H-plan $60^{\circ}$ to be improved.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2006.05a
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• pp.996-1001
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• 2006

Automatic washing machines have been improved and popularized steadily since the first electric washing machine was produced in the early 1900's. Appliance industry has tried to obtain the performance of washing machine with large capacity, high energy efficiency, low vibration and low noise levels. As the installation peace of a washer becomes closer to the living space, vibration and noise problems become more important challenges. In general, a washing machine has four legs to support its body. Four legs of the washing machine should be attached on a floor. If not so, it may cause severe vibration or walking in the spin-drying process. Unfortunately, the floor of an ordinary house is bumpy in general, and the consumers will not accept bolting washing machines to a foundation; moreover, sometimes they move the location of their washing machines to utility rooms or bath rooms or kitchens and don't care for leveling the legs exactly. In this study, we devise an auto-leg system that prevents the occurrence of abnormal vibration and walking of washing machines. It is simply composed of a spring and a friction damper. Some experiments are implemented to show the dynamic characteristics of the three-dimensional auto-legged washing machine model that is located on the even or uneven ground. A spring parameter is optimized to adjust the length of the auto-leg system automatically up to 10 mm irregularity, and the friction damper is designed to decrease a resonance induced by the spring of the auto-leg system. Some numerical results show that placing the proposed auto-leg system in a washing machine makes good performance with low vibration, as well as low noise, regardless of the unevenness of the floor.

• Smart Media Journal
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• v.9 no.2
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• pp.22-32
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• 2020

The hippocampal volume atrophy is known to be linked with neuro-degenerative disorders and it is also one of the most important early biomarkers for Alzheimer's disease detection. The measurements of hippocampal pure volumes from Magnetic Resonance Imaging (MRI) is a crucial task and state-of-the-art methods require a large amount of time. In addition, the structural brain development is investigated using MRI data, where brain morphometry (e.g. cortical thickness, volume, surface area etc.) study is one of the significant parts of the analysis. In this study, we have proposed a patch-based ensemble model of 3-D convolutional neural network (CNN) to measure the hippocampal pure volume from MRI data. The 3-D patches were extracted from the volumetric MRI scans to train the proposed 3-D CNN models. The trained models are used to construct the ensemble 3-D CNN model and the aggregated model predicts the pure volume in one-step in the test phase. Our approach takes only 5 seconds to estimate the volumes from an MRI scan. The average errors for the proposed ensemble 3-D CNN model are 11.7±8.8 (error%±STD) and 12.5±12.8 (error%±STD) for the left and right hippocampi of 65 test MRI scans, respectively. The quantitative study on the predicted volumes over the ground truth volumes shows that the proposed approach can be used as a proxy.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.14 no.8
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• pp.855-862
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• 2003

This paper suggests the PIFA structure modified antenna in which short-circuit plate is located between planar element and ground plane, in order to solve the problem of narrow band of existing internal antenna, PIFA. It is also suggested that internal antenna has the perturbation in the patch to broaden the frequency bandwidth. It is possible that the antenna is installed into the mobile telephone with a low profile condition(h=0.015 λ) to use internally, and acquired desired bandwidth(5.2 %) through double resonance structure, remodeling the PIFA that is already well-known as an internal antenna. This paper investigated how characteristic is affected by the feeding point(Yf, Zf), short strip plate(Zs), short strip width(Ws), perturbation width(w), length(d), short plate height(h), dielectric($\varepsilon$$\_$r/) to be slim type antenna. It is compared with existing PIFA bandwidth, and is suggested pattern as the H.E plane. It is simulated using the Microwave Studio of the CST Inc. based on FIM(Finite Integration Method) method and analyzed antenna characteristic following the variation each parameters. The result proved the practical use of PIFA antenna by comparing the measured and simulated data of the antenna.