• Geomechanics and Engineering
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• 제14권3호
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• pp.225-231
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• 2018

In this paper, in order to explain the splitting of cylindrical rock specimen under uniaxial loading, cracks in cylindrical rock specimen are divided into two kinds, the longitudinal crack and the slanting crack. Mechanical behavior of the rock is described by elastic-brittle-plastic model and splitting is assumed to suddenly occur when the uniaxial compressive strength is reached. Expression of the stresses induced by the longitudinal crack in direction perpendicular to the major axis of the crack is deduced by using the Maxwell model. Results show that the induced stress is tensile and can be greater than the tensile strength even before the uniaxial compressive strength is reached. By using the Inglis's formula and simplifying the cracks as slender ellipse, the above conclusions that drawn by using the Maxwell model are confirmed. Compared to shearing fracture, energy consumption of splitting seems to be less, and splitting is most likely to occur when the uniaxial loading is great and quick. Besides, explaining the rock core disking occurred under the fast axial unloading by using the Maxwell model may be helpful for understanding that rock core disking is fundamentally a tensile failure phenomenon.

• 대한금속재료학회지
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• 제46권5호
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• pp.296-303
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• 2008

Hydrogen permeation through dense palladium-based membranes has attracted the attention of many scientists largely due to their unmatched potential as hydrogen-selective membranes for membrane reactor applications. Although it is well known that the permeation mechanism of hydrogen through Pd involves various processes such as dissociative adsorption, transitions to and from the bulk Pd, diffusion within Pd, and recombinative desorption, it is still unclear which process mainly limits hydrogen permeation at a given temperature and hydrogen partial pressure. In this study, we report an all-electron density-functional theory study of hydrogen permeation through Pd membrane (using VASP code). Especially, we focus on the variation of the energy barrier of the penetration process from the surface to the bulk with hydrogen coverage, which means the large reduction of the fracture stress in the brittle crack propagation considering Griffith's criterion. It is also found that the penetration energy barrier from the surface to the bulk largely decreases so that it almost vanishes at the coverage 1.25, which means that the penetration process cannot be the rate determining process.