• Korean Chemical Engineering Research
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• v.56 no.5
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• pp.647-654
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• 2018

In order to solve the global warming and reduce greenhouse gas emissions, it has been developed the $CO_2$ capture technology by oxy-fuel combustion. But there is a problem that the economic efficiency is low because the oxygen production cost is high. ASU (Air Separation Unit) is known to be most suitable method for producing large capacity of oxygen (>2,000 tpd). But most of them are optimized for high purity (>99.5%) oxygen production. If the ASU process is optimized for low purity(90~97%) oxygen producing, it is possible to reduce the production cost of oxygen by improving the process efficiency. In this study, the process analysis and comparative evaluation was conducted for developing large capacity ASU for oxy-fuel combustion. The process efficiency was evaluated by calculating the recovery rate and power consumption according to the oxygen purity using the AspenHysys. As a result, it confirmed that the optimal purity of oxygen for oxyfuel combustion is 95%, and the power consumption can be reduced by process optimization to 12~18%.

• Korean Chemical Engineering Research
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• v.56 no.5
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• pp.631-640
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• 2018

The application of an oxy-combustion circulating fluidized bed combustor (Oxy-CFBC) for low grade coals has recently developed in the world to meet the continuous increase of energy demand and to achieve the reduction of greenhouse gases. Since demo plants for Oxy-CFBC have been developed, the combustion properties of Oxy-CFBC in various operation conditions, such as gas flow rates, combustion temperature, fuel, and so on, should be investigated to develop design criteria for a commercial Oxy-CFBC. In this study, a computational simulation tool for Oxy-CFBC was developed on the basis of the IEA-CFBC (International Energy Agency Circulating Fluidized Bed Combustor) model. Simulation was performed under various conditions such as reaction temperature ($800^{\circ}C{\sim}900^{\circ}C$), oxygen contents (21%~41%), coal feeding rate, Ca/S mole ratio (1.5~4.0), and so on. Simulation results show that the combustion furnace temperature is higher in oxy 1 than air fired. However, the temperature gradient tended to decrease with increasing oxy mixing percent. In case of $SO_x$, the higher the Ca/S mole ratio and oxy mixing percent, the higher the desulfurization efficiency.

• Korean Journal of Construction Engineering and Management
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• v.18 no.1
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• pp.74-82
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• 2017

It is known that energy usage from Korean Universities was growing rapidly in the early 2000s. But since 2011, the change was caused by GHG emissions regulation enforced by the government. The purpose of this research was to find the characteristics and trends of greenhouse gas emissions from major universities in Korea according to the each university's data and information. The result shows that GHG emissions from University have increased steadily prior to enforcement by 4-5% annually, but the rate of increase marked 0.5~1% in 2011~2013 is the season of emission regulation and the total amount of emissions decreased 3%~5% in 2014~2015 while preparing an emissions trading scheme. Therefore we can say that the enforcement of GHG reduction such as energy target management system makes a visible effect at least in the University sector that level of GHG emissions is from $75kg/m^2$ to $58Kg/m^2$ for seven years. Another result says that the size of research fund is the main factor that affects the amount of GHG emissions before 2011, but the size of building area has been a new factor influencing the GHG emission since 2013. Thus we suggest that the criteria for evaluating the level of GHG emission from University is suitable if it is based on the building area intensity.

• Clean Technology
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• v.24 no.1
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• pp.50-54
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• 2018

In this work, N-methyl-2-pyrrolidone (NMP) was added into diethylenetriamine (DETA) aqueous solution for high $CO_2$ loading via phase splitting of absorbents during $CO_2$ absorption. Immiscible two phases were formed in the range of more than 30 wt% of NMP in 2 M DETA + NMP + water absorbents because of low solubility of DETA-carbamate in NMP solution. As the composition of NMP in the absorbents increased, the difference of $CO_2$ loading between each phase increased and the volume of bottom phase decreased. In $CO_2$ absorption in packed column by 2 M DETA + NMP + water absorbents, the absorption rate decreased in the range of more than 40 wt% of NMP. It is due to the increasing of mass transfer resistance in liquid film of absorbents at the high concentration of NMP. DETA + NMP + water absorbent is expected as the promising one for reducing the regeneration energy of absorbents according to volume reduction of $CO_2-rich$ phase.

• Journal of Korea Water Resources Association
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• v.39 no.12 s.173
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• pp.1043-1056
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• 2006

Our ultimate purpose is to investigate the potential change in regional surface climate due to the global warming and to produce higher quality regional surface climate information over the Korean peninsula for comprehensive impact assessment. Toward this purpose, we carried out two 30-year long experiments, one for present day conditions (covering the period 1971-2000) and one for near future climate conditions (covering the period 2021-2050) with a regional climate model (RegCM3) using a one-way double-nested system. In order to obtain the confidence in a future climate projection, we first verify the model basic performance of how the reference simulation is realistic in comparison with a fairly dense observation network. We then examine the possible future changes in mean climate state as well as in the frequency and intensity of extreme climate events to be derived by difference between climate condition as a baseline and future simulated climate states with increased greenhouse gas. Emphasis in this study is placed on the high-resolution spatial/temporal aspects of the climate change scenarios under different climate settings over Korea generated by complex topography and coastlines that are relevant on a regional scale.

• Journal of Korea Water Resources Association
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• v.53 no.11
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• pp.961-971
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• 2020

The Intergovernmental Panel on Climate Change (IPCC) reported that the amount of precipitation in South Korea would increase regardless of the reduction of Greenhouse Gas (GHG) emissions. Moreover, the temporal and spatial rainfall variation would also increase in the future. Due to the geographic allocation of Korea, more than 80% of the annual precipitation occurs in the wet season from early July to late September. It is expected that the average precipitation in this period will increase from the Representative Concentration Pathways (RCP) scenario projections. These predictions imply an increased variability of available water resources. Rainwater harvesting system is widely used as an alternative water resources today. This study introduces a RBSN (rain barrel sharing network) as an efficient way to utilize alternative water resources under the RCP scenarios. The concept of RBSN combines individual rainwater harvesting system to a sharing network, which make the whole system more reliable. This study evaluated a RBSN in South Korea composed of four users based on a storage-reliability-yield (SRY) relationship. The study area comprises all 17 provincal areas in South Korea. The result showed a huge benefit from a RBSN in Korea under the historical rainfall condition. Even in the climate change condition, the results showed that a RBSN is still beneficial but the changes in reliability are different depending on provinces in Korea. The results of this study shows that a RBSN is a very effective and alternative measure that can deal with the impacts of climate change in the near future.

• Journal of Korean Society of Forest Science
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• v.103 no.1
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• pp.137-146
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• 2014

We have developed the Forest Carbon Sink Index on afforestation and reforestation activities, a regulation stated in article 26 of the 'Law on the maintenance and enhancement of carbon sink (Carbon Sink Law)', which took effect on March, 2013. According to the legal purpose to evaluate the performance of individual forest carbon offset projects and to compare each other at a certain point, values of the forest carbon sink index were calculated by the scoring method. Three criteria were established based on the Carbon Sink Law: 'Carbon' (real greenhouse gas reduction), 'Human' (socio-economic effect) and 'Nature' (environmental effect). Continuously, 9 indicators from the three criteria were selected by top-down approach; the adequacy of each criteria and indicators were reviewed through on-line Delphi survey; and finally weighted value of each criteria and indicators were assigned. To reflect the characteristics of the domestic forest carbon offset projects, which focus on corporate social responsibility-typed projects, we applied the score weighting method to minimize gaps among criteria and ones among indicators. After applying our newly developed forest carbon sink index to five domestic forest carbon offset projects, we could confirm that the criteria of 'Human' and 'Nature', which criteria are in relatively low weight, can play a role as an actual incentive to reduce negative socio-economic and environmental impacts. Based on performance evaluation of the five forest carbon offset project by the forest carbon sink index, the best or good performance project developers could be rewarded, and further the performance evaluation would work as an incentive to stimulate the involvement of domestic project developers in the field of forest carbon offset project.

• Journal of Energy Engineering
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• v.17 no.2
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• pp.54-66
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• 2008

After the Kyoto Protocol has been ratified in Feb. 16 2005, the developed countries which is involved in Annex-1 have tried to mitigate GHG to the reduction objective. To accomplish this objective, EU developed EU-ETS, CDM project, and so on. Korea has faced pressure to be a member of Annex-1, because Korea and Mexico are only non-Annex-1 countries in the OECD nations. In this study, we simulated power plant expansion plan and calculated $CO_2$ emission with changing Carbon Tax. Especially, we focused on the competitiveness of IGCC and carbon capture technology. In our result, even though carbon tax rise, nuclear power plant does not always increase, it increase up to minimum load. LNG combined cycle power plants substitute the coal fired power plants. If there are many alternatives like IGCC, these substitute a coal fired power plant and we can reduce more $CO_2$ and save mitigation cost.

• Journal of Energy Engineering
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• v.24 no.1
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• pp.32-41
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• 2015

The Metropolitan Area Green Heat Project (MAGHP), which collects unused heat gathered from power plants, steel works, landfills in western Metropolitan area and distribute it to integrated energy business (IEB) companies, is proposed for the purpose of enhancing energy efficiency and providing low-price heat for IEB companies. Therefore, in order to decide on whether to initiate the MAGHP, the economic feasibility analysis of the project is widely demanded. This paper attempts to consider and measure four economic benefits: heat supply benefit, production cost reduction benefit, greenhouse gas mitigation benefit, and air quality improvement benefit. In addition, the paper tries to conduct the economic feasibility analysis. The project requires three-year investment and thirty-year operation. Three important findings emerge from the analysis. First, its net present value is computed to be 1,269 billion won and more than zero. Second, its benefit/cost ratio is calculated to be 1.72 and bigger than 1.0. Third, its internal rate of return is estimated to be 24.26% and larger than the social rate of return, 5.5%. In conclusion, the MAGHP is socially profitable and should be conducted immediately.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.1
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• pp.55-62
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• 2012

The present paper investigates the performance of the KOH aqueous solution as an absorbent to capture carbon dioxide ($CO_2$). The chemical absorption was carried out according to consecutive reactions that are generated in the order of $K_2CO_3$ and $KHCO_3$. The overall absorption was completed with following the physical absorption. When the absorption was conducted with the KOH as the limiting reactants in batch a reactor, $K_2CO_3$ production rate was the 1st order reaction for $OH^-$. However, $KHCO_3$ generation reaction was independent of the $CO_3^{2-}$ concentration and the rate was calculated to be $0.18gCO_2/min$ for all KOH absorbents, which is the same value of the reaction rate using $K_2CO_3$ aqueous solution as the absorbents. The overall $CO_2$ capture ratio of the 5% KOH absorbent was estimated to be 19% and the individual value in section 1 and 2 was 57 and 12%, respectively. The amount of $CO_2$ absorbed in the solution was very slightly less than the theoretical value, which was ascribed to the side reaction that produces $K_2CO_3{\cdot}KHCO_3{\cdot}1.5H_2O$ during the reaction and the consequent diminish in $CO_2$ absorption in the KOH solution.