• Composites Research
• /
• v.35 no.2
• /
• pp.98-105
• /
• 2022

In this study, polyvinyl alcohol (PVA)/graphene oxide (GO)/iron oxide (Fe₃O₄) magnetic microgels were prepared using a microfluidic approach and the dye adsorption capacity of the microgels was confirmed. The adsorption capacity (q_e) of the gels was evaluated by varying the dye concentration, pH, and contact time with the microgels. The dyes used in this work were methylene blue (MB), crystal violet (CV), and malachite green (MG), and microgels showed the highest adsorption capacity (191.1 mg/g) in methylene blue. The microgels exhibited the highest adsorption capacity in the dye aqueous solution at pH 10 due to the presence of atomic nitrogen ions (N⁺) on the dye molecules. The adsorption isotherm studies revealed that the Langmuir isotherm is the best fit isotherm model for the dye adsorption on the microgels, indicative of monolayer adsorption. The kinetic analysis exhibited that the pseudo-second order model fits better than the pseudo-first order model, confirming that the adsorption process is chemisorption. In addition, the magnetic microgels showed good reusability and recovery efficiency. It was confirmed that the adsorption capacity of the gels maintains more than 70% of the initial capacity after 5 times of cycle experiments.

• Composites Research
• /
• v.36 no.6
• /
• pp.454-460
• /
• 2023

Recently, regulations on greenhouse gas emissions have been strengthened, and the International Maritime Organization (IMO) has been strengthening greenhouse gas regulations with a goal of net 'zero' emissions by 2050. In addition, in the shipbuilding/offshore sector, it is important to reduce operating costs, such as improving propulsion efficiency and lightening structures. In this regard, research is currently being conducted on topology optimization using 3D printed composite materials to satisfy structural lightness and high rigidity. In this study, three topology shapes (hexagonal, square, and triangular) were applied to the interior of a rudder, a ship structure, using 3D printed composite materials. Structural analysis was performed to determine the appropriate shape for the rudder. CFD analysis was performed at 10° intervals from 0° to 30° for each rudder angle under the condition of 8 knots, and the load conditions were set based on the CFD analysis results. As a result of the structural analysis considering the internal topology shape of the rudder, it was confirmed that the triangular, square, and hexagonal topology shapes have excellent performance. The rudder with a square topology shape weighs 78.5% of the rudder with a triangular shape, and the square topology shape is considered to superior in terms of weight reduction.

• Journal of Korean Society of Environmental Engineers
• /
• v.29 no.9
• /
• pp.1013-1019
• /
• 2007

Electronic wastes have increased tremendously. However, any reliable treatment methodologies have rarely been established. Electronic wastes have posed serious disposal problem due to their physico-chemical stability. This paper investigated the application possibility of pyrolysis for the purpose of recycling the p-CCL(phenol based Copper Clad Laminate). Thermogravimetric analysis(TGA) was used to investigate the thermal decomposition pattern of p-CCL. We elucidated the characteristics of pyrolysis by-products at operating temperatures of 280, 350 and $600^{\circ}C$. GC/MS and FT-IR were used to characterize the liquid by-products along with general characterization methods such as Ultimate Analysis, Proximate Analysis and Heating Value, whereas general characterization methods were only introduced for the solid by-products. At a heating rate of $5^{\circ}C$/min, TGA curves exhibited three decomposition stages: (1) low-temperature decomposition region$(<280^{\circ}C)$, (2) medium temperature region$(280\sim350^{\circ}C)$ and (3) high-temperature region$(>350^{\circ}C)$. The major compounds of liquid by-products at low- and medium-temperatures were accounted for by water and phenol, whereas branched phenols and furans were major compounds at high-temperatures. As the temperature increases, volatile quantities decreased but the fixed carbon increased. High heating values of solid by-products($7,400\sim7,600$ kcal/kg) would suggest that the solid by-products could be applicable as fuel. In addition, high fixed carbon but low ash content of the solid by-products offered an implication that they are capable of being upgradable for adsorbent after applying appropriate activating process.