• Bulletin of the Korean Chemical Society
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• 제29권4호
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• pp.767-771
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• 2008

Second-order rate constants have been measured spectrophotometrically for the Michael-type reaction of 1-(Xsubstituted phenyl)-2-propyn-1-ones (2a-f) with amines in $H_2O$ at 25.0 ${\pm}$ 0.1 ${^{\circ}C}$. A linear Brønsted-type plot is obtained with ${\beta}_{nuc}$ = 0.25 ${\pm}$ 0.02, a typical $\beta_{nuc}$ value for reactions which proceed through a stepwise mechanism with attack of amine on the electrophilic center being the rate-determining step. Secondary alicyclic amines are found to be more reactive than isobasic primary amines. The Hammett plot for the reactions of 2a-f with morpholine is not linear, i.e., the substrate with a strong electron-donating group (e.g., 4-MeO) exhibits a negative deviation from the Hammett plot. However, the Yukawa-Tsuno plot for the same reactions exhibits an excellent linear correlation with ρ = 0.62 and r = 0.82. Thus, it has been proposed that the nonlinear Hammett plot is not due to a change in the ra te-determining step but due to ground-state stabilization through resonance interactions.

• Geomechanics and Engineering
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• 제7권1호
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• pp.87-103
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• 2014

This study investigated the effect of soil-structure interaction (SSI) on the response of base-isolated buildings. Seismic isolation can significantly reduce the induced seismic loads on a relatively stiff building by introducing flexibility at its base and avoiding resonance with the predominant frequencies of common earthquakes. To provide a better understanding of the movement behavior of multi-story structures during earthquakes, this study analyzed the dynamic behavior of multi-story structures with high damping rubber bearing (HDRB) behavior base isolation systems that were built on soft soil. Various models were developed, both with and without consideration of SSI. Both the superstructure and soil were modeled linearly, but HDRB was modeled non-linearly. The behavior of the specified models under dynamic loads was analyzed using SAP2000 computer software. Erzincan, Marmara and Duzce Earthquakes were chosen as the ground motions. Following the analysis, the displacements, base shear forces, top story accelerations, base level accelerations, periods and maximum internal forces were compared in isolated and fixed-base structures with and without SSI. The results indicate that soil-structure interaction is an important factor (in terms of earthquakes) to consider in the selection of an appropriate isolator for base-isolated structures on soft soils.

• Bulletin of the Korean Chemical Society
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• 제33권6호
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• pp.1955-1961
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• 2012

In this work, the reactions of carbamyl and thiocarbamyl halides with $NH_3$ were studied in the gas phase at the MP2(FC)/6-31+G(d) level of theory. Single point calculations were performed at the QCISD/6-311+G(3df,2p) to refine the energetics. The reaction mechanisms were also studied in aqueous solution. The structures were fully optimized at the CPCM-MP2(FC)/6-31+G(d) and refined by a single point CPCM-QCISD/6-311+G(3df,2p) calculations. The reaction mechanisms for the title compounds were compared with those for the acetyl and thioacetyl halides. The lower reactivity of carbamyl (and thiocarbamyl) groups was explained by comparing the C=O and C=S ${\pi}$-bond strengths as well as resonance contributions in the ground state.

• 한국철도학회논문집
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• 제14권2호
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• pp.160-166
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• 2011

열차하중에 의한 토공노반의 동적응답은 다양한 주변환경에 종속적이기 때문에 정확한 특성을 규명하는 것은 어렵다. 그러나 일부 궤도틀림의 원인이 노반의 불균일한 지지력과 이에 따른 동적 응답의 영향일 것으로 예상되기 때문에 다양한 궤도틀림원인 분석 및 대책에 대한 연구를 위해서는 노반의 동적응답에 대한 연구가 필요하다. 본 논문에서는 노반의 동적응답이 궤도변형에 미치는 영향을 분석하기 위한 기초연구로서 여러가지 영향조건 중 노반의 구조와 재료강성의 변화에 따른 노반의 탁월 주파수와 진동에너지의 크기에 대한 응답을 검토하였다. 검토단면은 탁월대역의 에너지 증폭이 쉬운 이 층노반구조로서 노반과 연암으로 구성하였다. 검토내용은 각 조건별 파의 전파특성을 규명하고 노반의 동적응답을 이론적, 해석적, 경험적 방법으로 비교 검토하여 궤도틀림에 미치는 영향을 평가하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2003년도 하계학술대회 논문집 B
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• pp.840-842
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• 2003

저 주파수에서 인덕턴스 단위(H, Henry)는 전기용량의 단위(F, Farad)로부터 Maxwell bridge 또는 LC를 이용한 resonance 방법으로써 유도가 된다. 이중 Maxwell bridge 방법은 국가의 단위표준을 유지하는 연구소 또는 기관에서 가장 많이 사용되는 "product arm" 형의 bridge로 잘 알려져 있다. 개발된 bridge는 ratio-transformer를 전압공급 쪽(source)과 신호검출 쪽(detector)에 사용하여 종래의 Maxwell bridge 평형조절 시 main balance와 Wagner balance의 2개 과정을 진행하던 것과는 달리 main balance, source balance, detector balance의 과정을 진행함으로서 기존 bridge의 불안정한 ground admittance들의 영향에 의해 나타나는 불확도를 완전히 제거하였다. 한편 개발된 bridge는 10 mH, 100 mH를 10 nF의 전기용량표준기와 $1\;k{\Omega}$, $10\;k{\Omega}$의 저항표준기로부터 유도 되도록 제작되었으며. 10 mH의 경우 $400\;Hz{\sim}5\;kHz$의 주파수 영역에서 약 $2.2{\times}10^{-6}$(k=1)의 불확도로 인덕턴스 단위를 유도할 수가 있게 되었다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2003년도 하계학술대회 논문집 C
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• pp.1958-1960
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• 2003

Here we describe a unique self-oscillating mixer (SOM) design using a modified defected ground structure (DGS) for down-converter. Proposed SOM is consisted of self-oscillator, which can produce negative resistance and select resonance frequency, and input/output matching filter. As the advantage of this SOM can be reused by module that mix signals with transistor that is used to oscillator, it is simply and low-costly designed Also, there is easy advantage to be applied in RFIC/ MMIC technology because it offers excellent high Q value in spite of using micro-strip structure. Designed self-oscillating frequency is 1.04GHz and RF frequency established is 0.8GHz. It was achieved 20dB conversion loss and phase noise of -95dBc/Hz at 100KHz offset frequency over intermediate frequency (IF). The equivalent circuit parameters for DGS are extracted by using a three dimensional EM simulator and simple circuit analysis method.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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• pp.173-175
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• 2002

In general, CT and Shunt have been traditionally used as a sensor for detecting the partial discharges in order to diagnose the present insulation state of the electric power apparatus. The former is very convenient for the practical application since it is not only non-contact method but its frequency bandwidth and resonance frequency could be designed for its specific application. However, it has been proved to have poor linearity and low sensitivity. For the latter, even though it is an ideal sensor, noise from the power source and the ground could flow into the system. Furthermore, the surge current could be easily come into the measuring systems giving rise to a severe breakdown. In this respect, a hybrid sensor has been designed and fabricated in order to overcome the shortcoming of these two types of sensors. For this purpose, the experimental comparison with commercialized products has been also carried out. In this concept of the hybrid sensor, two different impedances could provide the passage of the signals. In this way, the discrimination of the noise could be accomplished very effectively with high ratio of signal over noise(S/N) under the little influence from the external noises and the breakdown.

• Bulletin of the Korean Chemical Society
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• 제21권10호
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• pp.953-954
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• 2000

The equilibrium geometrical structures of silver atom clusters at their electronic ground states have been theo-retically determined by using the nonrelativistic semiempirical INDO/1 method. The clusters investigated are Agn, Agn+, and Agn- (n = 7 , 8, 9). In order to find the most stable structure, i.e., the global minimum in energy hypersurface, geometry optimization and energy calculation processes have been repeatedly performed for all the possible graphical models by changing the bond parameters (resonance integral values). The heptamers are pentagonal bipyramidal-Ag7(D5h), Ag7+ (D5h), Ag7- (D5h); the octamers are pentagonal bipyramidal with one atom capped-Ag8(D2d), Ag8+ (Cs), Ag8- (D2d); the nonamers are pentagonal bipyramidal with two atoms capped -Ag9(C2v), Ag9+ (C2v), Ag9- (C2v). Our structures are in good agreement with those by ab initio calculations ex-cept for the anionic Ag9- cluster. And it is noted that the INDO/1 method can accurately predict the Ag cluster geometries when a proper set of bond parameters is used.

• Earthquakes and Structures
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• 제3권3_4호
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• pp.549-561
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• 2012

Many building foundations are embedded, however it is not easy to compact the backfill around the foundation especially for the deeply embedded ones. The soil condition around the embedded foundation may affect the seismic response of a building due to the weak contact between the soil and the foundation. In this paper, the response accelerations in the short-period range and at the period of 1 second (in the long-period range) for a seismic design spectrum specified in the IBC design code were compared considering perfect and poor backfills to investigate the effect of backfill compaction around the embedded foundation. An in-house finite-element software (P3DASS) which has the capability of horizontal pseudo-3D seismic analysis with linear soil layers was used to perform the seismic analyses of the structure-soil system with an embedded foundation. Seismic analyses were carried out with 7 bedrock earthquake records provided by the Pacific Earthquake Engineering Research Center (PEER), scaling the peak ground accelerations to 0.1 g. The results indicate that the poor backfill is not detrimental to the seismic response of a building, if the foundation is not embedded deeply in the soft soil. However, it is necessary to perform the seismic analysis for the structure-soil system embedded deeply in the soft soil to check the seismic resonance due to the soft soil layer beneath the foundation, and to compact the backfill as well as possible.

• Earthquakes and Structures
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• 제23권1호
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• pp.75-85
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• 2022

The megacity Istanbul was struck by an earthquake on September 26, 2019, with a moment magnitude (Mw) of 5.8. The mainshock was followed by many aftershocks. Although the peak ground acceleration (PGA) of the mainshock was as low as 0.08 g, its effect has been more than expected. The intensive reconnaissance studies were accomplished in the highly populated Zeytinburnu and Pendik districts of Istanbul. While the earthquake (EQ) was relatively smaller concerning record-specific intensity measures; the damages such as concrete spalling in reinforced concrete (RC) members, detachment and diagonal cracking of infill walls in RC frames as well as cracks in masonry structures were reported from non-engineered and some engineered buildings. Many studies in the literature state that record-specific intensity measures are not sufficient to evaluate the seismic performance of the structures. The structure-specific intensity measures, soil characteristics, as well as significant duration, energy, and frequency content of EQs should be considered for the evaluation. Dependently, the frequency and energy contents of the Istanbul Earthquake are evaluated to discuss the possible reasons for the perceived effects and the damages. It is concluded that the EQ caused resonance effects on a variety of structures because of its complex frequency content as well as rather low building quality.