• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제37회 추계학술대회논문집
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• pp.685-693
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• 2011

에너지기후시대에 신에너지원 발굴, 저탄소 녹색성장의 일환으로 석탄 IGCC기술이 개발 중에 있다. 본 연구는 IGCC기술 중 가스화기에서 생산된 합성가스를 가스터빈에 직접 주입시 생길 수 있는 문제점을 미리 파악하고, 그 연소특성자료를 축적하기 위해 수행되었다. GE7EA연소기를 대상으로한 상압 및 고압연소실험을 통해 합성가스의 기본적인 연소특성을 파악하였으며, 수소화염이 과다한 NOx발생의 원인임을 파악하고, 질소희석을 통해 NOx배출량을 제어할 수 있음을 확인하였으며, 연소진동은 크게 발생치 않음을 확인하였다. 본 연구를 통해 축적된 시험 데이터는 2015년에 국내 최초로 준공예정인 태안 IGCC플랜트에 연소진단시스템 및 최적화 기술적용시 활용된 예정이다.

• 한국분말재료학회지
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• 제20권4호
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• pp.253-257
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• 2013

Freeze drying for porous Mo was accomplished by using $MoO_3$ powder as the source and camphor-naphthalene eutectic system as the sublimable material. Eutectic composition of camphor-naphthalene slurries with the initial $MoO_3$ content of 5 vol%, prepared by milling at $55^{\circ}C$ with a small amount of oligomeric dispersant, was frozen at $-25^{\circ}C$. The addition of dispersant showed improvement of dispersion stability in slurries. Pores were generated subsequently by sublimation of the camphor-naphthalene during drying in air for 48 h. To convert the $MoO_3$ to metallic Mo, the green body was hydrogen-reduced at $750^{\circ}C$, and sintered at $1100^{\circ}C$ for 2 h. The sintered samples, frozen by heated Teflon cylinder, showed large pores with the size of about 40 ${\mu}m$ which were aligned parallel to the sublimable vehicles growth direction. The formation of unidirectionally aligned pores is explained by the rejection and accumulation of solid particles in the serrated solid-liquid interface.

• 한국수소및신에너지학회논문집
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• 제29권1호
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• pp.64-70
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• 2018

In this study, the kg-class Ni-Al alloy fabrication process at low temperature was developed from the physical mixture of Ni and Al powders. The AlCl3 as an activator was used to reduce the temperature of alloy synthesis below the melting temperature of Ni and Al elements (<$500^{\circ}C$). Mixed phase of Ni3Al intermetallic and Ni-Al solid-solution were identified in the XRD pattern analysis. Furthermore, from the analysis of SEM and particle size analyzer, we found that the particle size of synthesized alloy powders was not changed compared to the initial size of Ni particle after the formation of alloy powder at $500^{\circ}C$. In the creep test, the anode (which was fabricated by the prepared Ni-Al alloy powders in this study) displayed the enhanced creep resistance compared to the conventional anode.

• 한국수소및신에너지학회논문집
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• 제23권2호
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• pp.143-149
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• 2012

용융탄산염 연료전지 상용화를 위해서 40,000 시간이상 장기 운전이 가능해야 한다. 장기운전을 위해 크랙 발생이 적고 기계적 강도가 높은 강화 매트릭스의 개발이 절실히 요구되고 있다. 본 연구에서는 $LiAlO_2$에 알루미늄 나노입자를 첨가하여 매트릭스의 기계적 강도를 향상시키는 연구를 수행하였다. 나노 알루미늄 첨가 $LiAlO_2$ 그린 시트를 수소 분위기에서 열처리한 결과, 공기 분위기에서 열처리한 매트릭스에 비해 기계적 강도가 1.5배 증가함을 확인하였다. 이는 환원분위기에서 열처리를 할 경우, 알루미늄의 입자간의 소결으로 인한 neck이 형성 되어 $LiAlO_2$ 입자 간에 다리를 만들어주는 효과가 나타나 매트릭스의 기계적 강도가 크게 증진되었으리라 판단된다.

• 한국재료학회지
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• 제25권11호
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• pp.602-606
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• 2015

Porous W with spherical and directionally aligned pores was fabricated by the combination of sacrificial fugitives and a freeze-drying process. Camphene slurries with powder mixtures of $WO_3$ and spherical PMMA of 20 vol% were frozen at $-25^{\circ}C$ and dried for the sublimation of the camphene. The green bodies were heat-treated at $400^{\circ}C$ for 2 h to decompose the PMMA; then, sintering was carried out at $1200^{\circ}C$ in a hydrogen atmosphere for 2 h. TGA and XRD analysis showed that the PMMA decomposed at about $400^{\circ}C$, and $WO_3$ was reduced to metallic W at $800^{\circ}C$ without any reaction phases. The sintered bodies with $WO_3$-PMMA contents of 15 and 20 vol% showed large pores with aligned direction and small pores in the internal walls of the large pores. The pore formation was discussed in terms of the solidication behavior of liquid camphene with solid particles. Spherical pores, formed by decomposition of PMMA, were observed in the sintered specimens. Also, microstructural observation revealed that struts between the small pores consisted of very fine particles with size of about 300 nm.

• 대한화학회지
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• 제57권3호
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• pp.329-334
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• 2013

솔잎조직과 ferrocene을 각각 효소원 및 매개체로, CSM 고무를 흑연가루 결합재로 사용하여 전류법 과산화수소 정량 효소전극을 제작하고, 그것의 특성을 전기화학적인 방법으로 관찰하였다. 낮은 퍼텐샬 영역(-100 ~ -500 mV)에서 보여준 ln($i(1-e^{nf{\eta}})$) vs. ${\eta}$ 및 Lineweaver-Burk 도시의 좋은 직선성은 신호전류의 생성이 효소의 촉매작용에 의한 것임을 확인하여 주었다. 이 때 얻어진 대칭인자(${\alpha}$, 0.17), 한계전류($i_1$, 1.99 $A/cm^2$), 교환전류밀도($i_0$, $5.86{\times}10^{-5}\;A/cm^2$), 마이클 상수($K_M$, $1.68{\times}10^{-3}$ M) 및 기타 전극 파라메터들은 전극 표면에서 소나무 과산화효소가 정량적으로 성능을 발휘하고 있음을 보여 주었다. 이런 실험적 사실들은 솔잎조직이 상업용 과산화효소를 대치하여 실용 효소전극 제작에 사용될 수 있음을 보여 주었다.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.437-447
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• 2012

Ceria ($CeO_2$) was used to scavenge free radicals which attack the membrane in the polymer electrolyte membrane water electrolysis (PEMWE) circumstance and to increase the duration of the membrane. In order to improve the electrochemical, mechanical and electrocatalytic characteristics, engineering plastic of the sulfonated polyether ether ketone (SPEEK) as polymer matrix was prepared in the sulfonation reaction of polyether ether ketone (PEEK) and the organic-inorganic blended composite membranes were prepared by sol-gel casting method with loading the highly dispersed ceria and cesium-substituted tungstophosphoric acid (Cs-TPA) with cross-linking agent contents of 0.01 mL. In conclusion, CL-SPEEK/Cs-TPA/ceria (1%) membrane showed the optimum results such as 0.130 S/cm of proton conductivity at $80^{\circ}C$, 2.324 meq./g-dry-membrane of ion exchange capacity and mechanical characteristics, and 65.03 MPa of tensile strength which were better than Nafion 117 membrane.

• 한국수소및신에너지학회논문집
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• 제21권5호
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• pp.435-441
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• 2010

To verify the possibility of a power generation system using biogas from the waste of pig farm for rural electric production, a SI gasoline engine is modified to use biogas fuel and was installed in a 20 KVA power generation system. An electronic speed regulation unit is developed to keep the system speed at 1500 rpm. Experimental investigations have been carried out to examine the performance characteristics of power generation system (such as: system frequency, phase output voltage,$\ldots$). In addition, the operating parameters and output emissions ($NO_x$, HC, and $CO_2$) of biogas-fueled engine are preliminary evaluated and analyzed for the change of system load. Results indicated that the researched power generation system shows a high stability of output voltage and frequency with help of speed regulator. Biogas fuel (mainly $CH_4$ and $CO_2$) has an environmental impact and potential as a green alternative fuel for SI engine and they would not require significant modification of existing engine hardware. Output emissions of biogas-fueled engine are found to be relative low. $NO_x$ emission increases with the increase of output electric power of the power generation system.

• 한국진공학회지
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• 제7권2호
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• pp.127-134
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• 1998

스테인레스강은 내식성이 우수해서 많은 용도로 사용되고 있다. 스테인레스강의 내 식특성과 함께 장식용으로 적당한 색상을 부역하기 위한 여러 방법으로 시도되고 있다. 본 연구에서는 DC amgnetron sputtering장치를 사용하여 스테인레스강의 표면에 TiN(C,O,H) 코팅층을 코팅한 후, 집합조직과 색상에 미치는 산소, 수소, 아세칠렌가스의 영향에 관한 연 구를 수행하였다. 수소와 아세칠렌이 첨가됨에 따라 (220)집합조직은 (200)거쳐서 (111)으로 변화하였고, 아세칠렌이 더욱 증가되면 (111)집합조직을 나타내었다. 산소의 첨가는 (111)을 거쳐 (200)으로 변화시켰다. TiN의 색상은 산소의 첨가에 따라 황금색으로부터 회색을 거쳐 녹색으로 변화하였다. 아세칠렌의 첨가는 분홍색을 거쳐서 회색으로 변화하였다. 반사율은 수소의 첨가에 따라 단파장의 영역에서 증가하였고, 산소와 아세칠렌의 첨가에 따라 감소하 였다.

• 한국분말재료학회지
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• 제28권4호
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• pp.331-335
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• 2021

The effects of drying temperature on the microstructure of porous W fabricated by the freeze-casting process of tert-butyl alcohol slurry with WO₃ powder was investigated. Green bodies were hydrogen-reduced at 800℃ for 1 h and sintered at 1000℃ for 6 h. X-ray diffraction analysis revealed that WO₃ powders were completely converted to W without any reaction phases by hydrogen reduction. The sintered body showed pores aligned in the direction of tert-butyl alcohol growth, and the porosity and pore size decreased as the amount of WO₃ increased from 5 to 10vol%. As the drying temperature of the frozen body increased from -25℃ to -10℃, the pore size and thickness of the struts increased. The change in microstructural characteristics based on the amount of powder added and the drying temperature was explained by the growth behavior of the freezing agent and the degree of rearrangement of the solid powder during the solidification of the slurry.